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Topic Review
Radiolabeled Gold Nanoseeds and Glioblastoma Multiforme
Glioblastoma multiforme (GBM), classified as a grade IV brain tumor, represents the most frequent brain tumor, accounting for approximately 12–15% of all intracranial neoplasms. Current therapeutic strategies for GBM rely on open surgery, chemotherapy and radiotherapy. Despite some progress in the past 30 years, the overall survival of patients with glioblastoma remains extremely poor. The average lifespan is approximately 15 months after diagnosis, with most patients experiencing tumor relapse and outgrowth within 7–10 months of initial radiation therapy.
  • 663
  • 14 Jan 2022
Topic Review
Layer-by-Layer Deposition to Reduce Flammability of Textiles
Layer-by-layer (LbL) deposition is an emerging green technology to reduce flammability of the most widely used fibers (cotton, polyester, polyamide and their blends), which shows numerous advantages over current commercially available textile finishing processes due to the use of water as a solvent for a variety of active substances at very low concentrations. The LbL deposition includes immersing textiles into the solutions of oppositely charged polyelectrolytes or spraying textiles with charged solutions to build LbL assemblies with the desired number of bilayers (BLs), trilayers (TLs), or quadlayers (QLs) with different functionality. In conventional LbL deposition, layers are attracted by weak electrostatic forces of polyelectrolytes soluble in water, polyanions and polycations with one charged group per monomer unit, but polymers bearing hydrogen bond donors and acceptors are also able to form assemblies. 
  • 914
  • 14 Jan 2022
Topic Review
Thienopyrimidine
Thienopyrimidine emerges as an attractive scaffold in medicinal chemistry with a wide array of pharmacological properties, such as antibacterial, antifungal, antiparasitic and antiviral. Considering the fusion between pyrimidine and thiophene rings, three different thienopyrimidines can be obtained, namely thieno[2,3-d]pyrimidines, thieno[3,2-d]pyrimidines and thieno[3,4-d]pyrimidines. Different synthetic pathways involving the construction of the pyrimidine or the thiophene ring were reported in the literature to access polysubstituted thienopyrimidines. In these approaches, the synthetic strategies mostly involved the synthesis of a thienopyrimidin-4-one derivative, where position 4 could be modified via further functionalization.
  • 908
  • 13 Jan 2022
Topic Review
Seed Priming
Seed nano-priming is an efficient process that can change seed metabolism and signaling pathways, affecting not only germination and seedling establishment but also the entire plant lifecycle.
  • 2.7K
  • 13 Jan 2022
Topic Review
(−)-Methyl-Oleocanthal, a New Oleocanthal Metabolite
The antioxidant and anti-inflammatory responses of (−)-methyl-oleocanthal (met-OLE), a new metabolite of the extra virgin olive oil (EVOO) phenolic oleocanthal (OLE), were explored in lipopolysaccharide (LPS)-induced murine peritoneal macrophages. Possible signaling pathways and epigenetic modulation of histones were studied. Met-OLE inhibited LPS-induced intracellular reactive oxygen species (ROS) and nitrite (NO) production and decreased the overexpression of the pro-inflammatory enzymes COX-2, mPGES-1 and iNOS in murine macrophages.
  • 741
  • 13 Jan 2022
Topic Review
Secondary Metabolites of Purpureocillium lilacinum
Fungi can synthesize a wealth of secondary metabolites, which are widely used in the exploration of lead compounds of pharmaceutical or agricultural importance. Beauveria, Metarhizium, and Cordyceps are the most extensively studied fungi in which a large number of biologically active metabolites have been identified. However, relatively little attention has been paid to Purpureocillium lilacinum. P. lilacinum are soil-habituated fungi that are widely distributed in nature and are very important biocontrol fungi in agriculture, providing good biological control of plant parasitic nematodes and having a significant effect on Aphidoidea, Tetranychus cinnbarinus, and Aleyrodidae. At the same time, it produces secondary metabolites with various biological activities such as anticancer, antimicrobial, and insecticidal. 
  • 688
  • 13 Jan 2022
Topic Review
Hydroxyapatite Doped with Photoluminescent Elements
Photoluminescence is an especially important and useful mechanism for in situ investigations in tissue engineering, surgery, tissue restoration. Labeling with the aid of organic fluorescent molecules has been popular in clinical trials for years. In recent times, many inorganic components, even nanoparticles, have been proposed to be such candidates. Nonetheless, the toxicity of such particles represents a challenge to practical application because of their composition and nano-size character. A luminescent material with high biocompatibility is a perfect candidate for implantation and clinical application. 
  • 466
  • 13 Jan 2022
Topic Review
H2 in CO Oxidation over Ceria Catalysts
The preferential CO oxidation (so-called CO-PROX) is the selective CO oxidation amid H2-rich atmospheres, a process where ceria-based materials are consolidated catalysts. This article aims to disentangle the potential CO–H2 synergism under CO-PROX conditions on the low-index ceria surfaces (111), (110) and (100). Polycrystalline ceria, nanorods and ceria nanocubes were prepared to assess the physicochemical features of the targeted surfaces. Diffuse reflectance infrared Fourier-transformed spectroscopy (DRIFTS) shows that ceria surfaces are strongly carbonated even at room temperature by the effect of CO, with their depletion related to the CO oxidation onset. Conversely, formate species formed upon OH + CO interaction appear at temperatures around 60 °C and remain adsorbed regardless the reaction degree, indicating that these species do not take part in the CO oxidation. Density functional theory calculations (DFT) reveal that ceria facets exhibit high OH coverages all along the CO-PROX reaction, whilst CO is only chemisorbed on the (110) termination. 
  • 338
  • 13 Jan 2022
Topic Review
Commercial Polymeric Membrane for Gas Separation
CO2 has been highly emitted to the environment, with the distribution of 25% being from electricity and heat production, 24% from agriculture, forestry, and other land usages, 21% by industry, 14% from transportation, 10% by other energies, and 6% from building. CO2 removal from natural gas is needed due to issues such as corrosion, catalyst poisoning and its effects on lowering the heating value of fuel. Several mass-transfer technologies can be used for this purpose, namely, membrane, absorption, adsorption and cryogenic. Membrane-based separation methods are more energy-efficient than heat-driven separations. Membrane-based separation uses 90% less energy than its distillation counterpart.
  • 1.9K
  • 12 Jan 2022
Topic Review
Carbohydrates/Matrix Lignin in Mechanically Graded Bamboo Culms
The mechanical performance of bamboo is highly dependent on its structural arrangement and the properties of biomacromolecules within the cell wall. Along the radius of bamboo culms, the concentration of xylan within the fiber sheath increased, while that of cellulose and lignin decreased gradually. At cellular level, although the consecutive broad layer (Bl) of fiber revealed a relatively uniform cellulose orientation and concentration, the outer Bl with higher lignification level has higher elastic modulus (19.59–20.31 GPa) than that of the inner Bl close to the lumen area (17.07–19.99 GPa). Comparatively, the cell corner displayed the highest lignification level, while its hardness and modulus were lower than that of fiber Bl, indicating the cellulose skeleton is the prerequisite of cell wall mechanics. The obtained cytological information is helpful to understand the origin of the anisotropic mechanical properties of bamboo.
  • 476
  • 12 Jan 2022
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