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Topic Review
Logic Gates and Molecular Logic Gates
Logic gates are devices used to perform binary arithmetic and logical operations and thus constitute the basis of modern computers. They perform Boolean logic operations on one or more inputs to produce an output. Molecular switches convert input stimulations into output signals. Therefore, the principles of binary logic can be applied to the signal transduction operated by molecular switches. The presence of various ions, neutral species, pH, temperature, and viscosity, among many others, result in color or emission changes due to the complex interplay of many excited state processes and environmental parameters. In this entry, basic logic gates are defined, and their types are given, while examples of molecular logic gates are also presented.
  • 425
  • 29 Mar 2024
Topic Review
LnBaCo2O5+δ
Solid oxide fuel cells (SOFCs) represent a breed of eco-friendly, weather-independent, decentralized power generation technologies, distinguished for their broad fuel versatility and superior electricity generation efficiency. 
  • 366
  • 20 Sep 2023
Topic Review
Living Anionic Polymerization
Living anionic polymerization is a living polymerization technique involving an anionic propagating species. Living anionic polymerization was demonstrated by Szwarc and co workers in 1956. Their initial work was based on the polymerization of styrene and dienes. One of the remarkable features of living anionic polymerization is that the mechanism involves no formal termination step. In the absence of impurities, the carbanion would still be active and capable of adding another monomer. The chains will remain active indefinitely unless there is inadvertent or deliberate termination or chain transfer. This gave rise to two important consequences: The following experimental criteria have been proposed as a tool for identifying a system as living polymerization system. However, in practice, even in the absence of terminating agents, the concentration of the living anions will reduce with time due to a decay mechanism termed as spontaneous termination.
  • 1.5K
  • 31 Oct 2022
Topic Review
Lithium−Sulfur Pouch Cells
Strategies to enhance sulfur loading and utilization and compaction of the cathode are crucial objectives in accelerating the industrial realization of Li–S pouch cells.
  • 740
  • 29 Nov 2021
Topic Review
Lithium-Sulfur Redox Battery
The lithium-sulfur (Li-S) redox battery system is considered to be the most promising next-generation energy storage technology due to its high theoretical specific capacity (1673 mAh/g), high energy density (2600 Wh/kg), low cost, and environmentally friendly nature of sulfur. Though this system is deemed to be the next-generation energy storage device for portable electronics and electric vehicles, its poor cycle life, low coulombic efficiency, and low rate capability limit it from practical applications. These performance barriers were linked to several issues like polysulfide (LiPS) shuttle, inherent low conductivity of charge/discharge end products, and poor redox kinetics. Here, we review the recent developments made to alleviate these problems through an electrocatalysis approach, which is considered to be an effective strategy not only to trap the LiPS but also to accelerate their conversion reactions kinetics. Herein, the influence of different chemical interactions between the LiPS and the catalyst surfaces and their effect on the conversion of liquid LiPS to solid end products are reviewed. Finally, we also discussed the challenges and perspectives for designing cathode architectures to enable high sulfur loading along with the capability to rapidly convert the LiPS.
  • 1.5K
  • 21 Oct 2020
Topic Review
Lithium Silicates in Anode Materials
The structural and interfacial stability of silicon-based and lithium metal anode materials is essential to their battery performance. Scientists are looking for a better inactive material to buffer strong volume change and suppress unwanted surface reactions of these anodes during cycling. Lithium silicates formed in situ during the formation cycle of silicon monoxide anode not only manage anode swelling but also avoid undesired interfacial interactions, contributing to the successful commercialization of silicon monoxide anode materials. Additionally, lithium silicates have been further utilized in the design of advanced silicon and lithium metal anodes, and the results have shown significant promise in the past few years.
  • 458
  • 26 Jan 2022
Topic Review
Lithium Metal Anodes with Three-Dimensional Lithium Hosts
Li metal has emerged as a promising anode material for high energy density batteries, due to its low electrochemical potential and high specific capacity of 3860 mAh·g−1. These characteristics make it an attractive choice for electric vehicles and power grids.
  • 421
  • 10 Aug 2023
Topic Review
List of UN Numbers 3301 to 3400
The UN numbers from UN3301 to UN3400 as assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods.
  • 323
  • 02 Nov 2022
Topic Review
List of Oxidation States of the Elements
This is a list of known oxidation states of the chemical elements, excluding nonintegral values. The most common states appear in bold. The table is based on that of Greenwood and Earnshaw, with additions noted. Oxidation state 0, which occurs for all elements, is implied by the column with the symbol of the element. The format of the table, which was devised by Dmitri Mendeleev in 1889, shows the periodicity of the oxidation states of the elements.
  • 13.1K
  • 18 Oct 2022
Topic Review
List of Adrenergic Drugs
This is a list of adrenergic drugs. These are pharmaceutical drugs, naturally occurring compounds and other chemicals that influence the function of the neurotransmitter epinephrine (adrenaline).
  • 697
  • 21 Oct 2022
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