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Topic Review
Metal-Organic Frameworks in CO2 Cycloaddition with Epoxides
The level of carbon dioxide in the atmosphere is growing rapidly due to fossil fuel combustion processes, heavy oil, coal, oil shelter, and exhausts from automobiles for energy generation, which lead to depletion of the ozone layer and consequently result in global warming. The realization of a carbon-neutral environment is the main focus of science and academic researchers of today. Several processes were employed to minimize carbon dioxide in the air, some of which include the utilization of non-fossil sources of energy like solar, nuclear, and biomass-based fuels. Consequently, these sources were reported to have a relatively high cost of production and maintenance. The applications of both homogeneous and heterogeneous processes in carbon capture and storage were investigated in recent years and the focus now is on the conversion of CO2 into useful chemicals and compounds. It was established that CO2 can undergo cycloaddition reaction with epoxides under the influence of special catalysts to give cyclic carbonates, which can be used as value-added chemicals at a different level of pharmaceutical and industrial applications. Among the various catalysts studied for this reaction, metal-organic frameworks are now on the frontline as a potential catalyst due to their special features and easy synthesis. Several metal-organic framework (MOF)-based catalysts were studied for their application in transforming CO2 to organic carbonates using epoxides. Here, we report some recent studies of porous MOF materials and an in-depth discussion of two repeatedly used metal-organic frameworks as a catalyst in the conversion of CO2 to organic carbonates
  • 1.2K
  • 25 Nov 2021
Topic Review
Classification of the Approved EGFR-TKIs
Targeting EGFR with small-molecule inhibitors is a valid strategy in cancer therapy. Since the approval of the first EGFR-TKI in 2003, a huge number of EGFR inhibitors were reported. Classification of these inhibitors could help the researchers to understand their structure-activity relationship. Herein, we introduce different types of classifications of the EGFR-TKIs, which received global approval for clinical use. In the following, the EGFR-targeting drugs are classified based on their chemistry, clinical use, target kinases, and the type of inhibition/interaction with EGFR. 
  • 4.0K
  • 25 Nov 2021
Topic Review
Starch-Based Materials
Starch is one of the most common biodegradable polymers found in nature, and it is widely utilized in the food and beverage, bioplastic industry, paper industry, textile, and biofuel industries. Starch has received significant attention due to its environmental benignity, easy fabrication, relative abundance, non-toxicity, and biodegradability. 
  • 1.5K
  • 25 Nov 2021
Topic Review
2,7(3,6)-Diaryl(arylamino)-substituted Carbazoles
The carbazole is an electron-rich heterocyclic compound, whose structure can be easily modified by rather simple reactions in order to obtain 2,7(3,6)-diaryl(arylamino)-substituted carbazoles. The substituted derivatives are widely used for the formation of Organic light emitting diode (OLED) due to their good charge carrier injection and transfer characteristics, electroluminescence, thermally activated delayed fluorescence, improved thermal and morphological stability as well as their thin film forming characteristics. 
  • 1.1K
  • 24 Nov 2021
Topic Review
Bio-Photonic Cavities
An eco-friendly approach to usual optical cavities, in which an electromagnetic radiation can release energy to matter by interacting with its molecular or atomic structure. Based on bio-inspired and biodegradable meta-surfaces, able to behave as a resonator for light, their optical response can be engineered at will to accomplish a particular optical task.  
  • 637
  • 24 Nov 2021
Topic Review
Molecularly Imprinted (Micro)Solid Phase Extraction
Molecularly imprinted polymers (MIPs) are versatile materials that mimic natural antigen–antibody mechanisms and allow molecules/analytes recognition [2,3]. MIPs have been used as selective sorbents for (micro)solid extraction (µ-SPE) procedures leading to molecularly imprinted (micro)solid extraction (MIMSPE), which allows advanced miniaturized sample pre-treatments for green procedures in Analytical Chemistry.
  • 1.0K
  • 24 Nov 2021
Topic Review
Sample Preparation for Cosmetics Analysis
Traditional cosmetics sample preparation techniques involve liquid–liquid extraction (LLE) and solid–liquid extraction (SLE). In last years, modern sample extraction techniques are advancing towards fast sample processing, easy automatization, as well as a reduction in organic solvent volumes, in agreement with the green chemistry principles in two ways (i) the miniaturization of conventional procedures allowing a reduction of the solvents and reagents consumption and (ii) the development and application of sorbent- and liquid-based microextraction technologies to obtain a high analyte enrichment, avoiding or significantly reducing the use of organic solvents.
  • 1.2K
  • 24 Nov 2021
Topic Review
Food Science's Chemical Element Compositions
In recent years, many analyses have been carried out to investigate the chemical components of food data. However, studies rarely consider the compositional pitfalls of such analyses. This is problematic as it may lead to arbitrary results when non-compositional statistical analysis is applied to compositional datasets. In this study, compositional data analysis (CoDa), which is widely used in other research fields, is compared with classical statistical analysis to demonstrate how the results vary depending on the approach and to show the best possible statistical analysis. For example, honey and saffron are highly susceptible to adulteration and imitation, so the determination of their chemical elements requires the best possible statistical analysis. Our study demonstrated how principle component analysis (PCA) and classification results are influenced by the pre-processing steps conducted on the raw data, and the replacement strategies for missing values and non-detects. Furthermore, it demonstrated the differences in results when compositional and non-compositional methods were applied. Our results suggested that the outcome of the log-ratio analysis provided better separation between the pure and adulterated data and allowed for easier interpretability of the results and a higher accuracy of classification. Similarly, it showed that classification with artificial neural networks (ANNs) works poorly if the CoDa pre-processing steps are left out. From these results, we advise the application of CoDa methods for analyses of the chemical elements of food and for the characterization and authentication of food products.
  • 998
  • 24 Nov 2021
Topic Review
Ellagic Acid
Polyphenol ellagic acid (EA) possesses antioxidant, anti-inflammatory, anti-carcinogenic, anti-diabetic and cardio protection activities, making it an interesting multi-targeting profile. EA also controls the central nervous system (CNS), since it was proven to reduce the immobility time of mice in both the forced swimming and the tail-suspension tests, with an efficiency comparable to that of classic antidepressants. The proposed mechanism revealed that EA mimics clonidine at the presynaptic release-regulating α2 autoreceptors in hippocampal noradrenergic nerve endings.
  • 868
  • 24 Nov 2021
Topic Review
Thallium
Thallium, as a pharmaceutical cosmetic product, is applied for facial hair removal and fungal infections of the scalp. Thallium acetate is currently used as a catalyst in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions. Detection of Tl is a challenging task because its concentration in environmental samples may be at a nanogram per gram level or lower.
  • 1.7K
  • 23 Nov 2021
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