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Topic Review
Biological Properties of Flavonoids
It has been reported that nutritional phytochemicals present in fruits, vegetables and cereals, such as flavonoid polyphenolic compounds, can improve bone mineral density by several mechanisms, in addition to having beneficial effects on bone homeostasis and health. In addition to their nutritional properties, flavonoids may have applicability in the manufacture of polymers and can be used as stabilizing agents for biopolyesters, such as polylactide (PLA) and polyhydroxyalkanoate (PHA), which have been widely used in tissue engineering for membranes and scaffolds.
  • 3.8K
  • 11 May 2022
Topic Review
Kiev
Kiev or Kyiv (Ukrainian: Київ; Russian: Киев, romanized: Kiyev) is the capital and most populous city of Ukraine . It is in north-central Ukraine along the Dnieper River. Its population in July 2015 was 2,887,974 (though higher estimated numbers have been cited in the press), making Kiev the seventh-most populous city in Europe. Kiev is an important industrial, scientific, educational and cultural center of Eastern Europe. It is home to many high-tech industries, higher education institutions, and historical landmarks. The city has an extensive system of public transport and infrastructure, including the Kiev Metro. The city's name is said to derive from the name of Kyi, one of its four legendary founders. During its history, Kiev, one of the oldest cities in Eastern Europe, passed through several stages of prominence and obscurity. The city probably existed as a commercial center as early as the 5th century. A Slavic settlement on the great trade route between Scandinavia and Constantinople, Kiev was a tributary of the Khazars, until its capture by the Varangians (Vikings) in the mid-9th century. Under Varangian rule, the city became a capital of the Kievan Rus', the first East Slavic state. Completely destroyed during the Mongol invasions in 1240, the city lost most of its influence for the centuries to come. It was a provincial capital of marginal importance in the outskirts of the territories controlled by its powerful neighbours, first Lithuania, then Poland and Russia. The city prospered again during the Russian Empire's Industrial Revolution in the late 19th century. In 1918, after the Ukrainian National Republic declared independence from Soviet Russia, Kiev became its capital. From 1921 onwards Kiev was a city of Soviet Ukraine, which was proclaimed by the Red Army, and, from 1934, Kiev was its capital. The city was almost completely ruined during World War II but quickly recovered in the postwar years, remaining the Soviet Union's third-largest city. Following the collapse of the Soviet Union and Ukrainian independence in 1991, Kiev remained Ukraine's capital and experienced a steady influx of ethnic Ukrainian migrants from other regions of the country. During the country's transformation to a market economy and electoral democracy, Kiev has continued to be Ukraine's largest and wealthiest city. Its armament-dependent industrial output fell after the Soviet collapse, adversely affecting science and technology, but new sectors of the economy such as services and finance facilitated Kiev's growth in salaries and investment, as well as providing continuous funding for the development of housing and urban infrastructure. Kiev emerged as the most pro-Western region of Ukraine; parties advocating tighter integration with the European Union dominate during elections.
  • 3.8K
  • 10 Nov 2022
Topic Review
Verb–Subject–Object
In linguistic typology, a verb–subject–object (VSO) language is one in which the most typical sentences arrange their elements in that order, as in Ate Sam oranges (Sam ate oranges). VSO is the third-most common word order among the world's languages, after SOV (as in Hindi and Japanese) and SVO (as in English and Mandarin). Families where all or many of the languages are VSO include the following: Spanish resembles Semitic languages such as Arabic in allowing for both VSO and SVO structures: "Jesús vino el jueves"/"Vino Jesús el jueves, "Tu madre dice que no vayas"/"Dice tu madre que no vayas". Many languages, such as Greek, have relatively free word order, where VSO is one of many possible orders. Low level programming languages such as assembly tend to follow VSO order in how they assign bits in a memory word. Although the bit sizes vary between architectures, the general form consists of an opcode (verb) followed by a combination of memory or register addresses (subjects) and/or values (objects).
  • 3.8K
  • 04 Nov 2022
Topic Review
Catalyst Design via Colloidal Synthesis
Supported nanoparticles are commonly applied in heterogeneous catalysis. The catalytic performance of these solid catalysts is, for a given support, dependent on the nanoparticle size, shape, and composition, thus necessitating synthesis techniques that allow for preparing these materials with fine control over those properties. Such control can be exploited to deconvolute their effects on the catalyst’s performance, which is the basis for knowledge-driven catalyst design. In this regard, bottom-up synthesis procedures based on colloidal chemistry have proven successful in achieving the desired level of control for a variety of fundamental studies. This article aims to give an overview of recent progress made in this synthesis technique for the application of controlled catalytic materials in gas-phase catalysis. The focus goes to mono- and bimetallic materials, as well as to recent efforts in enhancing their performance by embedding colloidal templates in porous oxide phases.
  • 3.8K
  • 12 May 2021
Topic Review
Contact Lens Materials - A Materials Science Perspective
Contact lens materials are typically based on polymer- or silicone-hydrogel, with additional manufacturing technologies employed to produce the final lens. These processes are simply not enough to meet the increasing demands from CLs and the ever-increasing number of contact lens (CL) users. New materials and engineering offer increasing functionality or improved properties over previous generations.
  • 3.8K
  • 27 Jan 2022
Topic Review
Crosslinking Agent for on Cellulose-Based Hydrogels
Hydrogels are interlinked hydrophilic polymers that are insoluble in water but are capable of absorbing large amounts of water through the swelling process. During the swelling process, the polar groups in the polymer chain swiftly draw the first water molecules into the hydrogel network (bound water). The hydrogel network absorbs more water molecules due to the osmotic pressure of the interstitial water and free water. Both synthetic and natural polymers can be used to create hydrogels. Natural polymer-based hydrogels are typically chosen because of their excellent biocompatibility and biodegradability. In addition, natural polymers are less expensive than synthetic ones.  A crosslinking agent is used to strengthen the properties of the hydrogel. A chemical crosslinking agent is used more often than a physical crosslinking agent. In a chemical crosslinking agent, there are two types of crosslinking agents, which is synthetic and natural crosslinking agents. Hydrogels that utilize synthetic crosslinking agents have advantages, such as adjustable mechanical properties and easy control of the chemical composition. However, hydrogels that use natural crosslinking agents have better biocompatibility and less latent toxic effect.
  • 3.8K
  • 28 Sep 2022
Topic Review
Preconsolidation Pressure
Preconsolidation pressure is the maximum effective vertical overburden stress that a particular soil sample has sustained in the past. This quantity is important in geotechnical engineering, particularly for finding the expected settlement of foundations and embankments. Alternative names for the preconsolidation pressure are preconsolidation stress, pre-compression stress, pre-compaction stress, and preload stress. A soil is called overconsolidated if the current effective stress acting on the soil is less than the historical maximum. The preconsolidation pressure can help determine the largest overburden pressure that can be exerted on a soil without irrecoverable volume change. This type of volume change is important for understanding shrinkage behavior, crack and structure formation and resistance to shearing stresses. Previous stresses and other changes in a soil's history are preserved within the soil's structure. If a soil is loaded beyond this point the soil is unable to sustain the increased load and the structure will break down. This breakdown can cause a number of different things depending on the type of soil and its geologic history. Preconsolidation pressure cannot be measured directly, but can be estimated using a number of different strategies. Samples taken from the field are subjected to a variety of tests, like the constant rate of strain test (CRS) or the incremental loading test (IL). These tests can be costly due to expensive equipment and the long period of time they require. Each sample must be undisturbed and can only undergo one test with satisfactory results. It is important to execute these tests precisely to ensure an accurate resulting plot. There are various methods for determining the preconsolidation pressure from lab data. The data is usually arranged on a semilog plot of the effective stress (frequently represented as σ'vc) versus the void ratio. This graph is commonly called the e log p curve or the consolidation curve.
  • 3.8K
  • 17 Oct 2022
Topic Review
Surface Passivation
Passivation, in physical chemistry and engineering, refers to coating a material so it becomes "passive", that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. In electrochemical treatment of water, passivation reduces the effectiveness of the treatment by increasing the circuit resistance, and active measures are typically used to overcome this effect, the most common being polarity reversal, which results in limited rejection of the fouling layer.[clarification needed] When exposed to air, many metals naturally form a hard, relatively inert surface layer, usually an oxide (termed the "native oxide layer") or a nitride, that serves as a passivation layer. In the case of silver, the dark tarnish is a passivation layer of silver sulfide formed from reaction with environmental hydrogen sulfide. (In contrast, metals such as iron oxidize readily to form a rough porous coating of rust that adheres loosely and sloughs off readily, allowing further oxidation.) The passivation layer of oxide markedly slows further oxidation and corrosion in room-temperature air for aluminium, beryllium, chromium, zinc, titanium, and silicon (a metalloid). The inert surface layer formed by reaction with air has a thickness of about 1.5 nm for silicon, 1–10 nm for beryllium, and 1 nm initially for titanium, growing to 25 nm after several years. Similarly, for aluminium, it grows to about 5 nm after several years. Surface passivation refers to a common semiconductor device fabrication process critical to modern electronics. It is the process by which a semiconductor surface such as silicon is rendered inert, and does not change semiconductor properties when it interacts with air or other materials. This is typically achieved by thermal oxidation, in which the material is heated and exposed to oxygen. In a silicon semiconductor, this process allows electricity to reliably penetrate to the conducting silicon below the surface, and to overcome the surface states that prevent electricity from reaching the semiconducting layer. Surface passivation by thermal oxidation is one of the key features of silicon technology, and is dominant in microelectronics. The surface passivation process was developed by Mohamed M. Atalla at Bell Labs in the late 1950s. It is commonly used to manufacture MOSFETs (metal-oxide-semiconductor field-effect transistors) and silicon integrated circuit chips (with the planar process), and is critical to the semiconductor industry. Surface passivation is also critical to solar cell and carbon quantum dot technologies.
  • 3.8K
  • 22 Nov 2022
Topic Review
Financial Accounting and Sustainability Accounting
A phenomenon in development of accounting knowledge is the generalisation of accounting  principles and concepts from the traditional (financial) domain/context to the sustainability domain/context. This phenomenon draws debates between two schools. Some scholars support the way of simulation, maintaining it is necessary and inevitable for sustainability accounting researchers and practitioners to draw knowledge the financial accounting that has been familiar for them. But some scholars take a critical stance against the simulation, arguing that it is too difficult to apply financial accounting concepts to sustainability practices, for the two accounting contexts are significantly different from each other. But the sustainability accounting application of the materiality concept indicates another side of the phenomenon. That is, sustainability accounting academy should neither give up or discourage the way of generalisation, nor simply and directly simulate the definitions and practices of financial accounting concepts. 
  • 3.8K
  • 29 Oct 2020
Topic Review
Structure and Physiological Activities of Anthocyanins
Anthocyanidin is a kind of water-soluble natural pigment that widely exists in natural plants. Like other natural flavonoids, anthocyanin has a C6-C3-C6 carbon skeleton. Due to the different carbon substituents (-OH, -OCH3) on the B ring, different types of anthocyanins were derived. The six common anthocyanins were Pelargonidin (Pg), Cyanidin (Cy), Delphinidin (Dp), Peonidin (Pn), Petunidin (Pt), and Malvidin (Mv). In addition to giving food a variety of bright colors, anthocyanin also has important biological activities, such as antioxidant, anti-inflammatory, and anti-aging effects, among others. A large number of studies have shown that dietary anthocyanins have a good preventive effect on cardiovascular diseases.
  • 3.8K
  • 01 Aug 2022
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