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Topic Review
Sodium-Vanadium Bronze Na9V14O35
Na9V14O35 (η-NaxV2O5) has been synthesized by a solid-state route in an evacuated sealed silica tube and tested as electroactive material for Na half-cells. Being charged to 4.6 V vs. Na+/Na, almost 3 Na can be extracted per Na9V14O35 formula unit, resulting in a charge capacity of about 60 mAh g−1. Upon discharge below 1 V, Na9V14O35 uptakes Na up to the Na:V = 1:1 atomic ratio that is accompanied by a drastic increase of the separation between the layers of the VO4 tetrahedra and VO5 tetragonal pyramids, and a volume increase of about 31%. The induced structure instability triggers a transformation of the ordered layered Na9V14O35 structure into a rock-salt type disordered structure. Ultimately, the amorphous products of a conversion reaction are formed at 0.1 V, delivering the discharge capacity up to 490 mAh g−1, which, however, quickly fades with the number of charge-discharge cycles.
  • 1.1K
  • 11 Jan 2022
Topic Review
Nanocarbon-Iridium Oxide Nanostructured Hybrids
Nanostructuring nanocarbons with IrOx yields to material coatings with large charge capacities for neural electrostimulation, and large reproducibility in time, that carbons do not exhibit.
  • 1.1K
  • 21 Jul 2021
Topic Review
Electrodeposition of Iron Selenide
Metal selenide materials have attracted attention due to their wide application prospects. In this family of materials, FeSe is particularly studied since it is both a semiconductor used in solar cells and a superconductor with a critical transition temperature, Tc, of 8 K. For any envisaged application, the possibility of preparing large-area FeSe thin films at low cost is extremely appealing, and one possible technique suitable for this purpose is electrodeposition. Several groups have reported successful electrodeposition of FeSe, but the investigated systems are different in many aspects, and the results are difficult to compare.
  • 1.1K
  • 20 Nov 2023
Topic Review
Biomedical Applications of Chitosan
Chitosan, a biocompatible and biodegradable polysaccharide derived from chitin, has surfaced as a material of promise for drug delivery and biomedical applications. Different chitin and chitosan extraction techniques can produce materials with unique properties, which can be further modified to enhance their bioactivities. Chitosan-based drug delivery systems have been developed for various routes of administration, including oral, ophthalmic, transdermal, nasal, and vaginal, allowing for targeted and sustained release of drugs. Additionally, chitosan has been used in numerous biomedical applications, such as bone regeneration, cartilage tissue regeneration, cardiac tissue regeneration, corneal regeneration, periodontal tissue regeneration, and wound healing. Moreover, chitosan has also been utilized in gene delivery, bioimaging, vaccination, and cosmeceutical applications. Modified chitosan derivatives have been developed to improve their biocompatibility and enhance their properties, resulting in innovative materials with promising potentials in various biomedical applications.
  • 1.1K
  • 05 Jul 2023
Topic Review
MS Combined with EAOPs
Membrane separation (MS) and electrochemical advanced oxidation process (EAOPs) are the important technologies in water pollution control. They can not only effectively remove pollutants in water, but also have the advantages of environmental friendliness, easy automation and low land occupation. However, both MS and EAOPs still have some problems to overcome, namely membrane fouling and high energy consumption. In recent years, many researchers proposed that the combination of the two technologies can overcome this problem. In this case, both of them can be used as a pretreatment for the other to achieve different purposes. When MS is prior to EAOPs, the purpose is to reduce the turbidity as well as to concentrate pollutants and salinity in order to weaken the mass transfer limitation and increase the conductivity. When setting MS after EAOPs, the purpose is to treat the concentrate to meet the discharge standard or permeate water to further improve the quality for reuse. The combination of MS and EAOPs offers a valuable way to implement them in the practical project of wastewater treatment which deserves more attention.
  • 1.1K
  • 20 Nov 2020
Topic Review
Halogen Hybrid Flow Batteries
Among the most effective energy systems for stationary applications, a special place is occupied by redox flow battery (RFB) technology, encompassing easy scalability with independent scaling of power density and energy capacity, no detrimental effects of a deep discharge, very low self-discharge, low cost for a large system compared to other types of batteries, and long cycle life.
  • 1.1K
  • 31 Oct 2022
Topic Review
Electrode Materials in Hybrid Supercapacitors
Energy storage systems are of great importance in daily life due to our dependence on portable electronic devices and hybrid electric vehicles. Among these energy storage systems, hybrid supercapacitor devices, constructed from a battery-type positive electrode and a capacitor-type negative electrode, have attracted widespread interest due to their potential applications. In general, they have a high energy density, a long cycling life, high safety, and environmental friendliness.
  • 1.1K
  • 18 Sep 2023
Topic Review
Pharmaceuticals Removal from Water
Pharmaceuticals (PhCs) hold a special place since their presence even at low concentrations can cause irreversible damage to the ecosystem and human health. PhCs can be divided into various categories concerning their characteristics such as anti-inflammatory (e.g., diclofenac), antiepileptic (e.g., carbamazepine), stimulant (e.g., caffeine), β-blockers (e.g., propranolol), antibiotics (sulfamethoxazole), psychiatric (e.g., venlafaxine), antimicrobials (e.g., triclosan), etc.
  • 1.0K
  • 10 Sep 2021
Topic Review
Mesoporous Carbon in PEMFC Catalysts
Developing durable oxygen reduction reaction (ORR) electrocatalysts is essential to step up the large-scale applications of proton exchange membrane fuel cells (PEMFCs). Traditional ORR electrocatalysts provide satisfactory activity, yet their poor durability limits the long-term applications of PEMFCs. Porous carbon used as catalyst support in Pt/C is vulnerable to oxidation under high potential conditions, leading to Pt nanoparticle dissolution and carbon corrosion.
  • 1.0K
  • 14 Mar 2024
Topic Review
Surfactants as Performance-Enhancing Additives in Supercapacitor Electrolyte Solutions
Wetting the surface area of an electrode material as completely as possible is desirable to achieve optimum specific capacity of an electrode material. Keeping this surface area utilized even at high current densities and even when inside small pores is required for high capacitance retention. The addition of surfactants at small concentrations to aqueous supercapacitor electrolyte solutions has been suggested as a way to improve performance in terms of capacitance, capacitance retention at increased current density and stability. Effects are pronounced with carbon materials used in electrochemical double-layer capacitors; they are also observed with redox materials. 
  • 1.0K
  • 29 Jan 2024
Topic Review
Chemically Modified Electrodes for the Detection of Antidepressants
Major depressive disorder is a widespread condition with antidepressants as the main pharmacological treatment. However, some patients experience concerning adverse reactions or have an inadequate response to treatment. Analytical chromatographic techniques, among other techniques, are valuable tools for investigating medication complications, including those associated with antidepressants. Nevertheless, there is a growing need to address the limitations associated with these techniques. In recent years, electrochemical (bio)sensors have garnered significant attention due to their lower cost, portability, and precision. Electrochemical (bio)sensors can be used for various applications related to depression, such as monitoring the levels of antidepressants in biological and in environmental samples. They can provide accurate and rapid results, which could facilitate personalized treatment and improve patient outcomes.
  • 1.0K
  • 05 Jun 2023
Topic Review
Characterization of Polymeric Coatings
The development of anti-corrosion polymeric coatings has grown exponentially in the fields of material science, chemistry, engineering, and nanotechnology and has prompted the evolution of efficient characterization techniques. Polymeric coatings represent a well-established protection system that provides a barrier between a metallic substrate and the environment. However, the increase in complexity and functionality of these coatings requires high-precision techniques capable of predicting failures and providing smart protection.
  • 1.0K
  • 22 Jun 2022
Topic Review
Applications of Micro-Sized pH Sensors
Monitoring pH changes at the micro/nano scale is essential to gain a fundamental understanding of surface processes. Detection of local pH changes at the electrode/electrolyte interface can be achieved through the use of miniaturized pH sensors. When combined with scanning electrochemical microscopy (SECM), these sensors can provide measurements with high spatial resolution. This article explores the applications of miniaturized pH sensors in biological studies, corrosion science, in energy applications, and environmental research.
  • 1.0K
  • 20 Dec 2022
Topic Review
Application of Biomass Materials in Zinc−Ion Batteries
Aqueous zinc-ion batteries (ZIBs), with large reserves of zinc metal and maturity of production, are a promising alternative to sustainable energy storage. Nevertheless, ZIBs also have many drawbacks, for instance, aqueous solution has poor frost resistance and is prone to side reactions. In addition, zinc dendrites also limit the performance of ZIBs. The deeper development and modification of ZIBs is crucial. Biomass, a green and sustainable resource with complex molecular structure and abundant functional groups, makes it have great application in ZIBs.
  • 1.0K
  • 20 Apr 2023
Topic Review
Metal Oxide Quantum-Dot-g-C3N4 Nanocomposites
Quantum dots and graphitic carbon nitride (g-C3N4) are essential elements in this science. In contrast to quantum dots, which have enormous potential due to their size-dependent bandgap tunability and effective charge carrier production, g-C3N4 has properties like chemical stability and a configurable bandgap that make it a versatile material for photocatalysis.
  • 1.0K
  • 15 Nov 2023
Topic Review
Design and Construction of Enzyme-Based Electrochemical Gas Sensors
The demand for the ubiquitous detection of gases in complex environments is driving the design of highly specific gas sensors for the development of the Internet of Things, such as indoor air quality testing, human exhaled disease detection, monitoring gas emissions, etc. The interaction between analytes and bioreceptors can described as a “lock-and-key”, in which the specific catalysis between enzymes and gas molecules provides a new paradigm for the construction of high-sensitivity and -specificity gas sensors. The electrochemical method has been widely used in gas detection and in the design and construction of enzyme-based electrochemical gas sensors, in which the specificity of an enzyme to a substrate is determined by a specific functional domain or recognition interface, which is the active site of the enzyme that can specifically catalyze the gas reaction, and the electrode–solution interface, where the chemical reaction occurs, respectively. As a result, the engineering design of the enzyme electrode interface is crucial in the process of designing and constructing enzyme-based electrochemical gas sensors.    
  • 992
  • 05 Jan 2024
Topic Review
Applications of Transistor-Based Biochemical Sensors
Transistor-based biochemical sensors feature easy integration with electronic circuits and non-invasive real-time detection. They have been widely used in intelligent wearable devices, electronic skins, and biological analyses and have shown broad application prospects in intelligent medical detection. Field-effect transistor (FET) sensors have high sensitivity, reasonable specificity, rapid response, and portability and provide unique signal amplification during biochemical detection. Organic field-effect transistor (OFET) sensors are lightweight, flexible, foldable, and biocompatible with wearable devices. Organic electrochemical transistor (OECT) sensors convert biological signals in body fluids into electrical signals for artificial intelligence analysis. In addition to biochemical markers in body fluids, electrophysiology indicators such as electrocardiogram (ECG) signals and body temperature can also cause changes in the current or voltage of transistor-based biochemical sensors. When modified with sensitive substances, sensors can detect specific analytes, improve sensitivity, broaden the detection range, and reduce the limit of detection (LoD). 
  • 987
  • 29 May 2023
Topic Review
Application of Carbon Materials for Lithium Metal Batteries
The use of fossil fuels has made invaluable contributions to the development of human society. However, problems such as resource depletion and environmental pollution force human beings to develop new energy systems and adjust the energy structure. New systems such as wind, hydro, solar, and fuel cells are expected to provide clean and sustainable energy for human society. As an effective way to store and transfer energy, electrochemical energy storage has gradually become an indispensable part of the transformation of energy structure. Since the advent of lithium-ion batteries in the 19th century, they have become an irreplaceable energy storage device in various fields.
  • 971
  • 12 Dec 2022
Topic Review
Application of 2D MoS2-Based Nanocomposites
The 2D molybdenum disulfide (MoS2) nanosheets have unique and complementary properties to those of graphene, rendering them ideal electrode materials that could potentially lead to significant benefits in many electrochemical applications. These properties include tunable bandgaps, large surface areas, relatively high electron mobilities, and good optical and catalytic characteristics.
  • 968
  • 24 Jun 2022
Topic Review
Silver Nanoparticles in Sensors for Aquatic Environmental Analysis
With rapidly increasing environmental pollution, there is an urgent need for the development of fast, low-cost, and effective sensing devices for the detection of various organic and inorganic substances. Silver nanoparticles (AgNPs) are well known for their superior optoelectronic and physicochemical properties, and have, therefore, attracted a great deal of interest in the sensor arena. The introduction of AgNPs onto the surface of two-dimensional (2D) structures, incorporation into conductive polymers, or within three-dimensional (3D) nanohybrid architectures is a common strategy to fabricate novel platforms with improved chemical and physical properties for analyte sensing.
  • 963
  • 05 Jun 2023
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