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Topic Review
Biography
Topic Review
Direct Optical Patterning of Semiconductor Quantum Dots
Patterning, stability, and dispersion of the semiconductor quantum dots (scQDs) are three issues strictly interconnected for successful device manufacturing. Several authors adopted direct optical patterning (DOP) as a step forward in photolithography to position the scQDs in a selected area. However, the chemistry behind the stability, dispersion, and patterning has to be carefully integrated to obtain a functional commercial device.
262
13 Jul 2023
Topic Review
Catalysts in Fischer-Tropsch Synthesis
With an increase in energy consumption globally, Fischer-Tropsch (FT) synthesis is a good alternative for producing fuels and chemicals from coal, natural gas or biomass. Among them, coal to liquids has been put into production in countries that have large coal reserves. In this process, Fe-based catalysts are commonly used due to their earth abundance, comparatively wide operation range and ready availability to handle low H2/CO ratio from coal.
416
13 Jul 2023
Topic Review
Electroanalysis of Heavy Metal Ions
The detection of toxic heavy metal ions, especially cadmium (Cd), lead (Pb), zinc (Zn), and copper (Cu), is a global problem due to ongoing pollution incidents and continuous anthropogenic and industrial activities. Therefore, it is important to develop effective detection techniques to determine the levels of pollution from heavy metal ions in various media. Electrochemical techniques, more specifically voltammetry, due to its properties, is a promising method for the simultaneous detection of heavy metal ions.
255
12 Jul 2023
Topic Review
Fabric Phase Sorptive Extraction in Sample Preparation
Fabric phase sorptive extraction (FPSE) is an evolutionary sample preparation approach which was introduced in 2014, meeting all green analytical chemistry (GAC) requirements by implementing a natural or synthetic permeable and flexible fabric substrate to host a chemically coated sol–gel organic–inorganic hybrid sorbent in the form of an ultra-thin coating. This construction results in a versatile, fast, and sensitive micro-extraction device. The user-friendly FPSE membrane allows direct extraction of analytes with no sample modification, thus eliminating/minimizing the sample pre-treatment steps, which are not only time consuming, but are also considered the primary source of major analyte loss. Sol–gel sorbent-coated FPSE membranes possess high chemical, solvent, and thermal stability due to the strong covalent bonding between the fabric substrate and the sol–gel sorbent coating. Subsequent to the extraction on FPSE membrane, a wide range of organic solvents can be used in a small volume to exhaustively back-extract the analytes after FPSE process, leading to a high preconcentration factor.
292
12 Jul 2023
Topic Review
Magnetic Sample Preparation Methods Prior to Liquid Chromatography
Magnetic nanomaterials and nanostructures compose an innovative subject in sample preparation. Most of them are designed according to the properties of the target analytes on each occasion. The unique characteristics of nanomaterials enhance the proficiency at extracting and enriching due to their selective adsorption ability as well as easy separation and surface modification. Their remarkable properties, such as superparamagnetism, biocompatibility and selectivity have established magnetic materials as very reliable options in sample preparation approaches.
187
12 Jul 2023
Topic Review
Crystal Structural Characterization Techniques in Degradation of Perovskite
The general chemical formula of halide perovskite materials is ABX3, where the A site can be occupied by organic cations, such as methyl ammonium (MA), formamidinium (FA), or inorganic cation cesium. The B site can be divalent cations, such as lead(Pb) or tin(Sn), while the X site consists of halide anions, such as chlorine(Cl), bromine(Br) or iodine(I). Due to the great variety of its chemical composition, halide perovskite forms a big material family with tunable optoelectronic properties.
278
12 Jul 2023
Topic Review
Iridium-Catalyzed Difunctionalization of Alkenes
Alkenes and their related analogs are a class of ideal starting materials for the construction of complex molecules, because they are readily available in bulk quantities from renewable resources and petrochemical feedstocks. They are also considered to be the most cost-effective and widely used raw material for organic synthesis, and due to the diversity of functional groups, they are used very frequently in different chemical industries. As basic functionalities, the exploration of efficient methods for the selective functionalization of alkenes has been a continuous pursuit throughout the history of organic chemistry.
440
12 Jul 2023
Topic Review
Decellularized Extracellular Matrix from Different Sources
The decellularized extracellular matrix (dECM) is capable of promoting stem cell proliferation, migration, adhesion, and differentiation. It is a promising biomaterial for application and clinical translation in the field of periodontal tissue engineering as it most effectively preserves the complex array of ECM components as they are in native tissue, providing ideal cues for regeneration and repair of damaged periodontal tissue. dECMs of different origins have different advantages and characteristics in promoting the regeneration of periodontal tissue. dECM can be used directly or dissolved in liquid for better flowability.
360
12 Jul 2023
Topic Review
The Chemical Fingerprint of Fortified Wines
The chemical fingerprint of fortified wines is very complex and fascinating, being constituted by several hundred volatile and non-volatile chemical groups, such as terpenoids, pyrazines, esters, alcohols, acids, furanic compounds, phenolic compounds, and organic acids, among others. These chemical groups were present in fortified wines at different volatilities, polarities, and concentration ranges, from a few ng/L to mg/L. However, the quality of wine also depends on several parameters, such as grape variety, vineyard location, terroir, and vinification conditions (e.g., fermentation, ageing), among others.
728
12 Jul 2023
Topic Review
Phosphonium-Based Polyelectrolytes
Phosphorous is an essential element for the life of organisms, and phosphorus-based compounds have many uses in industry, such as flame retardancy reagents, ingredients in fertilizers, pyrotechnics, etc. Ionic liquids are salts with melting points lower than the boiling point of water. The term “polymerized ionic liquids” (PILs) refers to a class of polyelectrolytes that contain an ionic liquid (IL) species in each monomer repeating unit and are connected by a polymeric backbone to form macromolecular structures. PILs provide a new class of polymeric materials by combining some of the distinctive qualities of ILs in the polymer chain. Ionic liquids have been identified as attractive prospects for a variety of applications due to the high stability (thermal, chemical, and electrochemical) and high mobility of their ions, but their practical applicability is constrained because they lack the benefits of both liquids and solids, suffering from both leakage issues and excessive viscosity. PILs are garnering for developing non-volatile and non-flammable solid electrolytes.
388
12 Jul 2023
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