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Topic Review
Strain
In chemistry, a molecule experiences strain when its chemical structure undergoes some stress which raises its internal energy in comparison to a strain-free reference compound. The internal energy of a molecule consists of all the energy stored within it. A strained molecule has an additional amount of internal energy which an unstrained molecule does not. This extra internal energy, or strain energy, can be likened to a compressed spring. Much like a compressed spring must be held in place to prevent release of its potential energy, a molecule can be held in an energetically unfavorable conformation by the bonds within that molecule. Without the bonds holding the conformation in place, the strain energy would be released.
  • 2.8K
  • 04 Nov 2022
Topic Review
Stone Cultural Heritage Elements
Stones are ones of the most ancient natural materials exploited by humans, with different uses, from tools to buildings, that have endured over time in better conditions than other objects belonging to cultural heritage. Given the importance of those silent witnesses of the past, as well as our duty to preserve all parts of cultural heritage for future generations, much effort was put into the development of materials for their consolidation, protection, self-cleaning, or restoration.
  • 1.2K
  • 20 Sep 2022
Topic Review
Stochastic Microsensors
Two three-dimensional (3D) stochastic microsensors based on immobilization of protoporphyrin IX (PIX) in single-walled carbon nanotubes (SWCNT) and multi-walled carbon nanotubes (MWCNT) decorated with copper (Cu) and gold (Au) nanoparticles were designed and used for the molecular recognition of isocitrate dehydrogenase 1 (IDH1) and isocitrate dehydrogenase 2 (IDH2) in biological samples (brain tumor tissues, whole blood).
  • 473
  • 22 Feb 2022
Topic Review
Stir Casting Routes for Metal Matrix Syntactic Foams
Metal matrix syntactic foams (MMSFs) are advanced lightweight materials constituted by a metallic matrix and a dispersion of hollow and/or porous fillers. Physical and mechanical properties can be fitted regarding matrix and filler properties and processing parameters. Their properties make them potential materials for sectors where density is a limiting parameter, such as transport, marine, defense, aerospace, and engineering applications. MMSFs are mainly manufactured by powder metallurgy, infiltration, and stir casting techniques. Stir casting techniques (SCTs) are low-cost and industrially scalable approaches. Critical limitations of SCTs are buoyancy of fillers, corrosion of processing equipment, premature solidification of molten metal during mixing, cracking of fillers, heterogeneous distribution, and limited incorporation of fillers. Efforts to overcome these limitations have led to the development of new techniques and to obtain MMSFs with improved properties.
  • 484
  • 19 Apr 2022
Topic Review
Stimulus-Responsive Polymers and Polypeptoid Skeletons
Polypeptoids have low cytotoxicity and good biocompatibility because of their structural similarity to polypeptides. Different from polypeptides, however, polypeptoids show thermal transformation similar to synthetic thermoplastics, making them suitable for various heat treatment methods. Polypeptoids combine the properties of natural macromolecules and synthetic polymers, and become great candidates as stimulus-responsive biopolymers.
  • 474
  • 05 Aug 2021
Topic Review
Stimuli-Responsive Zinc (II) Coordination Polymers
The unique role of the zinc (II) cation prompted us to cut a cross-section of the large and complex topic of the stimuli-responsive coordination polymers (CPs). Due to its flexible coordination environment and geometries, easiness of coordination–decoordination equilibria, “optically innocent” ability to “clip” the ligands in emissive architectures, non-toxicity and sustainability, the zinc (II) cation is a good candidate for building supramolecular smart tools. 
  • 612
  • 08 Nov 2021
Topic Review
Stimuli-Responsive Smart Materials for Wearable Technology in Healthcare
Thanks to the Internet of Things (IoT), the demand for the development of miniaturized and wearable sensors has skyrocketed. Among them, novel sensors for wearable medical devices are mostly needed. Wearable sensors can monitor physiological parameters in a non-invasive way, thus strongly reducing but not fully avoiding any reactions. With the goal of smart health monitoring, nanosized sol–gel precursors, bringing coupling agents into their chemical structure, were used to modify halochromic dyestuffs, both minimizing leaching from the treated surfaces and increasing photostability for the development of stimuli-responsive sensors.
  • 429
  • 21 Oct 2022
Topic Review
Stimuli-Responsive Nucleic Acids Delivery System in Gene Therapy
Compared with traditional drugs, gene therapy can directly correct the disease-related genes at the genetic level, which guarantees a sustained effect. However, nucleic acids are unstable in circulation and have short half-lives. They cannot pass through biological membranes due to their high molecular weight and massive negative charges. To facilitate the delivery of nucleic acids, it is crucial to develop a suitable delivery strategy. The emergence of stimuli-responsive delivery systems has made it possible to control the release of nucleic acids in an intelligent manner and to precisely guide the therapeutic nucleic acids to the target site. Considering the unique properties of stimuli-responsive delivery systems, various stimuli-responsive nanocarriers have been developed. 
  • 210
  • 19 May 2023
Topic Review
Stimuli-responsive materials
Smart or stimuli-responsive materials are an emerging class of materials used for tissue engineering and drug delivery. A variety of stimuli (including temperature, pH, redox-state, light, and magnet fields) are being investigated for their potential to change a material’s properties, interactions, structure, and/or dimensions. The specificity of stimuli response, and ability to respond to endogenous cues inherently present in living systems provide possibilities to develop novel tissue engineering and drug delivery strategies (for example materials composed of stimuli responsive polymers that self-assemble or undergo phase transitions or morphology transformations). Herein, smart materials as controlled drug release vehicles for tissue engineering are described, highlighting their potential for the delivery of precise quantities of drugs at specific locations and times promoting the controlled repair or remodeling of tissues.
  • 3.2K
  • 24 Jul 2020
Topic Review
Stimuli-Responsive Hydrogels in Drug Delivery
Stimuli-responsive hydrogels, also known as smart hydrogels, exhibit responsiveness to diverse external stimuli. These gels can undergo reversible or irreversible changes in physical or chemical properties upon exposure to stimuli, enabling a highly controllable drug release pattern. This capability contributes to achieving precise drug administration and enhancing treatment effectiveness and safety.
  • 364
  • 24 Oct 2023
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