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Topic Review
Bulk and Microfluidic-Based pH Sensors
The determination of pH is of paramount importance in environmental, pharmaceutical, and medicinal sciences, etc., for accurate controlling, monitoring, and adjusting whole processes on microscale and macroscale. Therefore, the pH measurements have drawn continuous efforts from a great deal of research. The bulk pH determination can tackle part of the demands from laboratories and industrial applications.
  • 496
  • 01 Dec 2022
Topic Review
Bulk Preparation Technologies in Food Packaging Applications
Active packaging has played a significant role in consumers’ health and green environment. Synthetic polymers, such as poly(ethylene terephthalate) (PET), polyethylene (PE), polypropylene (PP), polystyrene (PS), poly(vinyl chloride) (PVC), polycarbonate (PC), poly(lactic acid) (PLA), etc., and naturally derived ones, such as cellulose, starch, chitosan, etc., are extensively used as packaging materials due to their broad range of desired properties (transparence, processability, gas barrier properties, mechanical strength, etc.). The food packaging field has been challenged to deliver food products free from microbes that cause health hazards. However, most of the used polymers lack such properties. Owing to this, active agents such as antimicrobial agents and antioxidants have been broadly used as potential additives in food packaging substrates, to increase the shelf life, the quality and the safety of food products. Both synthetic active agents, such as Ag, Cu, ZnO, TiO2, nanoclays, and natural active agents, such as essential oils, catechin, curcumin, tannin, gallic acid, etc., exhibit a broad spectrum of antimicrobial and antioxidant effects, while restricting the growth of harmful microbes. Various bulk processing techniques have been developed to produce appropriate food packaging products and to add active agents on polymer matrices or on their surface. Among these techniques, extrusion molding is the most used method for mass production of food packaging with incorporated active agents into polymer substrates, while injection molding, thermoforming, blow molding, electrospinning, etc., are used to a lower extent.
  • 540
  • 27 Dec 2022
Topic Review
Buried Interface of Perovskite Solar Cells
Perovskite solar cells (PSCs) have been developed rapidly in recent years because of their excellent photoelectric performance. However, interfacial non-radiative recombination hinders the improvement of device performance. The buried interface modification strategy can minimize the non-radiation recombination in the interface and can obtain the high efficiency and stability of PSCs.
  • 328
  • 31 Jul 2023
Topic Review
Burn Pathophysiology
Burns are a widespread global public health traumatic injury affecting many people worldwide. Non-fatal burn injuries are a leading cause of morbidity, resulting in prolonged hospitalization, disfigurement, and disability, often with resulting stigma and rejection. The treatment of burns is aimed at controlling pain, removing dead tissue, preventing infection, reducing scarring risk, and tissue regeneration. 
  • 1.3K
  • 26 May 2023
Topic Review
C-,N- and S-Doped TiO2 Photocatalysts
This entry describes the basics of photocatalysis. It also presents properties and applications of C-,N- and S-Doped TiO2 as a photocatalyst.
  • 887
  • 28 May 2021
Topic Review
C-C and C-Heteroatom Bonds Construction
Acyl-containing organic compounds, including ketones, esters, amides, and so forth, are a huge library of widespread chemical feedstocks which play a vital role in countless fields such as pharmaceuticals, natural products, advanced materials, and fine chemicals.
  • 495
  • 28 Dec 2022
Topic Review
C–H Functionalisation
C–H bond functionalisation describes the transformation of a C-H bonds into a C-X bonds (X = C, N, O, B, halides, among many others). The term is typically associated with transition metals in processes like C-H activation. However, other methods such as nitrene/carbene insertion and hydrogen atom transfer (HAT) can also be used to functionalise C-H bonds with varying selectivity and ability to introduce different functional groups depending on the method used. 
  • 347
  • 09 Nov 2023
Topic Review
C,C- and C,N-Chelated Organocopper Compounds
Copper-catalyzed and organocopper-involved reactions are of great significance in organic synthesis. To have a deep understanding of the reaction mechanisms, the structural characterizations of organocopper intermediates become indispensable. Meanwhile, the structure-function relationship of organocopper compounds could advance the rational design and development of new Cu-based reactions and organocopper reagents. Compared to the mono-carbonic ligand, the C,N- and C,C-bidentate ligands better stabilize unstable organocopper compounds. Bidentate ligands can chelate to the same copper atom via η2-mode, forming a mono-cupra-cyclic compounds with at least one acute C-Cu-C angle. When the bidentate ligands bind to two copper atoms via η1-mode at each coordinating site, the bimetallic macrocyclic compounds will form nearly linear C-Cu-C angles. The anionic coordinating sites of the bidentate ligand can also bridge two metals via μ2-mode, forming organocopper aggregates with Cu-Cu interactions and organocuprates with contact ion pair structures. The reaction chemistry of some selected organocopper compounds is highlighted, showing their unique structure–reactivity relationships.
  • 673
  • 08 Oct 2021
Topic Review
CAD Algorithms for Adjusting Contours
In patients with atrophy of the temporalis muscle or flattened skin flaps (trephined syndrome), CAD/CAM (customized computer-assisted design/manufacturing)-fabricated implants with modified reconstructed curvature is crucial for cranioplasty. For the aforementioned clinical conditions, adequate scalp adaptation is significant for either the maintenance of soft tissue bulk or the prevention of the dead space between the dura and implant. This can thoroughly be achieved by adjusting CAD algorithms for the contouring of skull defects with outwardly elevation or inwardly depression, respectively. We herein demonstrate operative details involving modified contours for the reconstruction of skull defects in CAD Modeling.
  • 1.2K
  • 29 Oct 2020
Topic Review
CAD/CAM Ceramics
CAD/CAM ceramics present a promising alternative to metal-ceramic fixed dental prostheses.
  • 780
  • 23 Jun 2021
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