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Topic Review
Biography
Topic Review
Laser-Induced Breakdown Spectroscopy for Food Quality Evaluation
Laser-induced Breakdown Spectroscopy (LIBS) is becoming an increasingly popular analytical technique for characterizing and identifying various products; its multi-element analysis, fast response, remote sensing, and sample preparation is minimal or nonexistent, and low running costs can significantly accelerate the analysis of foods with medicinal properties (FMPs).
682
28 Jul 2022
Topic Review
Laser-Induced Breakdown Spectroscopy in Elemental Analysis
Laser-induced breakdown spectroscopy (LIBS) has evolved considerably in recent years, particularly the application of portable devices for the elemental analysis of solids in the field. However, aqueous analysis using LIBS instruments, either in the laboratory or in the field, is rather rare, despite extensive research on the topic since 1984. To achieve this, researchers examined the literature published between 1984 and 2023, comparing various settings and parameters in a database. There are four different categories of LIBS instruments: laboratory-based, online, portable, and telescopic. Additionally, there are four main categories of sample preparation techniques: liquid bulk, liquid-to-solid conversion, liquid-to-aerosol conversion, and hydride generation. Various experimental setups are also in use, such as double-pulse. Moreover, different acquisition settings significantly influence the sensitivity and therefore the detection limits. Documentation of the different methods of sample preparation and experimental settings, along with their main advantages and disadvantages, can help new users make an informed choice for a particular desired application. In addition, the presentation of median detection limits per element in a periodic table of elements highlights possible research gaps and future research opportunities by showing which elements are rarely or not analysed and for which new approaches in sample preparation are required to lower the detection limits.
320
29 Jan 2024
Topic Review
Last Deglaciation Rainfall Changes
Three drier periods (lower rainfall) (i.e., before ~17, ~1513.5, and 7–3 ka BP) and three wetter periods (higher rainfall) (i.e., ~17–15, ~13.5–7, and after ~3 ka BP) were detected on Southern Indonesia (off southwest Sumba) based on geochemical element (terrigenous input) proxies (ln Ti/Ca and K/Ca). During the Last Deglaciation, AISM rainfall responded to high latitude climatic events related to the latitudinal shifts of the austral summer ITCZ. Sea level rise, solar activity, and orbitally-induced insolation were most likely the primary driver of AISM rainfall changes during the Holocene, but the driving mechanisms behind the latitudinal shifts of the austral summer ITCZ during this period are not yet understood.
754
27 Jan 2022
Topic Review
Last Glacial Period
The last glacial period occurred from the end of the Eemian interglacial to the end of the Younger Dryas, encompassing the period c. 115,000 – c. 11,700 years ago. This most recent glacial period is part of a larger pattern of glacial and interglacial periods known as the Quaternary glaciation extending from c. 2,588,000 years ago to present. The definition of the Quaternary as beginning 2.58 Ma is based on the formation of the Arctic ice cap. The Antarctic ice sheet began to form earlier, at about 34 Ma, in the mid-Cenozoic (Eocene–Oligocene extinction event). The term Late Cenozoic Ice Age is used to include this early phase. During this last glacial period there were alternating episodes of glacier advance and retreat. Within the last glacial period the Last Glacial Maximum was approximately 22,000 years ago. While the general pattern of global cooling and glacier advance was similar, local differences in the development of glacier advance and retreat make it difficult to compare the details from continent to continent (see picture of ice core data below for differences). Approximately 13,000 years ago, the Late Glacial Maximum began. The end of the Younger Dryas about 11,700 years ago marked the beginning of the Holocene geological epoch, which includes the Holocene glacial retreat. From the point of view of human archaeology, the last glacial period falls in the Paleolithic and early Mesolithic periods. When the glaciation event started, Homo sapiens were confined to lower latitudes and used tools comparable to those used by Neanderthals in western and central Eurasia and by Homo erectus in Asia. Near the end of the event, Homo sapiens migrated into Eurasia and Australia. Archaeological and genetic data suggest that the source populations of Paleolithic humans survived the last glacial period in sparsely wooded areas and dispersed through areas of high primary productivity while avoiding dense forest cover. The retreat of the glaciers 15,000 years ago allowed groups of humans from Asia to migrate to the Americas.
5.4K
21 Oct 2022
Topic Review
Late Devonian Extinction
The Late Devonian extinction was one of five major extinction events in the history of life on Earth. A major extinction, the Kellwasser event, occurred at the boundary that marks the beginning of the last phase of the Devonian period, the Famennian faunal stage (the Frasnian–Famennian boundary), about 376–360 million years ago. Overall, 19% of all families and 50% of all genera became extinct. A second, distinct mass extinction, the Hangenberg event, closed the Devonian period. Although it is clear that there was a massive loss of biodiversity in the Late Devonian, the timespan of this event is uncertain, with estimates ranging from 500,000 to 25 million years, extending from the mid-Givetian to the end-Famennian. Nor is it clear whether there were two sharp mass extinctions or a series of smaller extinctions, though the latest research suggests multiple causes and a series of distinct extinction pulses during an interval of some three million years. Some consider the extinction to be as many as seven distinct events, spread over about 25 million years, with notable extinctions at the ends of the Givetian, Frasnian, and Famennian stages. By the Late Devonian, the land had been colonized by plants and insects. In the oceans were massive reefs built by corals and stromatoporoids. Euramerica and Gondwana were beginning to converge into what would become Pangaea. The extinction seems to have only affected marine life. Hard-hit groups include brachiopods, trilobites, and reef-building organisms; the reef-building organisms almost completely disappeared. The causes of these extinctions are unclear. Leading hypotheses include changes in sea level and ocean anoxia, possibly triggered by global cooling or oceanic volcanism. The impact of a comet or another extraterrestrial body has also been suggested, such as the Siljan Ring event in Sweden. Some statistical analysis suggests that the decrease in diversity was caused more by a decrease in speciation than by an increase in extinctions. This might have been caused by invasions of cosmopolitan species, rather than by any single event. Surprisingly, jawed vertebrates seem to have been unaffected by the loss of reefs or other aspects of the Kellwasser event, while agnathans were in decline long before the end of the Frasnian.
2.9K
30 Nov 2022
Topic Review
Late Glacial
The Late Glacial climate warming (c. 13,000–10,000 years ago), or Tardiglacial ("Late Glacial"), is defined primarily by the beginning of the modern warm period, in which temperatures in the Northern Hemisphere rose substantially, causing a process of accelerated deglaciation following the Last Glacial Maximum (c. 25,000–13,000 years ago). At this time, human populations, previously forced into refuge areas as a result of Last Glacial Maximum (LGM) climatic conditions, gradually begin to repopulate the Northern Hemisphere's Eurasian landmass and eventually populate North America via Beringia for the first time. The Late Glacial Interstadial c.14,670 to c.12,890 BP represents the first pronounced warming since the end of the LGM. Evidence for its occurrence stems from two main types of analysis. The first is the use of oxygen isotope stages (OIS) gathered from stratified deep-sea sediment cores. Samples are gathered and measured for change in isotope levels to determine temperature fluctuation for given periods of time. The second is a proxy measurement, the observation of certain reappearing fauna and flora fossils that can survive only in temperate climates, thus indicating warming trends for a given geographic area. Archaeological evidence of settlement and resettlement in certain areas by humans also serve as proxy measurements. Towards the end of OIS 2 in which the Late Glacial Maximum occurs, the deep-sea sediment cores indicate a gradually warming climate, and the reappearance of certain warm-weather flora and fauna remains throughout the Northern Hemisphere correlate with that trend. The Late Glacial was interrupted by a severe decline in temperatures during the Younger Dryas from c.12,890 to c.11,650 BP.
686
17 Nov 2022
Topic Review
Late Glacial Interstadial
The Late Glacial Interstadial (LGI) c.14,670 to c.12,890 BP represents the first pronounced warming since the end of the Last Glacial Maximum (LGM). Human populations, which had previously forced into refuge areas, gradually begin to repopulate the Northern Hemisphere's Eurasian landmass and eventually populate North America via Beringia for the first time. Evidence for its occurrence stems from two main types of analysis. The first is the use of oxygen isotope stages (OIS) gathered from stratified deep-sea sediment cores. Samples are gathered and measured for change in isotope levels to determine temperature fluctuation for given periods of time. The second is a proxy measurement, the observation of certain reappearing fauna and flora fossils that can survive only in temperate climates, thus indicating warming trends for a given geographic area. Archaeological evidence of settlement and resettlement in certain areas by humans also serve as proxy measurements. Towards the end of OIS 2 in which the Last Glacial Maximum occurs, the deep-sea sediment cores indicate a gradually warming climate, and the reappearance of certain warm-weather flora and fauna remains throughout the Northern Hemisphere correlate with that trend. The Late Glacial Interstadial was followed by a severe decline in temperatures during the Younger Dryas from c.12,890 to c.11,650 BP.
584
14 Nov 2022
Topic Review
Late Permian Coals
This study reports the mineralogy and geochemistry of the Late Permian C1 Coal from Bole and Laibin mines in eastern Yunnan, Southwestern China (C1 Coal in Laibin mine is composed of three layers termed B1, B2, and B3). The coals are characterized by medium-high ash yields and very low sulfur contents. Compared with average values of trace element concentrations in hard coals worldwide, the Bole and Laibin coals are enriched in V, Co, Cu, Zn, and Se, which were mainly derived from the sediment-source region of the Kangdian Upland. Major minerals in the coal samples and roof and floor strata include quartz, interstratified berthierine/chamosite (B/C), as well as kaolinite, mixed layer illite/smectite, calcite, pyrite, and anatase. Unlike a pure chamosite, the 7 Å peak of interstratified B/C is sharp and narrow, while the 14 Å peak is broad and weak, or absent in some coal samples. Interstratified B/C was largely precipitated from low-temperature Fe-rich and Mg-rich hydrothermal fluids or, in some cases, is an alteration product of kaolinite. Secondary phases of quartz, calcite, pyrite, kaolinite, chalcopyrite, gypsum, and REE-phosphates in the coal samples are the dominant authigenic minerals formed at syngenetic and early diagenetic stages. Four intra-seam partings in C1 Coal, B1, and B3 layers are identified as tonsteins derived from felsic volcanic ashes. These tonsteins consist mainly of cryptocrystalline kaolinite with graupen and vermicular textures, and minor amounts of high-temperature quartz, zircon, apatite, monazite, and anatase. The floor of the C1 Coal in the Bole mine is a tuffaceous claystone and consists of altered high-Ti basalt volcaniclastics, characterized by high concentrations of Zr, Nb, V, Co, Cu, and Zn, low Al2O3/TiO2 ratio (~4.62), high Ti/Y ratio (~900), enrichment of middle rare earth elements, and positive Eu anomalies.
801
19 Jan 2021
Topic Review
Late Renaissance Garden Units
The use of plants in Renaissance gardens is the subject of numerous studies and essays on botanical history in Europe. A garden unit was defined as a garden or garden section with distinct denomination and function (plant use). In the case of “Type A” sites, it can be identified as a total of three characteristic garden units on the basis of the archives, which occurred regularly in the examined Late Renaissance gardens: flower garden, vegetable garden, and orchard.
344
25 May 2023
Topic Review
Lattice Boltzmann Method
Biofilm growth and evolution are very complex interactions among physicochemical and biological processes. Mathematical models are critical to modern biotechnology—both in research and in the engineering practice. Thus, many models of biofilms have been developed to include various biofilm reactor modules. However, considerable challenges exist in modelling microbial processes where mesoscopic dynamics of nutrient transport must be coupled with microscopic bacteria growth and their elementary biochemical reactions at reactive or enzymatic interfaces, in addition to the microbiological and/or ecological aspects of the “micro” organisms involved in biofilms. Lattice Boltzmann Method (LBM) treats flows in terms of fictive parcels of particles which reside on a mesh and conduct translation according to collision steps entailing overall fluid-like behavior. The goal of this review is to discuss and identify the opportunities of applying different LBM-based models to specific areas of biofilm research as well as unique challenges that LBM-based models must overcome.
771
19 Jul 2021
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