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Topic Review
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Topic Review
Angle-Resolved Photoemission Spectroscopy (ARPES)
Angle-resolved photoemission spectroscopy (ARPES) is a vital technique in which spectra are collected from both the energy and momentum of photoemitted electrons and is indispensable for investigating the electronic band structure of solids.
8.1K
08 Dec 2020
Topic Review
Inelastic Neutron Scattering
Inelastic neutron scattering (INS) is a spectroscopy based on the energy analysis of neutrons after they have been scattered by a sample. A detected energy transfer can be related to a physical interaction of the corresponding atoms with their environment. An energy transfer of several meVs typically arises from vibrations of atoms. Thus, INS provides an amplitude-of-motion and neutron incoherent cross section weighted phonon density of states. Given the much higher incoherent scattering cross section of hydrogen relative to that of all other elements, INS is particular sensitive to hydrogen based vibrations. The method is widely used in condensed matter physics and solid state chemistry, because the vibrational properties of matter define various physical properties such as the heat capacity. If used as a fingerprint method, INS can be used to characterize chemical bonds both in the bulk as well as on the surface.
7.8K
30 Oct 2020
Topic Review
Materials Science, Glasses
Glasses are solid amorphous materials which transform into liquids upon heating through the glass transition. The International Commission on Glass defines glass as a state of matter, usually produced when a viscous molten material is cooled rapidly to below its glass transition temperature, with insufficient time for a regular crystal lattice to form. The solid-like behaviour of glasses is separated from the liquid-like behaviour at higher temperatures by the glass transition temperature, Tg. The IUPAC Compendium on Chemical Terminology defines glass transition as a second order transition in which a supercooled melt yields, on cooling, a glassy structure. It states that below the glass-transition temperature the physical properties of glasses vary in a manner similar to those of the crystalline phase. Moreover, it is deemed that the bonding structure of glasses has the same symmetry signature in terms of Hausdorff-Besikovitch dimensionality of chemical bonds as for the crystalline materials.
3.9K
09 May 2024
Topic Review
Boron-Doped Diamond
Boron-doped diamond (BDD) acts as an excellent p-type conductive material for high-temperature, high-power and radiation-proof photoelectronic devices with its large band gap at room temperature (5.47 eV) and high thermal conductivity.
2.7K
06 Jan 2021
Topic Review
Liquid Crystal Aided Nanotechnology/Nanoscience
The research field of liquid crystals and their applications is recently changing from being largely focused on display applications and optical shutter elements in various fields, to quite novel and diverse applications in the area of nanotechnology and nanoscience. Functional nanoparticles, such as ferroelectric and magnetic particles, have recently been used to a significant extent to modify the physical properties of liquid crystals. Also, intriguing photonic functionalities can be realized by adding nanoparticles such as quantum dots, metal particles, semiconductors, etc. into liquid crystals. The self-organization of liquid crystal molecules is exploited to used as order templates to orient nanoparticles. Similarly, anisodiametric nanoparticles such as rods, nanotubes and flakes are shown to form lyotropic liquid crystal phases in the presence of isotropic host solvents at a certain concentration.
2.4K
27 Oct 2020
Topic Review
N-Type Organic Semiconductors
This work was intended to enlarge the gates toward green organic technologies at room temperature, searching for new types of semiconductors with low toxicity and simple molecular organization. In our previous studies, para-aminobenzoic acid was used to construct a p-type green semiconductor. A non-toxic organic compound, acting as an electron donor, is sulpho-salicylic acid. SSA can be efficiently attached to the external shell of a ferrite (Fe3O4) nanocore, providing Fe3O4–SSA nanoparticles. This is a N-Type Organic Semiconductor - made by green technologies and used to construct a simple thin film transistor.
1.6K
22 Oct 2020
Topic Review
Ferroelastic Twinning in Minerals
Ferroelastic twinning in minerals is a very common phenomenon. The twin laws follow simple symmetry rules and they are observed in minerals, like feldspar, palmierite, leucite, perovskite, and so forth. The major discovery over the last two decades was that the thin areas between the twins yield characteristic physical and chemical properties, but not the twins themselves. Research greatly focusses on these twin walls (or ‘twin boundaries’); therefore, because they possess different crystal structures and generate a large variety of ‘emerging’ properties. Research on wall properties has largely overshadowed research on twin domains.
1.6K
15 Jun 2021
Topic Review
Cryotropic Gelation and Macroporous Scaffolds
Cryogels obtained by the cryotropic gelation process are macroporous hydrogels with a well-developed system of interconnected pores and shape memory. Biodegradable cryogels have been prepared from natural polymers (biopolymers) and synthetic polymers with biodegradable/bioresponsive bonds containing bio-resembling or artificial units. The cryogels could be composed of one type of polymer or a combination of different materials. Polymers from natural origins (plants or animals) attract considerable attention for their intrinsic biocompatibility and potential ability to mimic ECM, favoring cell-matrix interactions for tissue-engineering and regeneration.
1.4K
12 Jul 2021
Topic Review
Optical Properties of Plasmonic Metal Nanoparticles
Plasmonic phenomena and materials have been extensively investigated for a long time and gained popularity in the last few years, finding in the design of the biosensors platforms promising applications offering devices with excellent performances. Hybrid systems composed of graphene, or other 2D materials, and plasmonic metal nanostructures present extraordinary optical properties originated from the synergic connection between plasmonic optical effects and the unusual physicochemical properties of 2D materials, thus improving their application in a broad range of fields.
1.3K
08 Jul 2022
Topic Review
Low-Frequency Plasma-Enhanced Chemical Vapor Deposition (LFPECVD)
The low-frequency plasma-enhanced chemical vapor deposition in cyclohexane atmospheres is an easy-to-implement technology for carbon-based coatings deposition. LFPECVD (like RF PECVD), which has the capacity to be implemented in any scale, is widely used in industry.
1.3K
21 Oct 2021
Topic Review
Spins in Semiconductor Nanoparticles
- Spin-dependent phenomena in semiconductors are analyzed starting from a theory of the dynamic nuclear polarization via numerous insightful findings in the realm of characterization and control through the nuclear spin polarization in nanoparticles and their aggregates into microparticles as potential contrast agents for magnetic resonance imaging (MRI) applications. - Electron spin-dependent process of the photosensitized generation of singlet oxygen in porous silicon (Si) for photodynamic therapy application and design of Si-based nanoparticles with electron spin centers for MRI contrasting for cancer theranostics are discussed.
1.3K
12 Jan 2021
Topic Review
Lipid Bilayers on Silicon Substrates
Artificial membranes are models for biological systems that are important for several applications. In the present entry we talk about artificial membranes such as supported lipid bilayers (SLB) and ways to self- assemble them. We mainly focus on the results of a new dry evaporation process in high vacuum, i.e., physical vapor deposition, to make samples of dipalmitoylphosphatidylcholine (DPPC) on silicon substrates. We have characterized the main phase transitions and adhesion of our SLBs using high-resolution ellipsometry and AFM techniques. The finding of this new SLB fabrication approach is relevant for the understanding the interaction of lipid bilayers in contact with surfaces in dry environments, with the aim to develop new kinds of lab-on-chip bionanosensors. This discovery is especially relevant in the context of the viability of organisms covered with lipid bilayer structures. An example of this kind of interaction occurs between bilayer-protected viruses, e.g., corona viruses, and solid surfaces, allowing the virus to stay active during long periods of time. The prolonged stability of SLBs on dry SiO2/Si substrates detected in our research can explain the long-term stability of some viruses deposited or adsorbed on dry surfaces, including the SARS-CoV-2 virus.
1.2K
03 Nov 2020
Topic Review
Cellulose and Microfluidics
Cellulose, a linear polysaccharide, is the most common and renewable biopolymer in nature.
1.2K
10 Feb 2022
Topic Review
Calculation of the transition temperature of superconducting elements
Using the Roeser-Huber formalism, we establish a non-trivial relation between the crystal structure and the transition temperature, Tc, to the superconducting state. By means of this relation, we can calculate Tc for practically all superconducting elements quite accurately within a small error margin. It is shown that this works well also for polymorphic elements and elements under pressure. Furthermore, the Roeser-Huber formalism implies that all calculated data fall on a common line with the slope m1 = h2/(2πkB) = 5.061 × 10−45 m2 kg K, when plotting log(Σ((2x)-2n1-1ML-1))-1 versus 1/Tc, which can be employed as a test when predicting Tc of unknown superconductors.
1.2K
21 Jun 2023
Topic Review
Ferromagnetic
Ferromagnetism is a phenomenon whereby a substance can become a permanent magnet or strongly reacts to a magnetic field.
1.1K
27 Apr 2022
Topic Review
Direct Ultrafast Laser Processing
Direct ultrafast laser processing is nowadays considered the most flexible technique allowing to generate complex 3D optical functions in bulk glasses. The fact that the built-in optical element is embedded in the material brings several advantages in terms of prototype stability and lifetime, but equally in terms of complexity and number of possible applications, due to the 3D design. The generated optical functions, and in particular the single mode character of the light guiding element alongside the accessibility toward different spectral windows, depend on the refractive index contrast that can be achieved within the material transparency window and on the characteristic dimensions of the optical modification. In particular, the accessibility to the infrared and mid-infrared spectral domains, and to the relevant applications in sensing and imaging, requires increasing the cross-section of the guiding element in order to obtain the desired normalized frequency. Moreover, efficient signal extraction from the transported light requires nanometer size void-like index structures. All this demands a thorough knowledge and an optimal control of the material response within the interaction with the ultrafast laser pulse.
1.0K
25 Jun 2021
Topic Review
Rigid Templates for Fabricating 3D Nanostructures
Rigid templates are defined as opposed to soft templates, and are made of hard materials. Rigid templates have good chemical stability and mechanical rigidity, which are mostly used for the fabrication of nanostructure arrays. A wide choice of rigid templates is available, such as silicon, anodic aluminum oxide, carbon, silica spheres, biological structures, and so forth.
981
14 Jun 2022
Topic Review
Quantification of 5f Delocalization
By using M4,5 X-ray Emission Spectroscopy (XES) in the tender X-ray regime, it is possible to quantify 5f delocalization in the actinides. Previous analyses, utilizing the Branching Ratio (BR) in the N4,5 X-ray Absorption Spectroscopy (XAS), could not discriminate between the cases of localized n = 2 and delocalized n = 3, in uranium materials, where n is the number of 5f electrons on the U entity. Here, it is shown that, by employing the ubiquitous 6p→3d XES as a point of normalization, the localized n = 2 and delocalized n = 3 cases can be easily distinguished and quantified.
945
29 Oct 2020
Topic Review
Ramchandra Pode
I am involved in the field of organic light emitting devices since 2002. I also worked as visiting Scientist at Korea Electronics Technology Institute, South Korea in 2003 and 2005 (Brain Pool, KOFST) on OLEDs devices. I am specialized in Organic Light Emitting Diode (OLEDs) devices and displays and acquired enough expertize to conduct the research project on OLEDs. During these years, I have published around 65 research articles in various SCI journals of repute. In addition, I have contributed chapters to two books on OLEDs.
930
28 Oct 2020
Topic Review
Thermal Diffusivity and Mechanical Properties of Wood
A dependence of Brinell hardness and thermal diffusivity tensor components upon humidity for common pine wood is found. The results of the measurement of Brinell hardness, microhardness, Young’s modulus, and main components of thermal diffusivity tensor for three perpendicular cuts are found to be correlated. It is shown that the mechanical properties correlate better with the ratio of longitude to transversal thermal diffusivity coefficients than with the respective individual absolute values. The mechanical characteristics with the highest correlation with the abovementioned ratio are found to be the ratio of Young’s moduli in longitude and transversal directions.
885
17 Feb 2022
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