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Topic Review
Ion-selective Electrodes
An Ion-selective electrode (ISE) is a transducer (sensor) which converts the activity of a specific ion dissolved in a solution into an electrical potential which can be measured by a voltmeter or pH meter. The voltage is theoretically dependent on the logarithm of the ionic activity, according to the Nernst equation. The sensing part of the electrode is usually made as an ion-specific membrane, along with a reference electrode. Ion-selective electrodes are used in biochemical and biophysical research, where measurements of ionic concentration in an aqueous solution are required, usually on a real time basis.
  • 1.3K
  • 10 Oct 2022
Topic Review
Ionic and Excited Species
Experimental and theoretical studies of either characterization and reactivity of ionic and excited species with atoms, molecules, and radicals of interest in the chemistry of plasmas and energy production. Single and ionized species with single or multiple charge (H+, He+, H3+, HCO+, H3O+, He22+, CO22+, etc.), excited atoms and molecules (e.g. O(1D), N(2D), H*(2s2S1/2), He*(21,3S0,1), N2*(A3Σu+), etc.) play a crucial role in various important chemical systems such as flames (i.e. chemi-ionizations), natural plasmas (i.e. planetary ionospheres, comet tails and interstellar clouds), and biological environments (e.g. damaged biological tissues via the interaction between ionizing radiation and living cells). Such processes are very interesting from a fundamental point of view in Physical Chemistry and attracted the attention of a wide scientific community, since many applications to important fields: radiation chemistry, plasma physics and chemistry, combustion processes, development of laser sources. In particular, the conversion of waste carbon dioxide via assisted plasma technology gained recently increasing interest due to the possibility of obtaining value-added products, like gaseous or liquid fuels. Such characteristics make this an encouraging strategy for the storage of electrical energy from renewable sources into chemical energy in a circular economy scheme.
  • 1.4K
  • 01 Nov 2020
Topic Review
Ionising Radiation Sensors
Ionising radiation affects electronic circuits as well as living beings and has been a major concern for various critical applications such as healthcare, mining, avionics, nuclear, high-energy physics, and space applications. Radiation sensors are essential tools to estimate, measure and characterise radiation related information to assess the system performance and subsequently look for corrective measures. 
  • 886
  • 23 Sep 2021
Topic Review
Ionizing Irradiations in Food Industry
The ionizing radiations are particles or waves containing enough energy to ionize the matter when coming in contact. Their mode of action in living cells involves either the direct destruction of nucleic acid or by creating free radicals that can attack the cellular components. This cellular destruction and inactivation can be used to reduce the microbial burden in food items to increase the shelf life and safety of food, meanwhile maintaining the quality of the product. Although this technology is accepted by more than 60 countries, some consumers are reluctant to buy such products thinking that radiations might have modified their food which can also induce changes in their body after consumption. The proper scientific communication regarding the safety of ionization irradiations can change consumer behavior, and it requires the collaboration of all stakeholders in the food production chain. 
  • 2.1K
  • 05 Nov 2020
Topic Review
Ionizing Radiation
The development of protective agents against harmful radiations has been a subject of investigation for decades. However, effective (ideal) radioprotectors and radiomitigators remain an unsolved problem. Because ionizing radiation-induced cellular damage is primarily attributed to free radicals, radical scavengers are promising as potential radioprotectors. Early development of such agents focused on thiol synthetic compounds, e.g., amifostine (2-(3-aminopropylamino) ethylsulfanylphosphonic acid), approved as a radioprotector by the Food and Drug Administration (FDA, USA) but for limited clinical indications and not for nonclinical uses. To date, no new chemical entity has been approved by the FDA as a radiation countermeasure for acute radiation syndrome (ARS). All FDA-approved radiation countermeasures (filgrastim, a recombinant DNA form of the naturally occurring granulocyte colony-stimulating factor, G-CSF; pegfilgrastim, a PEGylated form of the recombinant human G-CSF; sargramostim, a recombinant granulocyte macrophage colony-stimulating factor, GM-CSF) are classified as radiomitigators. No radioprotector that can be administered prior to exposure has been approved for ARS. This differentiates radioprotectors (reduce direct damage caused by radiation) and radiomitigators (minimize toxicity even after radiation has been delivered). Molecules under development with the aim of reaching clinical practice and other nonclinical applications are discussed. Assays to evaluate the biological effects of ionizing radiations are also analyzed. Ionizing radiation is the energy released by atoms in the form of electromagnetic waves (e.g., X or gamma rays) or particle radiation (alpha, beta, electrons, protons, neutrons, mesons, prions, and heavy ions) with sufficient energy to ionize atoms or molecules.
  • 1.9K
  • 23 Feb 2022
Topic Review
Isotopes of Osmium
Osmium (76Os) has seven naturally occurring isotopes, five of which are stable: 187Os, 188Os, 189Os, 190Os, and (most abundant) 192Os. The other natural isotopes, 184Os, and 186Os, have extremely long half-life (1.12×1013 years and 2×1015 years, respectively) and for practical purposes can be considered to be stable as well. 187Os is the daughter of 187Re (half-life 4.56×1010 years) and is most often measured in an 187Os/188Os ratio. This ratio, as well as the 187Re/188Os ratio, have been used extensively in dating terrestrial as well as meteoric rocks. It has also been used to measure the intensity of continental weathering over geologic time and to fix minimum ages for stabilization of the mantle roots of continental cratons. However, the most notable application of Os in dating has been in conjunction with iridium, to analyze the layer of shocked quartz along the Cretaceous–Paleogene boundary that marks the extinction of the dinosaurs 66 million years ago. There are also 30 artificial radioisotopes, the longest-lived of which is 194Os with a half-life of six years; all others have half-lives under 94 days. There are also nine known nuclear isomers, the longest-lived of which is 191mOs with a half-life of 13.10 hours. All isotopes and nuclear isomers of osmium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.
  • 461
  • 27 Oct 2022
Topic Review
Isotopes of Unbiunium
Check temperatures Ubu: no input for C, K, F. Check temperatures Ubu: no input for C, K, F. Unbiunium, also known as eka-actinium or simply element 121, is the hypothetical chemical element with symbol Ubu and atomic number 121. Unbiunium and Ubu are the temporary systematic IUPAC name and symbol respectively, until a permanent name is decided upon. In the periodic table of the elements, it is expected to be the first of the superactinides, and the third element in the eighth period: analogously to lanthanum and actinium, it could be considered the fifth member of group 3 and the first member of the fifth-row transition metals. It has attracted attention because of some predictions that it may be in the island of stability, although newer calculations expect the island to actually occur at a slightly lower atomic number, closer to copernicium and flerovium. Unbiunium has not yet been synthesized. Nevertheless, because it is only three elements away from the heaviest known element, oganesson (element 118), its synthesis may come in the near future; it is expected to be one of the last few reachable elements with current technology, and the limit may be anywhere between element 120 and 124. It will also likely be far more difficult to synthesize than the elements known so far up to 118, and still more difficult than elements 119 and 120. The team at RIKEN in Japan has plans to attempt the synthesis of element 121 in the future after its attempts on elements 119 and 120. The position of unbiunium in the periodic table suggests that it would have similar properties to its lighter congeners, scandium, yttrium, lanthanum, and actinium; however, relativistic effects may cause some of its properties to differ from those expected from a straight application of periodic trends. For example, unbiunium is expected to have a s2p valence electron configuration instead of the s2d of its lighter congeners in group 3, but this is not expected to significantly affect its chemistry, which is predicted to be that of a normal group 3 element; it would on the other hand significantly lower its first ionisation energy beyond what would be expected from periodic trends.
  • 846
  • 26 Oct 2022
Topic Review
J/Psi Meson
The J/ψ (J/psi) meson /ˈdʒeɪ ˈsaɪ ˈmiːzɒn/ or psion is a subatomic particle, a flavor-neutral meson consisting of a charm quark and a charm antiquark. Mesons formed by a bound state of a charm quark and a charm anti-quark are generally known as "charmonium". The J/ψ is the most common form of charmonium, due to its spin of 1 and its low rest mass. The J/ψ has a rest mass of 3.0969 GeV/c2, just above that of the ηc (2.9836 GeV/c2), and a mean lifetime of 7.2×10−21 s. This lifetime was about a thousand times longer than expected. Its discovery was made independently by two research groups, one at the Stanford Linear Accelerator Center, headed by Burton Richter, and one at the Brookhaven National Laboratory, headed by Samuel Ting of MIT. They discovered they had actually found the same particle, and both announced their discoveries on 11 November 1974. The importance of this discovery is highlighted by the fact that the subsequent, rapid changes in high-energy physics at the time have become collectively known as the "November Revolution". Richter and Ting were awarded the 1976 Nobel Prize in Physics.
  • 1.2K
  • 09 Nov 2022
Topic Review
Jerk
In physics, jerk or jolt is the rate at which an object's acceleration changes with respect to time. It is a vector quantity (having both magnitude and direction). Jerk is most commonly denoted by the symbol j and expressed in m/s3 (SI units) or standard gravities per second (g0/s).
  • 917
  • 01 Nov 2022
Topic Review
Jet Flavour Tagging
Jet Flavour Tagging briefly describes the main algorithms used to reconstruct heavy-flavour jets. Jet Substructure and Deep Tagging focuses on the identification of heavy-particle decay in boosted jets. These so-called tagger algorithms have a relevant role in physics studies since they allow researchers to successfully reconstruct and identify the particles that caused the jet and, in some cases, allow analyses that would otherwise be unfeasible.
  • 470
  • 09 Nov 2022
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