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Topic Review
Characterization of MXene's Terminations
MXene, 2D transition metal carbides, nitrides, and carbonitrides with a unique 2D structure, inspired a series of function applications related to energy storage and conversion, biometrics and sensing, lighting, purification, and separation. Its surface terminations are confined by the adjacent MXene layers, and form the 2D planar space with symmetrical surfaces, which is similar to a 2D nanoreactor that can be utilized and determined MXene’s function. Accurate characterization of MXene surface terminations is the prerequisite for studying the regulatory methods and the influence of properties and performance. Because the surface termination of MXene presents two-dimensional plane distribution and the collision probability of atoms, molecules, electrons, and optical signals is low. MXene prepared by chemical methods has certain impurity content. In addition, most surface terminations do not exist in a stable state, which leads to the difficulty of the accurate characterization of MXene surface terminations. At present, XPS, EDX, XAS and EELS are often used for qualitative and quantitative analysis of MXene surface terminations.
  • 1.4K
  • 09 Nov 2022
Topic Review
Chemical Beam Epitaxy
Chemical beam epitaxy (CBE) forms an important class of deposition techniques for semiconductor layer systems, especially III-V semiconductor systems. This form of epitaxial growth is performed in an ultrahigh vacuum system. The reactants are in the form of molecular beams of reactive gases, typically as the hydride or a metalorganic. The term CBE is often used interchangeably with metal-organic molecular beam epitaxy (MOMBE). The nomenclature does differentiate between the two (slightly different) processes, however. When used in the strictest sense, CBE refers to the technique in which both components are obtained from gaseous sources, while MOMBE refers to the technique in which the group III component is obtained from a gaseous source and the group V component from a solid source.
  • 490
  • 30 Nov 2022
Topic Review
Chemical Ionization
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. This was first introduced by Burnaby Munson and Frank H. Field in 1966. This technique is a branch of gaseous ion-molecule chemistry. Reagent gas molecules (often methane or ammonia) are ionized by electron ionization to form reagent ions, which subsequently react with analyte molecules in the gas phase to create analyte ions for analysis by mass spectrometry. Negative chemical ionization (NCI), charge-exchange chemical ionization, atmospheric-pressure chemical ionization (APCI) and atmospheric pressure photoionization (APPI) are some of the common variants of the technique. CI mass spectrometry finds general application in the identification, structure elucidation and quantitation of organic compounds as well as some utility in biochemical analysis. Samples to be analyzed must be in vapour form, or else (in the case of liquids or solids), must be vapourized before introduction into the source.
  • 617
  • 28 Nov 2022
Topic Review
Compact Fusion Reactor
The Lockheed Martin Compact Fusion Reactor (CFR) is a proposed nuclear fusion reactor project at Lockheed Martin’s Skunk Works. Its high-beta configuration, which implies that the ratio of plasma pressure to magnetic pressure is greater than or equal to 1 (compared to tokamak designs' 0.05), allows a compact fusion reactor (CFR) design and expedited development. The CFR chief designer and technical team lead, Thomas McGuire studied fusion as a source of space propulsion in response to a NASA desire to improve travel times to Mars.
  • 474
  • 21 Nov 2022
Topic Review
Computational Chemistry Methods
The main objective of computational chemistry is to solve chemical problems by simulating chemical systems (molecular, biological, materials) in order to provide reliable, accurate and comprehensive information at an atomic level. To this end, there are two main methodological families: those based on quantum chemical methods and those based on molecular mechanics. The former are methods in which the electrons are explicitly accounted for, while in the latter their presence is hidden in the force field. 
  • 9.6K
  • 17 Jun 2021
Topic Review
Defects and Heteroatoms and Supported Graphene Layers
The possibility of using graphene-based materials as “metal-free” catalysts is attracting enormous interest, since it reduces the need for precious or rare elements currently used in heterogeneous catalysis. However, free standing  and perfect graphene is known to be “perfectly inert”, while it is now well established that there is an essential role of defects and dopants in activating its chemical properties.
  • 760
  • 02 Apr 2022
Topic Review
Defining Equation
In physics, defining equations are equations that define new quantities in terms of base quantities. This article uses the current SI system of units, not natural or characteristic units.
  • 410
  • 08 Oct 2022
Topic Review
Deformation
In physics, deformation is the continuum mechanics transformation of a body from a reference configuration to a current configuration. A configuration is a set containing the positions of all particles of the body. A deformation can occur because of external loads, intrinsic activity (e.g. muscle contraction), body forces (such as gravity or electromagnetic forces), or changes in temperature, moisture content, or chemical reactions, etc. Strain is related to deformation in terms of relative displacement of particles in the body that excludes rigid-body motions. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the final configuration of the body and on whether the metric tensor or its dual is considered. In a continuous body, a deformation field results from a stress field due to applied forces or because of some changes in the temperature field of the body. The relation between stress and strain is expressed by constitutive equations, e.g., Hooke's law for linear elastic materials. Deformations which cease to exist after the stress field is removed are termed as elastic deformation. In this case, the continuum completely recovers its original configuration. On the other hand, irreversible deformations remain. They exist even after stresses have been removed. One type of irreversible deformation is plastic deformation, which occurs in material bodies after stresses have attained a certain threshold value known as the elastic limit or yield stress, and are the result of slip, or dislocation mechanisms at the atomic level. Another type of irreversible deformation is viscous deformation, which is the irreversible part of viscoelastic deformation. In the case of elastic deformations, the response function linking strain to the deforming stress is the compliance tensor of the material.
  • 3.3K
  • 09 Oct 2022
Topic Review
Deformation (Engineering)
In engineering, deformation refers to the change in size or shape of an object. Displacements are the absolute change in position of a point on the object. Deflection is the relative change in external displacements on an object. Strain is the relative internal change in shape of an infinitesimally small cube of material and can be expressed as a non-dimensional change in length or angle of distortion of the cube. Strains are related to the forces acting on the cube, which are known as stress, by a stress-strain curve. The relationship between stress and strain is generally linear and reversible up until the yield point and the deformation is elastic. The linear relationship for a material is known as Young's modulus. Above the yield point, some degree of permanent distortion remains after unloading and is termed plastic deformation. The determination of the stress and strain throughout a solid object is given by the field of strength of materials and for a structure by structural analysis. Engineering stress and engineering strain are approximations to the internal state that may be determined from the external forces and deformations of an object, provided that there is no significant change in size. When there is a significant change in size, the true stress and true strain can be derived from the instantaneous size of the object. In the figure it can be seen that the compressive loading (indicated by the arrow) has caused deformation in the cylinder so that the original shape (dashed lines) has changed (deformed) into one with bulging sides. The sides bulge because the material, although strong enough to not crack or otherwise fail, is not strong enough to support the load without change. As a result, the material is forced out laterally. Internal forces (in this case at right angles to the deformation) resist the applied load. The concept of a rigid body can be applied if the deformation is negligible.
  • 3.4K
  • 24 Oct 2022
Topic Review
Deformation (Mechanics)
Deformation in continuum mechanics is the transformation of a body from a reference configuration to a current configuration. A configuration is a set containing the positions of all particles of the body. A deformation may be caused by external loads, body forces (such as gravity or electromagnetic forces), or changes in temperature, moisture content, or chemical reactions, etc. Strain is a description of deformation in terms of relative displacement of particles in the body that excludes rigid-body motions. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the final configuration of the body and on whether the metric tensor or its dual is considered. In a continuous body, a deformation field results from a stress field induced by applied forces or is due to changes in the temperature field inside the body. The relation between stresses and induced strains is expressed by constitutive equations, e.g., Hooke's law for linear elastic materials. Deformations which are recovered after the stress field has been removed are called elastic deformations. In this case, the continuum completely recovers its original configuration. On the other hand, irreversible deformations remain even after stresses have been removed. One type of irreversible deformation is plastic deformation, which occurs in material bodies after stresses have attained a certain threshold value known as the elastic limit or yield stress, and are the result of slip, or dislocation mechanisms at the atomic level. Another type of irreversible deformation is viscous deformation, which is the irreversible part of viscoelastic deformation. In the case of elastic deformations, the response function linking strain to the deforming stress is the compliance tensor of the material.
  • 754
  • 20 Oct 2022
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