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Topic Review
Biography
Peer Reviewed Entry
Video Entry
Topic Review
Woven Natural Fibre Polymer Composites
These woven materials are flexible, able to be tailored to the specific needs and have better mechanical properties due to their weaving structures.
2.1K
03 Mar 2021
Topic Review
Alkylimidazoles
Alkylimidazoles have good complexing properties, also they are cheap so can be successfully used in the separation of metal ions from aqueous solutions.
2.1K
16 Dec 2020
Topic Review
Fluorescent Polymers Conspectus
The development of luminescent materials is critical to humankind. The Nobel Prizes awarded in 2008 and 2010 for research on the development of green fluorescent proteins and super-resolved fluorescence imaging are proof of this (2014). Fluorescent probes, smart polymer machines, fluorescent chemosensors, fluorescence molecular thermometers, fluorescent imaging, drug delivery carriers, and other applications make fluorescent polymers (FPs) exciting materials.
2.0K
22 Mar 2022
Topic Review
Polylactic Acid for Single-Use Laboratory Components
Sustainability needs have driven interest in polymers which are degradable, recyclable, and/or derived from eco-friendly input materials. Biomass-based polymers are one option with many benefits to sustainability: reducing dependence on fossil fuel extraction; produced from renewable resources; may make use of waste materials; and better biodegradability. Polylactic Acid (PLA) is one of the most commonly used bioplastics, in 2021 it was reported to hold the largest market share worldwidefor biodegradable bioplastics manufacturing capacity.
2.0K
06 May 2022
Topic Review
Terpenes and Terpenoids for Bioplastics
This entry describes the most common types of bioplastics and biopolymers, and focuses specifically on the polymerization of terpenes and terpenoids, which represent a source of promising monomers to create bio-based polymers and copolymers.
2.0K
25 Aug 2021
Topic Review
Plasticized Polyvinyl Chloride
Plasticized polyvinyl chloride (p-PVC)—widely present in modern and contemporary art collections as objects, clothing and footwear, furniture and upholstery, and housewares and toys—is known to deteriorate very rapidly in museum collections. The tendency of colorless p-PVC-based objects to yellowing-browning in combination with stickiness and cracking are the main issues of this important plastic material, which require the attention of conservation scientists in cooperation with conservators, engineers, curators, and art historians.
2.0K
19 Dec 2023
Topic Review
Polyetheretherketone
Polyetheretherketone (PEEK) is an aromatic, semi-crystalline linear thermoplastic polymer.
2.0K
18 Mar 2021
Topic Review
Lignin-Based Resins
By increasing the environmental concerns and depletion of petroleum resources, bio-based resins have gained interest. Recently, lignin-based resins have attracted attention due to their low cost, environmental benefits, good thermal stability, excellent mechanical properties, and suitability for high-performance natural fiber composite applications. This content highlights the recent use of lignin-based resins with natural fiber composites for high-performance applications.
2.0K
31 Dec 2021
Topic Review
Conducting Poly(Methyl Methacrylate) (PMMA)
Poly(methyl methacrylate), PMMA is a lightweight insulating material that is known for its high Young's Modulus and good optical transmittance properties. Benefiting from these properties, there are recently vast interests to produce conducting PMMA for various applications including electronics, corrosion protective coatings, diodes, sensors, and many more. Conducting PMMA is possible to produce by incorporating conducting polymers such as polyaniline (PANi) by physical blending method or by co-polymerization technique. PANi has been the main choice to incorporate with PMMA due to its good conductivity, better environmental stability, and good redox reversibility. In addition, the limitations of PANi include poor adhesion, low mechanical stability and, limited solubility in most organic solvents can be surpassed by blending or co-polymerizing with thermoplastics such as PMMA.
1.9K
30 Jun 2021
Topic Review
Cellulose-Based Polymers in Additive Manufacturing
The materials for additive manufacturing (AM) technology have grown substantially over the last few years to fulfill industrial needs. Despite that, the use of bio-based composites for improved mechanical properties and biodegradation is still not fully explored. This limits the universal expansion of AM-fabricated products due to the incompatibility of the products made from petroleum-derived resources. The development of naturally-derived polymers for AM materials is promising with the increasing number of studies in recent years owing to their biodegradation and biocompatibility. Cellulose is the most abundant biopolymer that possesses many favorable properties to be incorporated into AM materials, which have been continuously focused on in recent years. This critical review discusses the development of AM technologies and materials, cellulose-based polymers, cellulose-based three-dimensional (3D) printing filaments, liquid deposition modeling of cellulose, and four-dimensional (4D) printing of cellulose-based materials. Cellulose-based AM material applications and the limitations with future developments are also reviewed.
1.9K
02 Sep 2020
Topic Review
Polyurethanes in Biomedicine
Due to their mechanical properties, ranging from flexible to hard materials, polyurethanes (PUs) have been widely used in many industrial and biomedical applications. PU characteristics, along with their biocompatibility, make them successful biomaterials in short and medium time applications. The most important biomedical applications of PUs include antibacterial surfaces and catheters, blood oxygenators, dialysis devices, stents, cardiac valves, vascular prostheses, bioadhesives/surgical dressings/pressure sensitive adhesives, drug delivery systems, tissue engineering scaffolds and electrospinning, nerve generation, pacemaker lead insulation and coatings for breast implants. The diversity of polyurethane properties due to the ease of bulk and surface modification plays a vital role in their applications.
1.9K
28 Oct 2020
Topic Review
Polysiloxane-Based Ionic Polymers
A diverse range of linear polysiloxane-based ionic polymers that are hydrophobic and highly flexible can be obtained by substituting the polymers with varying amounts of ionic centers. The materials can be highly crystalline solids, amorphous soft solids, poly(ionic) liquids or viscous polymer liquids.
1.9K
31 Dec 2020
Topic Review
Carbon Nanotube-Reinforced Polymer Composite
A novel class of carbon nanotube (CNT)-based nanomaterials has been surging since 1991 due to their noticeable mechanical and electrical properties, as well as their good electron transport properties. The development of CNT-reinforced polymer composites could contribute in expanding many areas of use, from energy-related devices to structural components. A CNT is defined as a one-atom thick sheet of graphite rolled into a tube with a diameter of one nanometer, which is classified as a single-wall carbon nanotube (SWCNT); if there are additional or multiple graphene tubes around the core of an SWCNT, this is known as a multiwalled carbon nanotube (MWCNT). Theoretical and experimental results on CNTs have showed a high modulus of elasticity: greater than 1 TPa (the elastic modulus of diamond is 1.2 TPa). In addition, CNTs also possess a strength that is 10–100 times higher than the resilient steel at a fraction of the weight. Additionally, CNTs have an excellent thermal stability of up to 2800 ◦C in vacuum and an electrical conductivity in the vicinity of 103 S/cm, with an electric-current-carrying capacity that is 1000 times higher and thermal conductivity of about 1900 W m−1 K−1 (which is about twice as high as diamond). SWCNTs in a hexagonal honeycomb structure consist of sp2 hybridized carbon in a that is rolled into a hollow tube morphology, while MWCNTs consist of multiple concentric tubes encircling one another.
1.9K
05 Aug 2021
Topic Review
Assessment of Bio-Based Polyurethanes
Among numerous synthetic macromolecules, polyurethane in its different forms has proven its sheer dominance and established a reputation as a reliable and trusted material due to its proficiency in terms of superior properties, which include: high mechanical strength and abrasion resistance, good durability, good adhesion, good thermal stability, excellent chemical and weathering resistance. Synthetic polyurethane materials are non-biodegradable, poisonous, and use petrochemical-based raw materials, which are now depleting, leading to a surge in polyurethane production costs. Enormous kinds of available bio-renewable sources as predecessors for the production of polyols and isocyanates have been explored for the development of “greener” PU materials; these bio-based polyurethanes have significant potential to be used as future PU products, with a partial or total replacement of petroleum-based polyurethanes, due to increasing concern about the environment, their relatively low cost and biodegradability.
1.9K
12 Aug 2022
Topic Review
Bacterial Biopolymer
Biopolymers are polymers being synthesized by living organisms with the help of enzymes that connects the building blocks like sugars, hydroxyl fatty acids, and amino acids to produce molecules with high molecular weight.
1.9K
30 Apr 2021
Topic Review
Spinning of Biopolymer Fibers
Increasing interest in bio-based polymers and fibers has led to the development of several alternatives to conventional plastics and fibers made of these materials. Biopolymer fibers can be made from renewable, environmentally friendly resources and can be fully biodegradable. Biogenic resources with a high content of carbohydrates such as starch-containing plants have huge potentials to substitute conventional synthetic plastics in a number of applications.
1.9K
06 May 2021
Topic Review
Antimicrobial Polymers
Antibiotic resistance has increased markedly in Gram-negative bacteria, causing severe infections intractable with traditional drugs and amplifying mortality and healthcare costs. Consequently, to find novel antimicrobial compounds, active on multidrug resistant bacteria, is mandatory. In this regard, cationic antimicrobial peptides (CAMPs)—able to kill pathogens on contact—could represent an appealing solution. However, low selectivity, hemolytic toxicity and cost of manufacturing, hamper their massive clinical application. In the recent years—starting from CAMPs as template molecules—less toxic and lower-cost synthetic mimics of CAMPs, including cationic peptides, polymers and dendrimers, have been developed. Although the pending issue of hemolytic toxicity and biodegradability is still left not completely solved, cationic antimicrobial polymers (CAPs), compared to small drug molecules, thanks to their high molecular weight, own appreciable selectivity, reduced toxicity toward eukaryotic cells, more long-term activity, stability and non-volatility. With this background, an updated overview concerning the state of the art of the main manufactured types of CAPs, active on Gram-negative bacteria, is herein reported, including synthetic procedure and action’s mechanism. Information about the antibacterial activity, advantages and drawbacks of the most appealing compounds was also provided.
1.8K
12 Jan 2021
Topic Review
Interfacial Polymerization Techniques for TFC/TFN
Here, we review various novel/modified interfacial polymerization (IP) techniques for the fabrication of polyamide (PA) thin film composite (TFC)/thin film nanocomposite (TFN) membranes in both pressure-driven and osmotically driven separation processes. Although conventional IP technique is the dominant technology for the fabrication of commercial nanofiltration (NF) and reverse osmosis (RO) membranes, it is plagued with issues of low membrane permeability, relatively thick PA layer and susceptibility to fouling, which limit the performance. Over the past decade, we have seen a significant growth in scientific publications related to the novel/modified IP techniques used in fabricating advanced PA-TFC/TFN membranes for various water applications. Novel/modified IP lab-scale studies have consistently, so far, yielded promising results compared to membranes made by conventional IP technique, in terms of better filtration efficiency (increased permeability without compensating solute rejection), improved chemical properties (crosslinking degree), reduced surface roughness and the perfect embedment of nanomaterials within selective layers. Furthermore, several new IP techniques can precisely control the thickness of the PA layer at sub-10 nm and significantly reduce the usage of chemicals.
1.8K
09 Mar 2021
Topic Review
N,N-Dimethylacrylamide-Based Hydrogels
N,N-dimethylacrylamide produces hydrogel when polymerized with cross-linkers. Moreover, poly(N,N-dimethylacrylamide) has gotten a lot of attention as it is commonly used as the hydrophilic side of copolymers due to its unique properties and high water solubility. In addition, van der Waals interactions between N,N-dimethylacrylamide and dye molecules even more increase the applicability of DMAA hydrogels.
1.8K
03 Dec 2021
Topic Review
Poly(methyl methacrylate) (PMMA)
Poly (methyl methacrylate) (PMMA) is a thermoplastic synthetic polymer, which displays superior characteristics such as transparency, good tensile strength, and processability.
1.8K
29 Jun 2021
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