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Topic Review
Self-Healing Elastomers
It is impossible to describe the recent progress of our society without considering the role of polymers; however, for a broad audience, “polymer” is usually related to environmental pollution. The poor disposal and management of polymeric waste has led to an important environmental crisis, and, within polymers, plastics have attracted bad press despite being easily reprocessable. Nonetheless, there is a group of polymeric materials that is particularly more complex to reprocess, rubbers. These macromolecules are formed by irreversible crosslinked networks that give them their characteristic elastic behavior, but at the same time avoid their reprocessing. Conferring them a self-healing capacity stands out as a decisive approach for overcoming this limitation. By this mean, rubbers would be able to repair or restore their damage automatically, autonomously, or by applying an external stimulus, increasing their lifetime, and making them compatible with the circular economy model.
  • 722
  • 26 May 2022
Topic Review
Hypercrosslinking of Poly(vinylbenzyl chloride) PolyHIPEs
The concept of polymer chain hypercrosslinking was introduced by Davankov, Rogoshin and Tsyurupa, using linear polystyrene or swollen gel-type poly (styrene-co-divinylbenzene) in the presence of an external crosslinker, solvent and a Lewis base as a catalyst.
  • 713
  • 30 Aug 2021
Topic Review
Perfluoropyridine
The fluorine atom exhibits many unique properties, including a small atomic radius, large electronegativity, and minimal polarizability. Thus, when coupled with carbon in the form of a C-F bond, organofluorine compounds with highly sought after properties can be obtained. Perfluoropyridine (PFPy) is an organofluorine compound that has been employed for a variety of applications, from straightforward chemical synthesis to more advanced functions, such as fluorinated networks and polymers. This can be directly attributed to the highly reactive nature of PFPy, especially towards nucleophilic aromatic substitution (SNAr).
  • 713
  • 10 Mar 2022
Topic Review
Filled Polymers and DMA
Dynamic mechanical analysis (DMA) provides reliable information about the viscoelastic behavior of neat and filled polymers. The properties of filled polymers are relevant to different industries as protective organic coatings, composites etc. Interfacial interactions in filled polymers play an important role in determining their bulk properties and performance during service life. In this entry, studies which used DMA to characterize the interfacial interactions in filled polymers have been reviewed.
  • 708
  • 26 Apr 2021
Topic Review
Methods for Reducing Water Absorption of Composite Materials
Plant fiber reinforced polymer matrix composites have attracted much attention in many industries due to their abundant resources, low cost, biodegradability, and lightweight properties. Compared with synthetic fibers, various plant fibers are easy to obtain and have different characteristics, making them a substitute for synthetic fiber composite materials. In order to address the adverse effects of natural fiber moisture absorption on the mechanical properties and dimensional stability of composite materials, researchers have modified fibers through various chemical and physical methods. The various methods to reduce the water absorption of composite materials such as fiber surface chemical treatment, the use of compatibilizers, fiber mixing, nanofillers, and polymer coatings.
  • 706
  • 27 Oct 2023
Topic Review
Bio-Vitrimers for Sustainable Circular Bio-Economy
The traditional polymer circular economy (CE) continues to be challenging due to its reprocessing/recycle ability; also, at the same time, newly developed substitute materials have not expressed similar performance to conventional materials involved in contemporary applications. Hence, linear approaches such as “take-make-use-waste” have severely affected sustainability modules where non-renewable resources have been used at maximum levels. In addition, sustainability is termed along with the circular economy paradigm in recent times, although material sustainability differs from CE material. The circular economy mainly focuses on the economic, environmental and social impacts, whereas sustainability is more about an ecological importance. Globally, frameworks have been formed to enhance the sustainable environment. The United Nations (UN) has designed 17 sustainable development goals to be enforced in all countries in order to reach the goal of a sustainable society by 2030.
  • 705
  • 01 Nov 2022
Topic Review Peer Reviewed
Fluorescence in Smart Textiles
Fluorescence has been identified as an advantageous feature in smart fabrics, notably for the protection of humans during outdoor athletic activities, as well as for preventing counterfeiting and determining authenticity. Fluorescence in smart fabrics is achieved using dendrimers, rare earth metal compounds, and fluorescent dye. The principal method for producing fluorescent fabrics is to immerse the sample in a solution containing fluorescent agents. However, covalent connections between fluorophores and textile substates should be established to improve the stability and intensity of the fluorescent characteristics. Fabric can be fluorescent throughout, or fluorescent fibers can be woven directly into the textile structures, made of natural (cotton, silk) or synthetic (polyamide- and polyester-based) fibers, into a precise pathway that becomes visible under ultraviolet irradiation.
  • 699
  • 14 Nov 2023
Topic Review
Alginate Microparticles for Food, Pharmaceutical and Cosmetic Applications
Alginates are the most widely used natural polymers in the pharmaceutical, food and cosmetic industries. Usually, they are applied as a thickening, gel-forming and stabilizing agent. Moreover, the alginate-based formulations such as matrices, membranes, nanospheres or microcapsules are often used as delivery systems. Alginate microparticles (AMP) are biocompatible, biodegradable and nontoxic carriers, applied to encapsulate hydrophilic active substances, including probiotics.
  • 698
  • 21 Oct 2022
Topic Review
MIPs Preparation by Computational Simulation–Aided
Molecularly imprinted polymers (MIP) are obtained by initiating the polymerization of functional monomers surrounding the template molecule in the presence of crosslinkers and porogens. Usually the best adsorption performance can be obtained by optimizing the polymerization conditions, but the process is time-consuming and labor-intensive. At the same time, the use of a large number of organic reagents in the process of experimental optimization also limits the development and promotion of molecular imprinting technology. Theoretical calculation based on calculation simulation and intermolecular force is an effective method to solve this problem because it is convenient, versatile, environmentally friendly and low in price. It is not affected by the space environment, and the calculation efficiency is high.
  • 697
  • 27 Aug 2021
Topic Review
Polypropylene Extrusion Molding Production Quality
Polypropylene is derived from the reaction of petrochemical propylene gas with a density of 0.89–0.94 g/cm3. It is a lightweight plastic material with a semitransparent white color and has a lower cost than other plastic materials.
  • 696
  • 02 Jun 2022
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