On average, houses including those in the tropics are responsible for almost 39% of the global carbon emission caused by non-renewables, first and foremost by fuel. Looking at the worldwide map of residential buildings’ contribution compared with commercial, the worldwide national maximum of 33.5% CO₂ of housing is caused by residential buildings in Uzbekistan. In an overwhelming number of most countries, their values are significantly lower, due to comparably lower energy demand than commercial buildings and because affordable homes increasingly use small PV to cater for their own basic needs. However, with the rising temperature and a likewise growing imperative to cool homes from about 30 °C onwards basically by split-unit air conditioners, the residential houses’ portion of CO₂-emission might dramatically increase to survive such more common hot periods in the future. In combination with air conditioners needing some airtightness, the first purpose of this entry is to show that by 2050 in tropical regions, there will be no alternative to relatively airtight houses if the temperatures rise at the present speed. This is one alternative to an uncontrollable and life-threatening migration of millions of people to cooler but still livable regions in 2050. To trigger necessary changes toward homes that can better avert the heat, using the method of qualitative comparative content analysis, passive houses (PH) have emerged as adaptations to the tropical climate. Therefore, the second purpose of this in-depth study with the perspective of social science, is to reveal a comparative closer qualitative look at the tropicalized PH-approach. It is probably the most civilized building energy-saving strategy on the planet and can systematically keep the threatening increasing heat outside. However, before utilizing the concept, herein need to investigate why PH-technology as a whole concept with all its modules discussed earlier has been very slow to “go South” into the tropical region (the original PH will be referred to as “PH1”). The reason is that some qualitative differences of the more affordable and more simplistic tropicalized “PH2” make it easier and more realistic to penetrate the market, without letting go meaningful R&D-insights of PH1. As a probably facilitating future solution, the result is the triple-tabled option to utilise more synergies between the usually closed PH1 and the more open and flexibly naturally ventilated PH2. Unlike the PH-platform, ZEMCH is a related concept which tries to cater specifically to the significantly growing market for lower-income homes to go for carbonless energy. The conclusion is that scaling for residential buildings as mass products using passive house technology in combination with ZEMCH could turn out to become an important topic. It comprises the question in how far low or no carbon affordable homes based on the PH-concept in combination with ZEMCH-applications also may come into play as standard and to help mother Earth’s struggle for survival.

The present overview concentrates on recent developments of tautomerism of β-diketones and β-thioxoketones, both in solution and in the solid state. In particular, the latter has been a matter of debate and unresolved problems. Measurements of ¹³C, ¹⁷O, and ²H chemical shifts have been used. Deuterium isotope effects on chemical shifts are proposed as a tool in the study of this problem. Photoconversion of β-diketones and β-thioxoketones are discussed in detail, and the incorporation of β-diketones into molecules with fluorescent properties is assessed. Finally, docking studies of β-diketones are scrutinized with an emphasis on correct tautomeric structures and knowledge about barriers to interconversion of tautomers.

A sewer system is an important infrastructure of every settlement. A sewer system is a set of construction facilities used for the quick removal of wastewater from the humans’ immediate environment and its transport to a wastewater treatment plant or direct discharge into an appropriate recipient. In order for the sewer system to perform its purpose properly, its proper maintenance is required. Maintenance of a sewer system is very demanding since the system is mostly underground which makes it difficult to be accessed and maintained. The maintenance of a sewer system can be preventive (regular) or corrective (reactive). The regular maintenance occurs at certain intervals, whereas the reactive maintenance occurs in the case of some unforeseen event. This paper presents the history of sewer systems, as well as basic and alternative types of sewer systems. Furthermore, challenges that arise during sewer system maintenance and difficulties that maintenance employees face in their work are presented in this paper, as well as the ways in which sewer systems are maintained.