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Topic Review
Photonic Crystals-based Plasmonic Photocatalysts
Plasmonic photocatalysts, noble-metal (NM)-modified wide-bandgap semiconductors with activity under visible-light (vis) irradiation, due to localized surface plasmon resonance (LSPR), have been intensively investigated over the last few years as efficient materials for environmental purification and energy conversion. However, the low quantum yields of photocatalytic reactions under vis irradiation, resulting from fast charge carriers' recombination, must be overcome for possible commercialization. Accordingly, the morphology design of plasmonic photocatalysts for efficient light harvesting has been proposed by using wide-bandgap semiconductors in the form of photonic crystals (PCs). 
  • 623
  • 02 Nov 2020
Topic Review
Photoelectrochemical Cells
Artificial photosynthesis is a technology with immense potential that aims to emulate the natural photosynthetic process. The process of natural photosynthesis involves the conversion of solar energy into chemical energy, which is stored in organic compounds. Catalysis is an essential aspect of artificial photosynthesis, as it facilitates the reactions that convert solar energy into chemical energy.
  • 547
  • 03 Nov 2023
Topic Review
Photodynamic Therapy for Deep-Seated Tumors
Photodynamic therapy (PDT) works through the photoactivation of a specific photosensitizer (PS) in a tumor in the presence of oxygen. PDT is widely applied in oncology to treat various cancers as it has a minimally invasive procedure and high selectivity, does not interfere with other treatments, and can be repeated as needed. A large amount of reactive oxygen species (ROS) and singlet oxygen is generated in a cancer cell during PDT, which destroys the tumor effectively. However, the efficacy of PDT in treating a deep-seated tumor is limited due to three main reasons: Limited light penetration depth, the low oxygen concentration in the hypoxic core, and poor PS accumulation inside a tumor. Thus, PDT treatments are only approved for superficial and thin tumors. With the advancement of nanotechnology, PDT to treat deep-seated or thick tumors is becoming a reachable goal. In this review, we provide an update on the strategies for improving PDT with nanomedicine using different sophisticated-design nanoparticles, including two-photon excitation, X-ray activation, targeting tumor cells with surface modification, alteration of tumor cell metabolism pathways, the release of therapeutic gases, improvement of tumor hypoxia, and stimulation of host immunity.
  • 1.1K
  • 11 Oct 2021
Topic Review
Photodynamic Therapy against Cancer
Photodynamic therapy (PDT) is based on the initial absorption of light by the photosensitizer (PS) and the subsequent direct and oxygen-mediated reactions with the cell membrane and cytoplasmic cell components.
  • 327
  • 22 Sep 2023
Topic Review
Photocathode Materials
Photoelectrochemical water splitting is a promising approach to sustainable hydrogen production with no carbon emissions. Hydrogen being a future fuel to coming human generations is of utmost importance. The photocathodes in a photoelectrochemical (PEC) water-splitting cell are essential for the direct evolution of hydrogen. Among the known photocathodes, Cu-based p-type semiconducting materials are the most promising photo-absorber materials owing to their low-cost, low toxicity, natural abundance, suitable band-gaps, and favorable band edges for reduction. 
  • 1.4K
  • 08 Nov 2022
Topic Review
Photocatalyzed Production of Urea Using TiO2–Based Materials
Urea has been widely used in the agricultural industry as a fertilizer. It represents more than 50% of the nitrogen fertilizer market, and its global demand has increased more than 100 times in the last decades. In energy terms, urea has been considered a hydrogen–storage (6.71 wt.%) and ammonia–storage (56.7 wt.%) compound, giving it fuel potential. Urea properties meet the requirements of the US Department of Energy for hydrogen–storage substances, meanly because urea crystalizes, allowing storage and safe transportation. Conventional industrial urea synthesis is energy–intensive (3.2–5.5 GJ ton-1) since it requires high pressures and temperatures, so developing a photocatalyzed synthesis using TiO2 (Titanium dioxide) at ambient temperature and pressure is an attractive alternative to conventional synthesis. 
  • 528
  • 04 Aug 2022
Topic Review
Photocatalytic Transformation of Biomass and Biomass Derived Compounds
Biomass and biomass-derived compounds have become an important alternative feedstock for chemical industry. They may replace fossil feedstocks such as mineral oil and related platform chemicals. These compounds may also be transformed conveniently into new innovative bioactive products, for example, for the medicinal or the agrochemical domain.
  • 351
  • 27 Jun 2023
Topic Review
Photocatalytic Proprieties of BiFeO3-Based Materials
Owing to their remarkable success in photocatalytic applications, multiferroic BiFeO3 and its derivatives have gained a highly promising position as electrode materials for future developments of efficient catalysts. In addition to their appropriate band gaps, these materials exhibit inherent intrinsic polarizations enabling efficient charge carrier separation and their high mobility without the need for additional co-catalysts.
  • 329
  • 05 Jan 2024
Topic Review
Photocatalytic Properties of SnO2
SnO2 is an n-type semiconductor with a band gap between 3.6 and 4.0 eV, whose intrinsic characteristics are responsible for its electrical conductivity, good optical characteristics, high thermal stability, and other qualities. Such characteristics have provided excellent results in advanced oxidative processes, i.e., heterogeneous photocatalysis applications. This process involves semiconductors in the production of hydroxyl radicals via activation by light absorption, and it is considered as an emerging and promising technology for domestic-industrial wastewater treatment.
  • 1.5K
  • 05 May 2022
Topic Review
Photocatalytic Oxidation of Methane to Methanol
Methane is one of the promising alternatives to non-renewable petroleum resources since it can be transformed into added-value hydrocarbon feedstocks through suitable reactions. The conversion of methane to methanol with a higher chemical value has recently attracted much attention. The selective oxidation of methane to methanol is often considered a “holy grail” reaction in catalysis. However, methanol production through the thermal catalytic process is thermodynamically and economically unfavorable due to its high energy consumption, low catalyst stability, and complex reactor maintenance. Photocatalytic technology offers great potential to carry out unfavorable reactions under mild conditions. Many in-depth studies have been carried out on the photocatalytic conversion of methane to methanol. 
  • 657
  • 15 Sep 2022
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