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Topic Review
Chemical Rings
The epoxidized group, also known as the oxirane group, can be considered as one of the most crucial rings in chemistry. Due to the high ring strain and the polarization of the C–O bond in this three-membered ring, several reactions can be carried out. One can see such a functional group as a crucial intermediate in fuels, polymers, materials, fine chemistry, etc. 
  • 1.6K
  • 30 Aug 2021
Topic Review
Zeolites as Catalyst Supports for Hydrocarbon Oxidation Reactions
Catalytic oxidation is a key technology for the conversion of petroleum-based feedstocks into useful chemicals (e.g., adipic acid, caprolactam, glycols, acrylates, and vinyl acetate) since this chemical transformation is always involved in synthesis processes. Zeolites are microporous, crystalline aluminosilicate materials known since 1756 when the stilbite structure was identified by the Swedish mineralogist Crönstedt. Zeolites and other related porous materials can be supports for organometallic or metallic active species. These materials are the most studied supports due to their combined properties of mechanical and thermal stability that allows it an easy regeneration and recycling. 
  • 1.6K
  • 25 Mar 2022
Topic Review
Membrane Technologies in Dairy Industry
Membrane technologies can be used in the dairy industry for many applications, such as milk clarification or fractioning and a concentration increase in specific components or the separation of them, since they cover a huge range of pore sizes (from 0 to 2 μm) and MWCOs (from 1 to 100,000 Da). For instance, MF can be used for fat globule (10 μm) fractionation as well as bacteria and spore (1 μm) removal. UF can be used for casein micelles (100 nm) or serum protein (10 nm) separation, whereas NF and RO can be used for lactose (1 nm), salt (0.1 nm) and water recovery.
  • 1.6K
  • 18 Nov 2021
Topic Review
Concentrated Solar Power Technology in Photocatalytic Water Purification
Photocatalysis, a promising semiconductor-based technology activated by free and eternal solar energy, has great potential for addressing environmental remediation and energy conversion challenges. Concentrated solar power (CSP) technologies, namely parabolic trough reflectors, solar power towers, parabolic dish reflectors and linear Fresnel reflectors, exhibited excellent feasibility for boosting solar-driven photocatalytic processes. Based on the structural characteristics of CSP technologies, the CSP-based photocatalytic reactors could be divided into concentrated types and non/low-concentrated types. 
  • 1.6K
  • 23 Feb 2024
Topic Review
Sustainable Consumption and Production History
SCP has two constituents, consumption and production. Shall we treat them separately or together? Sustainable production is “the creation of goods and services using processes and systems that are non-polluting, conserving of energy and natural resources, economically viable, safe and healthful for workers, communities, and consumers”. Sustainable consumption is the use of products and services that have a minimal impact on environment and enable future generations to meet their needs.
  • 1.6K
  • 22 Sep 2021
Topic Review
C-,N- and S-Doped TiO2 Photocatalysts
This entry describes the basics of photocatalysis. It also presents properties and applications of C-,N- and S-Doped TiO2 as a photocatalyst.
  • 1.5K
  • 28 May 2021
Topic Review
Data-Driven Process Monitoring Methods for Industrial Data
Safe and stable operation plays an important role in the chemical industry. Fault detection and diagnosis (FDD) make it possible to identify abnormal process deviations early and assist operators in taking proper action against fault propagation. After decades of development, data-driven process monitoring technologies have gradually attracted attention from process industries. Although many promising FDD methods have been proposed from both academia and industry, challenges remain due to the complex characteristics of industrial data. In this work, classical and recent research on data-driven process monitoring methods is reviewed from the perspective of characterizing and mining industrial data. The implementation framework of data-driven process monitoring methods is first introduced. State of art process monitoring methods corresponding to common industrial data characteristics are then reviewed. Finally, the challenges and possible solutions for actual industrial applications are discussed. 
  • 1.5K
  • 21 Feb 2022
Topic Review
Fouling Prevention in Membranes by Radiation-Induced Graft Copolymerization
The application of membrane processes in various fields has now undergone accelerated developments, despite the presence of some hurdles impacting the process efficiency. Fouling is arguably the main hindrance for a wider implementation of polymeric membranes, particularly in pressure-driven membrane processes, causing higher costs of energy, operation, and maintenance. Radiation induced graft copolymerization (RIGC) is a powerful versatile technique for covalently imparting selected chemical functionalities to membranes’ surfaces, providing a potential solution to fouling problems. 
  • 1.5K
  • 17 Jan 2022
Topic Review
Microbial Production of C4 Dicarboxylic Acids
In addition to acetoin and 2,3-butanediol, another class of compounds that is readily derivable from biochemical conversions is C4 dicarboxylic acids; specifically, these are succinic (butanedioic acid), fumaric (trans-butenedioic acid), and malic (hydroxybutanedioic acid) acids. 
  • 1.5K
  • 19 May 2022
Topic Review
Electrocatalytic CO2 Reduction to Formate and Formic acid
The electrocatalytic CO2 reduction reaction (CO2RR) to formic acid has gained significant attention as a potential environmentally friendly approach to reducing CO2 emissions and producing carbon-neutral liquid fuels. However, several challenges must be addressed to achieve the production of high-purity and high-concentration formic acid through CO2RR. One major challenge is the formation of a formate mixture instead of pure formic acid in conventional reactors. This requires costly downstream purification and concentration processes to obtain pure formic acid. 
  • 1.5K
  • 19 Jun 2023
Topic Review
Pyrolysis of Biosolids to Produce Biochars
Biochar is a solid, charcoal material that can be used in different applications such as its use in agriculture as a soil enhancer in which moisture content is sustained for long periods of times. Biosolids or biosludges will refer to any form of sludge that has undergone some form of treatment (e.g., chemical, biological, heat treatment, etc.) in order to transform it into a less hazardous and organic form. More importantly, there seems to be an inconsistency in defining what classifies as biosolids, hence, a unified definition is established and provided. The aim is to enable the scientific community as a whole to use a standard definition that allows for synergies to take place. Specifically, the pyrolysis process is selected and is known as a thermochemical technique in which heat and an oxygen-free environment facilitate the decomposition of the feedstock into different products, depending on the operating parameters.
  • 1.5K
  • 14 Sep 2022
Topic Review
Pharmaceutical Removal on Wastewater
Pharmaceuticals enhance our quality of life; consequently, their consumption is growing as a result of the need to treat ageing-related and chronic diseases and changes in the clinical practice. The market revenues also show an historic growth worldwide motivated by the increase on the drug demand. However, this positivism on the market is fogged because the discharge of pharmaceuticals and their metabolites into the environment, including water, also increases due to their inappropriate management, treatment and disposal; now, worldwide, this fact is recognized as an environmental concern and human health risk. 
  • 1.5K
  • 08 May 2021
Topic Review
Crude Glycerol Upgrading
Crude glycerol is the main byproduct of biodiesel manufacturing from oleaginous crops and other biomass-derived oils. Approximately 10% crude glycerol is produced with every batch of biodiesel. Worldwide, there is a glut of glycerol and the price of it has decreased considerably. There are real opportunities for valorizing crude glycerol into higher value-added chemicals which can improve the economic viability of biodiesel production as an alternative fuel. Exploring new potential applications of glycerol in various sectors is needed such as in pharmaceuticals, food and beverages, cosmetics, and as a transportation fuel.
  • 1.5K
  • 24 Feb 2023
Topic Review
High-Frequency Ultrasound Technology for Biofuel Production
High-frequency ultrasound (HFU) is an ultrasound technology with a frequency higher than 1000 kHz. It has become increasingly recognized as an emerging process intensification technology in various fields, such as biofuel production, carbon dioxide absorption, and wastewater treatment. HFU is seen as a potential intensifier technology for biofuel production, as its mechanisms, such as cavitational phenomena, microstreaming, and fountain formation, can benefit biofuel production.
  • 1.5K
  • 06 May 2023
Topic Review
Surface-Enhanced Raman Spectroscopy Substrates for Food Safety Detection
Food safety analysis currently relies on the enzyme-linked immunosorbent assay (ELISA), polymerase chain reaction (PCR), high-performance liquid chromatography (HPLC), gas chromatography (GC), UV-visible spectrophotometry, and tandem mass spectrometry (MS), all of which require significant time to train qualified food safety testing laboratory operators. These factors have hindered the development of rapid food safety monitoring systems, especially in remote areas or areas with a relative lack of testing resources. Surface-enhanced Raman spectroscopy (SERS) has emerged as one of the tools of choice for food safety testing that can overcome these dilemmas. SERS offers advantages over chromatographic mass spectrometry analysis due to its portability, non-destructive nature, and lower cost implications. However, as it currently stands, Raman spectroscopy is a supplemental tool in chemical analysis, reinforcing and enhancing the completeness and coverage of the food safety analysis system. SERS combines portability with non-destructive and cheaper detection costs to gain an advantage over chromatographic mass spectrometry analysis. 
  • 1.5K
  • 10 Jul 2023
Topic Review
Hydrodynamics on Microbial Adhesion and Biofilm Formation
Studying microbial adhesion and biofilm growth is crucial for understanding the physiology of sessile organisms and forming the basis for the development of novel antimicrobial materials. Fluid hydrodynamics is one of the most important factors affecting cell adhesion, as well as biofilm structure and behavior. Therefore, to simulate the relevant biofilms of different fields (environment, industry, and medicine) in the laboratory, it is of utmost importance to select an adequate biofilm platform and be able to operate it at hydrodynamic conditions that are as close as possible to those encountered in a real scenario.
  • 1.5K
  • 21 Oct 2021
Topic Review
RDF Fire Hazards Mitigation
Experience has shown that power station conversions to a new fuel using the same materials handling methods and equipment, designed for the previous or original intended fuel, without a proper fire engineering re-evaluation of plant suitability (for the properties and behaviors of the new fuel) is not a safe option. Many times, the detection and suppression equipment is presumed adequate, whereas a complete technical evaluation is required. Given that RDF fires are extremely difficult to extinguish it should be remembered that fires could last for days or even weeks. Additionally, given the correct circumstances, the effluent from RDF smoldering fires within a pile can lead to explosion(s), possibly causing severe injuries and even the loss of life. In addition, there are also business considerations due to the subsequent severe interruptions, not forgetting the importance of the security of electricity supply. The difficulties of RDF fire hazards mitigation begin with the notoriously problematic factor of discovery of a fire within the storage pile; they then, more often than not, continue throughout the entire fire-fighting operations process.
  • 1.5K
  • 23 Nov 2021
Topic Review
Microalgae for Wastewater Treatment
The water resource crisis and concerns with environmental pollution prompt the necessity to upgrade conventional wastewater treatment processes. The microalgae-based wastewater treatment process has shown many advantages that can fulfill the stricter demands for improved wastewater treatment. Microalgae cultivation can be carried out in different photobioreactors and under different operational conditions. The cultivation of the microalgae biomass provides the bioremediation of some targeted pollutants through uptake/digestion or biosorption, resulting in treated effluent and the production of biomass.
  • 1.5K
  • 10 Apr 2023
Topic Review
Magneto-Fluorescent Nanoparticles
Novel nanomaterials are of interest in biology, medicine, and imaging applications. Multimodal fluorescent-magnetic nanoparticles demand special attention because they have the potential to be employed as diagnostic and medication-delivery tools, which, in turn, might make it easier to diagnose and treat cancer, as well as a wide variety of other disorders. 
  • 1.5K
  • 20 Apr 2023
Topic Review
Leaching Chalcocite in Chloride Media
Chalcocite is the most abundant secondary copper sulfide globally, with the highest copper content, and is easily treated by conventional hydrometallurgical processes, making it a very profitable mineral for extraction. Among the various leaching processes to treat chalcocite, chloride media show better results and have a greater industrial boom. Chalcocite dissolution is a two-stage process, the second being much slower than the first. During the second stage, in the first instance, it is possible to oxidize the covellite in a wide range of chloride concentrations or redox potentials (up to 75% extraction of Cu). Subsequently, CuS2 is formed, which is to be oxidized. It is necessary to work at high concentrations of chloride (>2.5 mol/L) and/or increase the temperature to reach a redox potential of over 650 mV, which in turn decreases the thickness of the elemental sulfur layer on the mineral surface, facilitating chloride ions to generate a better porosity of this. 
  • 1.5K
  • 10 Nov 2021
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