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Topic Review
Characterization of Ti/SnO2 Interface by X-ray Photoelectron Spectroscopy
The Ti/SnO2 interface has been investigated in situ via the technique of x-ray photoelectron spectroscopy. Thin films (in the range from 0.3 to 1.1 nm) of titanium were deposited on SnO2 substrates via the e-beam technique. The deposition was carried out at two different substrate temperatures, namely room temperature and 200 °C. The photoelectron spectra of tin and titanium in the samples were found to exhibit significant differences upon comparison with the corresponding elemental and the oxide spectra. These changes result from chemical interaction between SnO2 and the titanium overlayer at the interface. The SnO2 was observed to be reduced to elemental tin while the titanium overlayer was observed to become oxidized. Complete reduction of SnO2 to elemental tin did not occur even for the lowest thickness of the titanium overlayer. The interfaces in both the types of the samples were observed to consist of elemental Sn, SnO2, elemental titanium, TiO2, and Ti-suboxide. 
  • 640
  • 26 Jan 2022
Topic Review
Onium Compound
In chemistry, an onium ion is a cation formally obtained by the protonation of mononuclear parent hydride of a pnictogen (group 15 of the periodic table), chalcogen (group 16), or halogen (group 17). The oldest-known onium ion, and the namesake for the class, is ammonium, NH+4, the protonated derivative of ammonia, NH3. The name onium is also used for cations that would result from the substitution of hydrogen atoms in those ions by other groups, such as organic radicals, or halogens; such as tetraphenylphosphonium, (C6H5)4P+. The substituent groups may be divalent or trivalent, yielding ions such as iminium and nitrilium. A simple onium ion has a charge of +1. A larger ion that has two onium ion subgroups is called a double onium ion, and has a charge of +2. A triple onium ion has a charge of +3, and so on. Compounds of an onium cation and some other negative ion are known as onium compounds or onium salts. Onium ions and onium compounds are inversely analogous to -ate ions and ate complexes:
  • 639
  • 16 Nov 2022
Topic Review
Epoch
In astronomy, an epoch or reference epoch is a moment in time used as a reference point for some time-varying astronomical quantity. It is useful for the celestial coordinates or orbital elements of a celestial body, as they are subject to perturbations and vary with time. These time-varying astronomical quantities might include, for example, the mean longitude or mean anomaly of a body, the node of its orbit relative to a reference plane, the direction of the apogee or aphelion of its orbit, or the size of the major axis of its orbit. The main use of astronomical quantities specified in this way is to calculate other relevant parameters of motion, in order to predict future positions and velocities. The applied tools of the disciplines of celestial mechanics or its subfield orbital mechanics (for predicting orbital paths and positions for bodies in motion under the gravitational effects of other bodies) can be used to generate an ephemeris, a table of values giving the positions and velocities of astronomical objects in the sky at a given time or times. Astronomical quantities can be specified in any of several ways, for example, as a polynomial function of the time-interval, with an epoch as a temporal point of origin (this is a common current way of using an epoch). Alternatively, the time-varying astronomical quantity can be expressed as a constant, equal to the measure that it had at the epoch, leaving its variation over time to be specified in some other way—for example, by a table, as was common during the 17th and 18th centuries. The word epoch was often used in a different way in older astronomical literature, e.g. during the 18th century, in connection with astronomical tables. At that time, it was customary to denote as "epochs", not the standard date and time of origin for time-varying astronomical quantities, but rather the values at that date and time of those time-varying quantities themselves. In accordance with that alternative historical usage, an expression such as 'correcting the epochs' would refer to the adjustment, usually by a small amount, of the values of the tabulated astronomical quantities applicable to a fixed standard date and time of reference (and not, as might be expected from current usage, to a change from one date and time of reference to a different date and time).
  • 639
  • 22 Nov 2022
Topic Review
Three-Phase
In electrical engineering, three-phase electric power systems have at least three conductors carrying alternating current voltages that are offset in time by one-third of the period. A three-phase system may be arranged in delta (∆) or star (Y) (also denoted as wye in some areas). A wye system allows the use of two different voltages from all three phases, such as a 230/400 V system which provides 230 V between the neutral (centre hub) and any one of the phases, and 400 V across any two phases. A delta system arrangement only provides one voltage magnitude, but it has a greater redundancy as it may continue to operate normally with one of the three supply windings offline, albeit at 57.7% of total capacity. Harmonic current in the neutral may become very large if nonlinear loads are connected.
  • 638
  • 17 Oct 2022
Biography
Valery Rubakov
Valery Anatolyevich Rubakov (Russian: Валерий Анатольевич Рубаков, born 16 February 1955 in Moscow, USSR) is a Russian theoretical physicist. His scientific interests include quantum field theory, elementary particle physics, and cosmology. He is affiliated with the Institute for Nuclear Research (INR) of the Russian Academy of Sciences in Moscow. Rubakov studied phys
  • 638
  • 15 Nov 2022
Topic Review
Shock Capturing Method
In computational fluid dynamics, shock-capturing methods are a class of techniques for computing inviscid flows with shock waves. The computation of flow containing shock waves is an extremely difficult task because such flows result in sharp, discontinuous changes in flow variables such as pressure, temperature, density, and velocity across the shock.
  • 637
  • 25 Nov 2022
Topic Review
Glossary of Nanotechnology
This glossary of nanotechnology is a list of definitions of terms and concepts relevant to nanotechnology, its sub-disciplines, and related fields. For more inclusive glossaries concerning related fields of science and technology, see Glossary of chemistry terms, Glossary of physics, Glossary of biology, and Glossary of engineering.
  • 634
  • 02 Nov 2022
Topic Review
Chemical Beam Epitaxy
Chemical beam epitaxy (CBE) forms an important class of deposition techniques for semiconductor layer systems, especially III-V semiconductor systems. This form of epitaxial growth is performed in an ultrahigh vacuum system. The reactants are in the form of molecular beams of reactive gases, typically as the hydride or a metalorganic. The term CBE is often used interchangeably with metal-organic molecular beam epitaxy (MOMBE). The nomenclature does differentiate between the two (slightly different) processes, however. When used in the strictest sense, CBE refers to the technique in which both components are obtained from gaseous sources, while MOMBE refers to the technique in which the group III component is obtained from a gaseous source and the group V component from a solid source.
  • 633
  • 30 Nov 2022
Topic Review
Thermochemical Cycle
Thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If work is partially used as an input, the resulting thermochemical cycle is defined as a hybrid one.
  • 633
  • 14 Oct 2022
Topic Review
Graphene Based TE Materials
Graphene is a two-dimensional (2D) monolayer material with only one carbon atom thickness. The most promising method for transparent conductive graphene electrodes in optoelectronic devices is reportedly synthesized via chemical vapor deposition, where graphene films are deposited directly on a substrate such as Cu foil by passing a carbon source through a high-temperature vacuum chamber, and the synthesized graphene is transferred to the target substrate using a support film such as poly (methyl methacrylate).
  • 632
  • 14 Feb 2023
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