Topic Review
Soluble Chitosan Derivatives Nanoparticles
Herein, a novel chitosan derivative nanoparticle was proposed to function as a delivery carrier. First of all, an improvement was made to the way N-2-hydroxypropyl trimcthyl ammonium chloride chitosan (N-2-HACC) was synthesized. 
  • 606
  • 02 Dec 2021
Topic Review
Effect of Nano-Additives on PLA/Nanocomposite Properties
Poly(lactic acid) (PLA) is considered the most promising biobased substitute for fossil-derived polymers due to its compostability, biocompatibility, renewability, and good thermomechanical properties. However, PLA suffers from several shortcomings, such as low heat distortion temperature, thermal resistance, and rate of crystallization, whereas some other specific properties, i.e., flame retardancy, anti-UV, antibacterial or barrier properties, antistatic to conductive electrical characteristics, etc., are required by different end-use sectors. The addition of different nanofillers represents an attractive way to develop and enhance the properties of neat PLA. Numerous nanofillers with different architectures and properties have been investigated, with satisfactory achievements, in the design of PLA nanocomposites.
  • 607
  • 21 Mar 2023
Topic Review
Polymer Membranes in Contamination Situations
Depending on the type of contamination, various methods are used, including sorption, biodegradation, separation, or ion exchange processes in which membranes play an important role. The type of membrane is selected in respect of both the environment and the type of neutralized pollutants.
  • 604
  • 17 Jun 2021
Topic Review
General Synthesis Methods of Poly (ε-caprolactone)-Based Graft Copolymers
Synthetic biopolymers are attractive alternatives to biobased polymers, especially because they rarely induce an immune response in a living organism. Poly ε-caprolactone (PCL) is a well-known synthetic aliphatic polyester universally used for many applications, including biomedical and environmental ones.  To expand the range of applications for PCL, researchers have investigated the possibility of grafting polymer chains onto the PCL backbone. As the PCL backbone is not functionalized, it must be first functionalized in order to be able to graft reactive groups onto the PCL chain. These reactive groups will then allow the grafting of new reagents and especially new polymer chains. Grafting of polymer chains is mainly carried out by “grafting from” or “grafting onto” methods.
  • 603
  • 29 Nov 2022
Topic Review
Quinoxaline-Based Photoinitiators of Polymerization
Photopolymerization offers a unique opportunity to convert liquid monomers to polymers using light as the activation source. Major efforts have been devoted to developing visible light photo-initiating systems, and the search for new dyes that can be incorporated into photocurable resins and polymerize a resin within a few seconds is still ongoing.
  • 602
  • 24 Apr 2023
Topic Review
PEDOT-based Catalytic Counter Electrode Material
Dye-sensitized solar cells (DSSCs) emerged in the early 1990s as a promising alternative to the classic silicon-based solar cell due to their unique combination of low cost, ease of fabrication, color palette for building integration, and high efficiency in indoor applications. 
  • 601
  • 08 May 2021
Topic Review
Ionic Hydrogels
Hydrogels are three-dimensional polymer networks with excellent flexibility. Ionic hydrogels have attracted extensive attention in the development of tactile sensors owing to their unique properties, such as ionic conductivity and mechanical properties. These features enable ionic hydrogel-based tactile sensors with exceptional performance in detecting human body movement and identifying external stimuli. Currently, there is a pressing demand for the development of self-powered tactile sensors that integrate ionic conductors and portable power sources into a single device for practical applications.
  • 601
  • 06 Apr 2023
Topic Review
Silicones Renewed for Emerging Applications
Polydimethylsiloxane (PDMS) is the basis of the vast majority of silicone products that have found use in almost all areas of human activity, from cosmetics to the nuclear or aerospace industry. After 80 years from the first direct synthesis of silicones (2020), they still enjoy great interest, both scientific and applicative, being extremely versatile. Polydimethylsiloxane (PDMS), in spite of its well-defined helical structure, is an amorphous fluid even at extremely high molecular weights. The cause of this behavior is the high flexibility of the siloxane backbone and the lack of intermolecular interactions attributed to the presence of methyl groups. These make PDMS incompatible with almost any organic or inorganic component leading to phase separation in copolymers and blends. The material itself is hydrophobic and permeable to gases, with low viscosity, solubility parameters, low glass transition temperature and very low surface tension. This makes the silicones spread very easily, distinguished by their ability to form temporary films and thin coatings to more substantial durable films or with self-leveling and adhesive capacities as stand-alone sheets of different sizes and thickness, from a few micrometers to a few millimeters. One application that is based on this property is the formation of free standing, flexible submicrometric films of interest as active elements in certain devices, such as dielectric elastomer transducers (DETs). Dielectric elastomers (DEs), three-dimensional networks of long and flexible polymer chains, are soft active materials showing promising properties that mimic natural muscle for use in advanced robotics and smart prosthetics, as well as in haptic and microfluidic devices. They enjoy great interest due to their inherent flexibility, large strain, high efficiency, high energy density, and fast response of the material. In addition, some of their properties can be adjusted as required by chemical, physical or combined approaches. 
  • 588
  • 23 Jun 2021
Topic Review
Classification and Application of Natural Polymers
Natural polysaccharides are some of the most extensively used biopolymers in food, pharmaceutical, and medical applications, because they are renewable and have a high level of biocompatibility and biodegradability. The fundamental understanding required to properly exploit polysaccharides potential in the biocomposite, nanoconjugate, and pharmaceutical industries depends on detailed research of these molecules. Polysaccharides are preferred over other polymers because of their biocompatibility, bioactivity, homogeneity, and bioadhesive properties. Natural polysaccharides have also been discovered to have excellent rheological and biomucoadhesive properties, which may be used to design and create a variety of useful and cost-effective drug delivery systems. Polysaccharide-based composites derived from natural sources have been widely exploited due to their multifunctional properties, particularly in drug delivery systems and biomedical applications. These materials have achieved global attention and are in great demand because to their biochemical properties, which mimic both human and animal cells. 
  • 588
  • 07 Feb 2024
Topic Review
Recycling of High-Molecular-Weight Organosilicon Compounds in Supercritical Fluids
The main known patterns of thermal and/or catalytic destruction of high-molecular-weight organosilicon compounds are considered from the viewpoint of the prospects for processing their wastes. The advantages of using supercritical fluids in plastic recycling are outlined in this entry. They are related to a high diffusion rate, efficient extraction of degradation products, the dependence of solvent properties on pressure and temperature, etc. A promising area for further research is described concerning the application of supercritical fluids for processing the wastes of organosilicon macromolecular compounds.
  • 586
  • 14 Dec 2022
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