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Topic Review Peer Reviewed
Tautomerism of β-Diketones and β-Thioxoketones
The present overview concentrates on recent developments of tautomerism of β-diketones and β-thioxoketones, both in solution and in the solid state. In particular, the latter has been a matter of debate and unresolved problems. Measurements of 13C, 17O, and 2H chemical shifts have been used. Deuterium isotope effects on chemical shifts are proposed as a tool in the study of this problem. Photoconversion of β-diketones and β-thioxoketones are discussed in detail, and the incorporation of β-diketones into molecules with fluorescent properties is assessed. Finally, docking studies of β-diketones are scrutinized with an emphasis on correct tautomeric structures and knowledge about barriers to interconversion of tautomers.
  • 1.6K
  • 10 Mar 2023
Topic Review
Natural Antibacterial Additives in Bioactive Wound Dressings
Wound care is a global health issue with a financial burden of up to US $96.8 billion annually in the USA alone. Chronic non-healing wounds which show delayed and incomplete healing are especially problematic. Natural products and their derivatives have long been a significant source of pharmaceuticals against AMR. Scrutinising the data of newly approved drugs has identified plants as one of the biggest and most important sources in the development of novel antibacterial drugs.
  • 694
  • 10 Mar 2023
Topic Review
Additive Manufacturing Processes Classification
Additive manufacturing is an important and promising process of manufacturing due to its increasing demand in all industrial sectors, with special relevance in those related to metallic components since it permits the lightening of structures, producing complex geometries with a minimum waste of material. There are different techniques involved in additive manufacturing that must be carefully selected according to the chemical composition of the material and the final requirements.
  • 1.3K
  • 10 Mar 2023
Topic Review
Medicinally Viable Plants of the Genus Tylophora
Plants of the genus Tylophora have commonly been used in traditional medicine in various communities, especially in the tropical and subtropical regions of climatic zones. Of the nearly 300 species reported in the Tylophora genus, eight are primarily used in various forms to treat a variety of bodily disorders based on the symptoms. Certain plants from the genus have found use as anti-inflammatory, anti-tumor, anti-allergic, anti-microbial, hypoglycemic, hypolipidemic, anti-oxidant, smooth muscle relaxant, immunomodulatory, and anti-plasmodium agents, as well as free-radical scavengers. Pharmacologically, a few plant species from the genus have exhibited broad-spectrum anti-microbial and anti-cancer activity, which has been proven through experimental evaluations. Some of the plants in the genus have also helped in alcohol-induced anxiety amelioration and myocardial damage repair. The plants belonging to the genus have also shown diuretic, anti-asthmatic, and hepato-protective activities. Tylophora plants have afforded diverse structural bases for secondary metabolites, mainly belonging to phenanthroindolizidine alkaloids, which have been found to treat several diseases with promising pharmacological activity levels. 
  • 547
  • 09 Mar 2023
Topic Review
Solubility of Organic Compounds in Subcritical Water
Data on the solubility and decomposition of organic compounds in subcritical water, a green solvent, are needed in environmental remediation, chemistry, chemical engineering, medicine, polymer, food, agriculture, and many other fields. The solubility of organics is significantly enhanced with increasing water temperature. Likewise, the percentage of organic decomposition also increases with higher temperature.
  • 532
  • 09 Mar 2023
Topic Review
Flexible Textile-Based Sweat Sensors for Wearable Applications
The physical health care system has gradually evolved into a form of virtual hospitals communicating with sensors, which can not only save time but can also diagnose a patient’s physical condition in real time. Textile-based wearable sensors have recently been identified as detection platforms with high potential. They are developed for the real-time noninvasive detection of human physiological information to comprehensively analyze the health status of the human body. Sweat comprises various chemical compositions, which can be used as biomarkers to reflect the relevant information of the human physiology, thus providing references for health conditions. Combined together, textile-based sweat sensors are more flexible and comfortable than other conventional sensors, making them easily integrated into the wearable field. 
  • 715
  • 09 Mar 2023
Topic Review
Smart Mask
The concept of “intelligence” in a material refers to its ability to sense, respond or react to external stimuli or changes in environmental conditions. Heated research interests have focused on the synthesis, optimization and application of materials that can respond to their environment or adjust their properties given external stimuli. Increased involvement of such intelligent or smart materials is witnessed in filtration membrane design. Face masks as wearables with integrated multifunctional sensors that detect human body physiological signals and surrounding environmental status have broadened the practical applications of their conventional function as air filters. 
  • 435
  • 09 Mar 2023
Topic Review
Optical Properties of Carbon Quantum Dots
Carbon quantum dots (CQDs), also known as carbon dots (CDs), are novel zero-dimensional fluorescent carbon-based nanomaterials. CQDs have attracted enormous attention around the world because of their excellent optical properties as well as water solubility, biocompatibility, low toxicity, eco-friendliness, and simple synthesis routes. CQDs have numerous applications in bioimaging, biosensing, chemical sensing, nanomedicine, solar cells, drug delivery, and light-emitting diodes.
  • 779
  • 09 Mar 2023
Topic Review
MXenes as Electrode Materials for Supercapacitors
MXenes have been considered to be potential building blocks for composites for use in energy storage applications due to their distinctive 2D wafer structure and superior electrical conductivity. MXenes have been combined with multiple active ingredients, including metal oxides and conductive polymers, to produce a synergistic effect. The synthesis method of MXene shows various surface termini and topographies with different energy storage properties, and there have been multiple studies examining surface modification, stoichiometric ratio, and electrode composition control.
  • 847
  • 09 Mar 2023
Topic Review
Furane-Based Photoinitiators of Polymerization
Photopolymerization is an active research field enabling to polymerize in greener conditions than that performed with traditional thermal polymerization. A great deal of effort is devoted to developing visible light photoinitiating systems. Indeed, the traditional UV (Ultra Violet) photoinitiating systems are currently the focus of numerous safety concerns so alternatives to UV light are being actively researched. However, visible light photons are less energetic than UV photons so the reactivity of the photoinitiating systems should be improved to address this issue. In this field, furane constitutes an interesting candidate for the design of photocatalysts of polymerization due to its low cost and its easy chemical modification.
  • 421
  • 09 Mar 2023
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