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Topic Review
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Video Entry
Topic Review
Sicana odorifera Naudim Vell. Seeds By-Products
The “Kurugua” (Sicana odorifera) is a native fruit that demonstrates attractive nutritional, coloring, flavoring, and antioxidant properties. The main by-products from the processing and consumption of kurugua fruit are epicarp and seeds.
619
29 Jan 2022
Topic Review
Selective Sensing of Formaldehyde
Formaldehyde (FA) is a colorless, flammable, foul-smelling chemical used in building materials and in the production of numerous household chemical goods. Herein, a fluorescent chemosensor for FA is designed and prepared using a selective organ-targeting probe containing naphthalimide as a fluorophore and hydrazine as a FA-binding site. The amine group of the hydrazine reacts with FA to form a double bond and this condensation reaction is accompanied by a shift in the absorption band of the probe from 438 nm to 443 nm upon the addition of FA. Further, the addition of FA is shown to enhance the emission band at 532 nm relative to the very weak fluorescent emission of the probe itself. Moreover, a high specificity is demonstrated towards FA over other competing analytes such as the calcium ion (Ca2+), magnesium ion (Mg2+), acetaldehyde, benzaldehyde, salicylaldehyde, glucose, glutathione, sodium sulfide (Na2S), sodium hydrosulfide (NaHS), hydrogen peroxide (H2O2), and the tert-butylhydroperoxide radical. A typical two-photon dye incorporated into the probe provides intense fluorescence upon excitation at 800 nm, thus demonstrating potential application as a two-photon fluorescent probe for FA sensing.
608
25 Aug 2021
Topic Review
Graphene Derivatives with Conducting Polymers
The development of sensorial platforms based on graphene derivatives and conducting polymers (CPs), alternatively deposited or co-deposited on the working electrode (usually a glassy carbon electrode; GCE) using a simple potentiostatic method (often cyclic voltammetry; CV), possibly followed by the deposition of metallic nanoparticles (NPs) on the electrode surface (ES). These materials have been successfully used to detect an extended range of biomolecules of clinical interest, such as uric acid (UA), dopamine (DA), ascorbic acid (AA), adenine, guanine, and others.
603
06 Feb 2023
Topic Review
Applications of Metal–Organic Frameworks
Metal–organic frameworks (MOFs) have been broadly applied to numerous domains with a substantial surface area, tunable pore size, and multiple unsaturated metal sites. Hollow MOFs and their composites as well as their applications can be used in organic catalysis, electrochemical sensing, and adsorption separation.
602
06 Jan 2023
Topic Review
Biomedical Applications of Calcium Orthophosphate (CaPO
4
)-Based Bioceramics
A strong interest was raised in studying ceramics as potential bone grafts due to their biomechanical properties. Current biomedical applications of CaPO4-based bioceramics include artificial bone grafts, bone augmentations, maxillofacial reconstruction, spinal fusion, and periodontal disease repairs, as well as bone fillers after tumor surgery.
599
10 Jul 2023
Topic Review
Nanoencapsulated Phase-Change Materials
Phase-change materials (PCMs) are becoming more widely acknowledged as essential elements in thermal energy storage, greatly aiding the pursuit of lower building energy consumption and the achievement of net-zero energy goals. PCMs are frequently constrained by their subpar heat conductivity, despite their expanding importance.
595
30 Nov 2023
Topic Review
Array-Based Cell Sensing for Chemical Screening
Synthetic chemicals are widely used in the daily life, making chemical safety assessments necessary for environmental exposure. Additionally, the rapid determination of chemical drug efficacy and safety is a key step in therapeutic discoveries. Cell-based screening methods are non-invasive, and cellular phenotypic changes can also provide more sensitive indicators of chemical effects than conventional cell viability. Array-based cell sensors can be engineered to maximize sensitivity to changes in cell phenotypes, lowering the threshold for detecting cellular responses under external stimuli. Therefore, array-based sensing can provide a robust strategy for both cell-based chemical risk assessments and therapeutics discovery.
587
06 Apr 2022
Topic Review
Nucleic Acid Drugs Delivery Carriers
Nucleic acid drugs are not readily permeable through cell membranes and often exhibit poor blood serum stability, rapid renal clearance and poor endosomal escape/cytoplasmic escape. Therefore, they are commonly used in combination with drug delivery system (DDS) carriers. The drug carrier plays an important role in the process of drug delivery.
585
04 Aug 2021
Topic Review
Physicochemistry of Deep Eutectic Solvents
Deep eutectic solvents (DESs), considered as one of the greenest families of solvents, are used in many fields, such as organic synthesis, (bio)catalysis, electrochemistry, and (bio)medicine.
585
17 May 2023
Topic Review
Reducing Chlorine Evolution through Transitional Metal Dopants
Electrocatalytic water splitting is a possible route to the expanded generation of green hydrogen; a long-term challenge is the requirement of fresh water as an electrolyzer feed. The use of seawater as a direct feed for electrolytic hydrogen production would alleviate fresh water needs and potentially open an avenue for locally generated hydrogen from marine hydrokinetic or off-shore power sources. One environmental limitation to seawater electrolysis is the generation of chlorine as a competitive anodic reaction.
584
29 Dec 2021
Topic Review
Material Design in Implantable Biosensors
The impressive development in biosensing devices has led to the creation of man-made implantable devices that are temporarily or permanently introduced into the human body, and thus, diminishing the pain and discomfort of the person. Biosensors in the in vivo environment are required to have specific features, including biocompatibility (minimal immune response or biofouling), biodegradability, reliability, high accuracy, and miniaturization (flexible, stretchable, lightweight, and ultra-thin). However, the performance of implantable biosensors is limited by body responses and insufficient power supplies (due to minimized batteries/electronics and data transmission without wires).
583
13 Apr 2023
Topic Review
Solid-State Electrolytes for Lithium–Sulfur Batteries
Lithium–sulfur batteries (LSBs) represent a promising next-generation energy storage system, with advantages such as high specific capacity (1675 mAh g−1), abundant resources, low price, and ecological friendliness. During the application of liquid electrolytes, the flammability of organic electrolytes, and the dissolution/shuttle of polysulfide seriously damage the safety and the cycle life of lithium–sulfur batteries. Replacing a liquid electrolyte with a solid one is a good solution, while the higher mechanical strength of solid-state electrolytes (SSEs) has an inhibitory effect on the growth of lithium dendrites. However, the lower ionic conductivity, poor interfacial contact, and relatively narrow electrochemical window of solid-state electrolytes limit the commercialization of solid-state lithium–sulfur batteries (SSLSBs).
575
03 Nov 2022
Topic Review
Platinum and Palladium Solvent Extraction of Spent Catalysts
The strategic importance of platinum and palladium, two platinum-group metals (PGMs), is particularly supported by their technological applications, one of the most relevant being the role they perform as catalysts for several sorts of chemical reactions.
568
03 Aug 2023
Topic Review
Metal-Organic Frameworks for Water Remediation
Hexavalent chromium (Cr(VI)) is a highly mobile cancerogenic and teratogenic heavy metal ion. Among the varied technologies applied today to address chromium water pollution, photocatalysis offers a rapid reduction of Cr(VI) to the less toxic Cr(III). In contrast to classic photocatalysts, Metal-Organic frameworks (MOFs) are porous semiconductors that can couple the Cr(VI) to Cr(III) photoreduction to the chromium species immobilization.
567
16 Dec 2022
Topic Review
Phenoxypyridine as an Active Scaffold for Pesticides
Phenoxypyridine, the bioisostere of diaryl ethers, has been widely introduced into bioactive molecules as an active scaffold, which has different properties from diaryl ethers. In this paper, the bioactivities, structure-activity relationships, and mechanism of compounds containing phenoxypyridine were summarized, which may help to explore the lead compounds and discover novel pesticides with potential bioactivities.
565
12 Dec 2022
Topic Review
Microbial Surfactants: Sustainable Class of Versatile Molecules
Microbial Surfactants are the class of surfactants produced by microbes like bacteria, fungi or yeast. Due to their easy biodegradability, and less toxicity, this class is gaining huge interests of scientists, researchers, environmentalists and industrialists. Current article throws some light on the introduction and classification of microbial surfactants. Some properties og microbial surfactants has also been discussed in the same. Industrial Applications of Microbial surfactants will be discussed below.
563
31 Jan 2023
Topic Review
Ni-Based Catalysts Supported on Mg-Al Mixed Oxides
Ni-based catalysts supported on Mg-Al mixed oxides (Mg(Al)O) have been intensively investigated as catalysts for CH4 reforming processes (i.e., steam reforming (SMR) and dry reforming (DRM)), which are pivotal actors in the expanding H2 economy.
563
03 May 2023
Topic Review
Delivery Systems for the Controlled Release of Scents
Scents are volatile compounds highly employed in a wide range of manufactured items, such as fine perfumery, household products, and functional foods. One of the main directions of the research in this area aims to enhance the longevity of scents by designing efficient delivery systems to control the release rate of these volatile molecules and also increase their stability. Several approaches to release scents in a controlled manner have been developed in recent years. Thus, different controlled release systems have been prepared, including polymers, metal–organic frameworks and mechanically interlocked systems, among others.
560
13 Mar 2023
Topic Review
Organic Electronic Devices and Assessment Parameters
Organic electronic devices have gained popularity because of their promising tunable electronic properties, flexibility, low-cost, versatile functionalization, and processability. Organic field effect transistors (OFETs) are not only the fundamental building blocks of flexible and large-area electronic devices but are also a useful tool for measuring charge-carrier mobilities of newly organic semiconductors.
542
06 Apr 2023
Topic Review
Synthetic Bioactive Compounds and Chromatography
Natural and synthetic bioactive compounds occur in foods in small quantities and represent a wide group of chemical compounds. Because of the complexity of food matrices, the separation and next accurate determination of their bioactive constituents with different chemical structure requires an universal analytical methodology like liquid and gas chromatography or combination of both chromatographic techniques.
541
29 Oct 2021
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