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Topic Review
Biography
Topic Review
Bio-Inspired Hierarchical Fibres
Several naturally occurring biological systems, such as bones, nacre or wood, display hierarchical architectures with a central role of the nanostructuration that allows reaching amazing properties such as high strength and toughness. Developing such architectures in man-made materials is highly challenging, and recent research relies on this concept of hierarchical structures to design high-performance composite materials. This review deals more specifically with the development of hierarchical fibres by the deposition of nano-objects at their surface to tailor the fibre/matrix interphase in (bio)composites. Fully synthetic hierarchical fibre reinforced composites are described, and the potential of hierarchical fibres is discussed for the development of sustainable biocomposite materials with enhanced structural performance. Based on various surface, microstructural and mechanical characterizations, this review highlights that nano-objects coated on natural fibres (carbonnanotubes, ZnO nanowires, nanocelluloses) can improve the load transfer and interfacial adhesion between the matrix and the fibres, and the resulting mechanical performances of biocomposites. Indeed, the surface topography of the fibres is modified with higher roughness and specific surface area, implying increased mechanical interlocking with the matrix. As a result, the interfacial shear strength (IFSS) between fibres and polymer matrices is enhanced, and failure mechanisms can bemodified with a crack propagation occurring through a zig-zag path along interphases.
1.0K
29 May 2021
Topic Review
Antimicrobial Polymeric Structures
Certain natural and synthetic polymers are versatile materials that have already proved themselves to be highly suitable for the development of the next-generation of antimicrobial systems that can efficiently prevent and kill microbes in various environments.
721
28 May 2021
Topic Review
Polymeric Pipeline Coatings Time-Dependent Performance
The barrier performance of organic coatings is a direct function of mass transport and long-term stability of the polymeric structure. A predictive assessment of the protective coating cannot be conducted a priori of degradation effects on transport. Epoxy-based powder coatings are an attractive class of coatings for pipelines and other structures because application processing times are low and residual stresses between polymer layers are reduced.
858
27 May 2021
Topic Review
ABC-Type Linear Triblock Terpolymers
This entry aims to cover the most recent advances regarding the synthesis of linear ABC-type triblock terpolymers by RAFT polymerization, as well as their self-assembly properties in aqueous solutions. RAFT polymerization has received extensive attention, as it is a versatile technique, compatible with a great variety of functional monomers and reaction conditions, while providing exceptional and precise control over the final structure, with well-defined side-groups and post-polymerization engineering potential. Linear triblock terpolymers synthesis can lead to very interesting novel ideas, since there are countless combinations of stimuli/non-stimuli and hydrophilic/hydrophobic monomers that someone can use. One of their most interesting features is their ubiquitous ability to self-assemble in different nanostructures depending on their degree of polymerization (DP), block composition, solubilization protocol, internal and external stimuli.
650
26 May 2021
Topic Review
PET-RAFT
Photoinduced Electron/Energy Transfer Reversible Addition-Fragmentation Chain-Transfer (PET-RAFT) polymerization, proposed for the first time in 2014, is based on an alternative activation of the thiocarbonylthio compounds through photoredox catalysts (PCs). This last presents significant advantages compared to other photochemical techniques in terms of applicability, cost, and sustainability.
2.2K
26 May 2021
Topic Review
Skin Tissue Engineering Application
Skin tissue engineering has made remarkable progress in wound healing treatment with the advent of newer fabrication strategies using natural/synthetic polymers and stem cells. Currently, stem cells and biomaterials are popularly used in the skin tissue engineering approach in different wound healing treatments. In skin tissue engineering application, stem cell facilitates in the regeneration of disintegrated tissue. Whereas, biomaterials serve as a platform to improve the engraftment of implanted cells and facilitate the function of exogenous cells by mimicking the tissue microenvironment. Hence, the combination and synergistic effect of biomaterials and stem cells have the potential to broaden the application of skin tissue engineering in wound healing treatment therapies.
2.2K
19 May 2021
Topic Review
Polyvinylidene Fluoride-Graphene Oxide Membranes
In this study, polyvinylidene fluoride (PVDF)-graphene oxide (GO) membranes were obtained by employing triethyl phosphate (TEP) as a solvent. GO nanosheets were prepared and characterized in terms of scanning and transmission electron microscopy (SEM and TEM, respectively), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), chemical analysis and inductively coupled plasma mass spectroscopy (ICP).
481
18 May 2021
Topic Review
Hydrogels in Hand Sanitizers
Hand hygiene can be considered a strategic key useful in the containment of infections such as COVID-19 both at home and in communities because it can dramatically reduce the widespread outbreak of infections.
643
08 May 2021
Topic Review
The Polyethylene Terephthalate
The chemical recycling of PET is reviewed, such as pyrolysis, hydrolysis, methanolysis, glycolysis, ionic-liquid, phase-transfer catalysis and combination of glycolysis–hydrolysis, glycolysis–methanolysis and methanolysis–hydrolysis.
1.6K
08 May 2021
Topic Review
PEDOT-based Catalytic Counter Electrode Material
Dye-sensitized solar cells (DSSCs) emerged in the early 1990s as a promising alternative to the classic silicon-based solar cell due to their unique combination of low cost, ease of fabrication, color palette for building integration, and high efficiency in indoor applications.
590
08 May 2021
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