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Topic Review
Recycling of High-Molecular-Weight Organosilicon Compounds in Supercritical Fluids
The main known patterns of thermal and/or catalytic destruction of high-molecular-weight organosilicon compounds are considered from the viewpoint of the prospects for processing their wastes. The advantages of using supercritical fluids in plastic recycling are outlined in this entry. They are related to a high diffusion rate, efficient extraction of degradation products, the dependence of solvent properties on pressure and temperature, etc. A promising area for further research is described concerning the application of supercritical fluids for processing the wastes of organosilicon macromolecular compounds.
  • 557
  • 14 Dec 2022
Topic Review
Polymer-Based Thermally Conductive Materials by Fused Filament Fabrication
With the miniaturization and integration of electronic products, the heat dissipation efficiency of electronic equipment needs to be further improved. Notably, polymer materials are a choice for electronic equipment matrices because of their advantages of low cost and wide application availability. Intelligent electronic devices are currently being researched to meet people’s pursuit of a high-quality life through integration and miniaturization. In order to ensure product safety and operational efficiency, it is imperative to improve the thermal conductivity of electronic devices. Polymers are frequently used in preparing heat dissipation materials because of their low price, light weight, ease of processing, and wide applications.
  • 553
  • 25 Oct 2022
Topic Review
Thermally Conductive 3D Aerogels Based on Carbon Nanofillers
Aerogels are perfect 3D interconnected designs with unique properties provided by tenuous networks of nanosheets or filaments; they are typically fabricated via sol–gel, freeze drying, and other phase-separating and drying techniques and possess remarkable properties, such as an extraordinarily high specific surface area, great flexibility, low density, variable tunable porosity, low dielectric constant, and low TC. Due to the abovementioned advantageous physical features, they present a large amount of promise for applications as adaptable absorbent materials and for their uses in EM shielding, thermal insulation, and wearable pressure-sensing materials, to be employed as a multifunctional aerogel material. 
  • 549
  • 28 Nov 2022
Topic Review
Patchy Micelles via Crystallization-Driven Self-Assembly
Crystallization-driven self-assembly (CDSA) represents a highly versatile method for the production of well-defined block copolymer micelles in solution giving access to numerous tailor-made one-, two- and three-dimensional assemblies with controlled length, length distribution, shape, and corona chemistries. One special example of micelles derived by CDSA are the so-called patchy micelles, which possess a corona made of alternating nanometer-sized compartments. These patchy micelles show superior interfacial activity making them excellent candidates for the use as compatibilizers or metal (oxide) nanoparticle templates.
  • 546
  • 23 Jun 2021
Topic Review
Printable Hydrogels
The hydrogel is a hydrophilic scaffold composed of covalent and non-covalent polymeric chains bonds, providing a 3D shape environment similar to the native extra-cellular matrix (ECM).
  • 540
  • 18 Mar 2021
Topic Review
Biodegradable Microparticles for Regenerative Medicine
Regenerative medicine is one of the most attractive topics of research worldwide. Different strategies are proposed, and a range of materials of various forms and compositions tailored for tissue engineering are developed, but this approach just started to emerge in clinics. Biodegradable microparticles (MPs) made from degradable and biocompatible polymers, with a mean diameter of ~200 μm, are attractive not only as 3D matrices to multiply cells but also as a scaffold to support tissue rebuilding.
  • 538
  • 19 Apr 2022
Topic Review
Hierarchical Ceramide Microcapsules
As a main component of the stratum corneum, ceramides can construct protective lamellae to provide an epidermal barrier against dehydration or external microorganisms. However, as ceramide molecules can easily form the isolated crystalline phase through self-assembly due to the amphipathic nature of bioactive lipids, the effective incorporation of ceramides into liquid media is the remaining issue for controlled release. Here, we report an unprecedented effective strategy to fabricate a completely amorphous and highly sustainable hierarchical ceramide polymer microcapsule for promising epidermal barrier by using the interpenetrating and cooperative self-construction of conical amphiphiles with a different critical packing parameter. The self-constructed amorphous architecture of ceramides in polymer microcapsule is achieved by the facile doping of conical amphiphiles and subsequent in situ polymerization of shell polymer in the core-shell geometry. It is experimentally revealed that an irregular cooperative packing structure formed by adaptive hydrophobic–hydrophilic interactions of cylindrical ceramides and conical amphiphiles in the confined microcapsule geometry enables a completely amorphous morphology of ceramides to be realized during the spontaneous encapsulation process. Furthermore, this elegant approach affords a highly dispersible and uniform hierarchical amorphous ceramide microcapsule with a greatly enhanced long-term stability compared to conventional crystalline ceramides.
  • 537
  • 10 Nov 2020
Topic Review
Crosslinked nanogel for cancer theranostics
Crosslinked nanogels the structures of which are covalently crosslinked have better physiological stability than micelles and liposomes, making them more suitable for cancer theranostics. The applications of nanogels in drug and gene delivery as well as development of novel cancer therapeutic methods are first introduced, followed by the introduction of applications in optical and multimodal imaging, and imaging-guided cancer therapy. 
  • 535
  • 01 Sep 2020
Topic Review
Chitosan-Containing Composite Materials for Adsorption and Catalysis
Composite materials including organic–inorganic systems have drawn special attention due to their enhanced properties such as adsorbents and heterogeneous catalysts. At the same time, large-scale production of environmentally benign functionalized biopolymers, such as chitosan (CS), allows for constantly developing new materials, since CS reveals remarkable properties as a stabilizing agent for metal-containing compounds and enzymes and as an adsorbent of organic molecules. 
  • 534
  • 15 Mar 2023
Topic Review
Classification and Application of Natural Polymers
Natural polysaccharides are some of the most extensively used biopolymers in food, pharmaceutical, and medical applications, because they are renewable and have a high level of biocompatibility and biodegradability. The fundamental understanding required to properly exploit polysaccharides potential in the biocomposite, nanoconjugate, and pharmaceutical industries depends on detailed research of these molecules. Polysaccharides are preferred over other polymers because of their biocompatibility, bioactivity, homogeneity, and bioadhesive properties. Natural polysaccharides have also been discovered to have excellent rheological and biomucoadhesive properties, which may be used to design and create a variety of useful and cost-effective drug delivery systems. Polysaccharide-based composites derived from natural sources have been widely exploited due to their multifunctional properties, particularly in drug delivery systems and biomedical applications. These materials have achieved global attention and are in great demand because to their biochemical properties, which mimic both human and animal cells. 
  • 534
  • 07 Feb 2024
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