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Topic Review
Application of Two-Dimensional Materials towards CMOS-Integrated Gas Sensors
The semiconductor metal oxide (SMO)-based gas sensor, considered the current workhorse of semiconductor-based chemiresistive gas sensor technologies, requires high temperatures to initiate the surface reactions which result in the sensing response, making it difficult to fabricate and prone to high mechanical instability. Therefore, alternatives at lower temperatures are desired, where 2D materials seem to hold the most promise. Even at ambient temperature, their sensitivity is extraordinarily large due to their extremely high surface-to-volume ratio. However, some ongoing issues still need to be resolved before gas sensors based on 2D materials can be widely used and commercialized. The alternative room temperature solutions involve optical signals, either by designing an nondispersive infrared (NDIR) sensor based on the Beer-Lambert law or by introducing an additional UV illumination to SMO sensors. In both cases, complementary metal oxide semiconductor (CMOS) integration is not feasible, which is why continued interest in 2D-material-based gas sensors persists.
  • 1.1K
  • 02 Dec 2022
Topic Review
Reactivity
In chemistry, reactivity is the impulse for which a chemical substance undergoes a chemical reaction, either by itself or with other materials, with an overall release of energy. Reactivity refers to: The chemical reactivity of a single substance (reactant) covers its behavior in which it: The chemical reactivity of a substance can refer to the variety of circumstances (conditions that include temperature, pressure, presence of catalysts) in which it reacts, in combination with the: The term reactivity is related to the concepts of chemical stability and chemical compatibility.
  • 1.2K
  • 02 Dec 2022
Topic Review
Metal Bis(trimethylsilyl)amides
Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides. Due to the bulky hydrocarbon backbone metal bis(trimethylsilyl)amide complexes have low lattice energies and are lipophilic . For this reason, they are soluble in a range of nonpolar organic solvents, in contrast to simple metal halides, which only dissolve in reactive solvents. These steric bulky complexes are molecular, consisting of mono-, di-, and tetramers. Having a built-in base, these compounds conveniently react with even weakly protic reagents. The class of ligands and pioneering studies on their coordination compounds were described by Bürger and Wannagat. The ligands are often denoted hmds (e.g. M(N(SiMe3)2)3 = M(hmds)3) in reference to the hexamethyldisilazane from which they are prepared.
  • 1.2K
  • 02 Dec 2022
Topic Review
Biological Carbon Fixation
Biological carbon fixation or сarbon assimilation is the process by which inorganic carbon (particularly in the form of carbon dioxide) is converted to organic compounds by living organisms. The compounds are then used to store energy and as structure for other biomolecules. Carbon is primarily fixed through photosynthesis, but some organisms use a process called chemosynthesis in the absence of sunlight. Organisms that grow by fixing carbon are called autotrophs, which include photoautotrophs (which use sunlight), and lithoautotrophs (which use inorganic oxidation). Heterotrophs are not themselves capable of carbon fixation but are able to grow by consuming the carbon fixed by autotrophs or other heterotrophs. "Fixed carbon", "reduced carbon", and "organic carbon" may all be used interchangeably to refer to various organic compounds. Chemosynthesis is carbon fixation driven by chemical energy, rather than from sunlight. Sulfur- and hydrogen-oxidizing bacteria often use the Calvin cycle or the reductive citric acid cycle.
  • 752
  • 02 Dec 2022
Topic Review
Artificial Solid Electrolyte Interface in Anode Materials
Due to the ever-growing importance of rechargeable lithium-ion batteries, the development of electrode materials and their processing techniques remains a hot topic in academia and industry. Even the well-developed and widely utilized active materials present issues, such as surface reactivity, irreversible capacity in the first cycle, and ageing. Thus, there have been many efforts to modify and coat the surface of active materials to enhance the electrochemical performance of the resulting electrodes and cells. This type of coating stands out because of the possibility of acting as an artificial solid electrolyte interphase (A-SEI), serving as an anode protective layer. 
  • 635
  • 02 Dec 2022
Topic Review
Polyelectrolyte Multilayers Particle Immobilization Strategy
The coating of particles or decomposable cores with polyelectrolytes via Layer-by-Layer (LbL) assembly creates free-standing LbL-coated functional particles. Due to the numerous functions that their polymers can bestow, the particles are preferentially selected for a plethora of applications, including, but not limited to coatings, cargo-carriers, drug delivery vehicles and fabric enhancements. The number of publications discussing the fabrication and usage of LbL-assembled particles has consistently increased. The shape of the LbL particle is related to the particle core, whereas the charge was dependant on the outermost polyelectrolyte in the multilayer coating. The polyelectrolytes also determine the type of bonding that a particle can form with a solid surface. These can be via either physical (non-covalent) or chemical (covalent) bonds; the latter enforcing a stronger immobilization. 
  • 453
  • 02 Dec 2022
Topic Review
Processing Technologies for Thin Kesterite CZTS Absorber Films
Solar cells based on Cu(In, Ga)(S, Se)2 (CIGS) and CdTe thin-film solar cells have already reached the commercial stage, having an efficiency of 23.4% for CIGS and 21.0% for CdTe. However, their marketability has stagnated. A promising solution for a non-toxic and commercially attractive absorber for photovoltaic applications is offered by the family of kesterite semiconductor materials such as copper–zinc–tin–sulfide (with the chemical formula Cu2ZnSnS4) (CZTS) and copper–zinc–tin–selenide (with the chemical formula Cu2ZnSnSe4)(CZTSe) and their alloy family copper–zinc–tin–sulfo–selenide (Cu2ZnSn(Sx,Se1−x)4 (CZTSSe), where 0 ≤ x ≤ 1).
  • 762
  • 02 Dec 2022
Topic Review
Click Chemistry in Building Hierarchical Structures
Hierarchical structures are an essential part of numerous types of architecture in nature. They are defined as the presence of different structural elements with different length scales in a single body. This different length scale gives each hierarchical structure its “order, n” and characteristic properties. The higher the (n) the more sophisticated hierarchical structures; where n = 0 refers to continuum materials with only a single length scale. Noteworthy, several composites are considered low-ordered hierarchical structures. The idea of building blocks for hierarchical structures intersects perfectly with the modularity concept in click chemistry. Click chemistry is a powerful tool for constructing nano, micro and macro structures through two different approaches: (A) the first approach: through direct crosslinking of (pico-building blocks) monomers give a final micro/macro structure such as hydrogels; (B) the second approach: through nano-building blocks formation using click chemistry (e.g., dendrimers and dendrons) followed by connecting and crosslinking those formed nano-building blocks again using click chemistry to form bigger structures
  • 626
  • 01 Dec 2022
Topic Review
Phthalocyanine Blue BN
Phthalocyanine Blue BN, also called by many names (EINECS 205-685-1), is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. Its brilliant blue is frequently used in paints and dyes. It is highly valued for its superior properties such as light fastness, tinting strength, covering power and resistance to the effects of alkalis and acids. It has the appearance of a blue powder, insoluble in most solvents including water.
  • 999
  • 01 Dec 2022
Topic Review
Methods of Lysergic Acid Synthesis
Ergot is the spore form of the fungus Claviceps purpurea. Ergot alkaloids are indole compounds that are biosynthetically derived from L-tryptophan and represent the largest group of fungal nitrogen metabolites found in nature. The common part of ergot alkaloids is lysergic acid. 
  • 833
  • 01 Dec 2022
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