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Topic Review
Application of Biobased Solvents in Asymmetric Catalysis
The application of the so-called green solvents has emerged as a useful alternative to the classical organic solvents. These solvents must present some properties, such as a low vapor pressure and toxicity, high boiling point and biodegradability, and must be obtained from renewable sources.
  • 560
  • 12 Oct 2022
Topic Review
Medicinal Potential of Isoflavonoids
In recent years, there is emerging evidence that isoflavonoids could play an important role in the management of type 2 diabetes mellitus (T2DM) due to their reported pronounced biological effects in relation to multiple metabolic factors associated with diabetes. Hence, in this regard, we have comprehensively reviewed the potential biological effects of isoflavonoids, particularly biochanin A, genistein, daidzein, glycitein, and formononetin on metabolic disorders and long-term complications induced by T2DM in order to understand whether they can be future candidates as a safe antidiabetic agent. Based on in-depth in vitro and in vivo studies evaluations, isoflavonoids have been found to activate gene expression through the stimulation of peroxisome proliferator-activated receptors (PPARs) (α, γ), modulate carbohydrate metabolism, regulate hyperglycemia, induce dyslipidemia, lessen insulin resistance, and modify adipocyte differentiation and tissue metabolism. Moreover, these natural compounds have also been found to attenuate oxidative stress through the oxidative signaling process and inflammatory mechanism. Hence, isoflavonoids have been envisioned to be able to prevent and slow down the progression of long-term diabetes complications including cardiovascular disease, nephropathy, neuropathy, and retinopathy. 
  • 559
  • 28 Sep 2021
Topic Review
Chitosan Nanocomposite Coatings
Functional nanocomposites with biopolymers and zinc oxide (ZnO) nanoparticles is an emerging application of photocatalysis in antifouling coatings. The reduced chemical stability of ZnO photocatalyst in the acidic media in which chitosan is soluble affects the performance of chitosan nanocomposites in antifouling applications. In this study, a thin shell of amorphous tin oxide (SnOx) was grown on the surface of ZnO to form ZnO–SnOx core–shell nanoparticles that improved the chemical stability of the photocatalyst, as examined at pH 3 and 6. The photocatalytic activity of ZnO–SnOx in the degradation of methylene blue (MB) dye under visible light showed a higher efficiency than that of ZnO nanoparticles due to improved electron-hole separation. Meanwhile, the incorporation of photocatalysts into the chitosan matrix enhanced the thermal stability of the coatings. Chitosan-based antifouling coatings with varying percentages of ZnO or ZnO–SnOx nanoparticles, with or without the glutaraldehyde (GA) crosslinking of chitosan, were developed and studied for the prevention of biofouling. 
  • 559
  • 19 May 2021
Topic Review
Nanotechnology-Based Techniques for Sensing Amino Acids/Peptides/Proteins
Protein, peptide- and amino acid-based drug delivery systems have proficiently transformed nanotechnology via immense flexibility in their features for attaching various drug molecules and biodegradable polymers. In this regard, novel nanostructures including carbon nanotubes, electrospun carbon nanofibers, gold nanoislands, and metal-based nanoparticles have been introduced as nanosensors for accurate detection of these organic compounds. These nanostructures can bind the biological receptor to the sensor surface and increase the surface area of the working electrode, significantly enhancing the biosensor performance.
  • 559
  • 13 Dec 2021
Topic Review
Polymer-Based Thermally Conductive Materials by Fused Filament Fabrication
With the miniaturization and integration of electronic products, the heat dissipation efficiency of electronic equipment needs to be further improved. Notably, polymer materials are a choice for electronic equipment matrices because of their advantages of low cost and wide application availability. Intelligent electronic devices are currently being researched to meet people’s pursuit of a high-quality life through integration and miniaturization. In order to ensure product safety and operational efficiency, it is imperative to improve the thermal conductivity of electronic devices. Polymers are frequently used in preparing heat dissipation materials because of their low price, light weight, ease of processing, and wide applications.
  • 559
  • 25 Oct 2022
Topic Review
Mazer (Drinking Vessel)
A mazer is a special type of wooden drinking vessel, a wide cup or shallow bowl without handles, with a broad flat foot and a knob or boss in the centre of the inside, known technically as the print or boss. They vary from simple wood pieces all in wood to those ornamented with metalwork, often in silver or silver-gilt. They use dense impervious woods such as maple, beech and walnut wood, and get their name from the spotted or birdseye marking on the wood (Ger. Maser, spot, marking, especially on wood; cf. "measles"), or possibly maserle as a name for Acer campestre. They are a north European medieval tradition, mostly made from the 11th (or earlier) to the 16th centuries.
  • 559
  • 30 Nov 2022
Topic Review
Radiation-Assisted Synthesis of Polymer-Based Nanomaterials
Nanotechnology is the science and technology of making and using very small structures called nanomaterials. As the scales of the constructions become smaller, the conventional methods of making these structures—lithography, etching, micromolding—reach physical limits and it becomes extremely difficult to apply these top-down methods at nanoscale dimensions. To overcome the limitations and create smaller and ordered structures, a so-called “bottom-up” approach must be used. As the component size decreases in nanofabrication, the “bottom-up” approach is being increasingly used in the preparation of nanomaterials, which are materials with at least in one dimension less than 100 nm in size.
  • 558
  • 10 Sep 2021
Topic Review
Synthesis and Electron Doping of TiNCl
Layered metal nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I) have two polymorphs, including α- and β-forms, which have the FeOCl and SmSI structures, respectively. These compounds are band insulators and become metals and show superconductivity after electron doping by intercalating alkali metals between the layers. The superconductivity of β-form had been extensively characterized from decades ago, but it is not easy to consistently interpret all experimental results using conventional phonon-mediated Bardeen–Cooper–Schriefer mechanisms. The titanium compound TiNCl crystallizes only in the α-form structure. TiNCl also exhibits superconductivity as high as ~16 K after electron doping by intercalating metals and/or organic basis. It is important to compare the superconductivity of different M–N networks. However, α-form compounds are vulnerable to moisture, unlike β-form ones. The intercalation compounds are even more sensitive to humid air.
  • 558
  • 07 Jun 2022
Topic Review
Gas/Solid Interface Charging Phenomena
Surface charge accumulation in the spacer modifies local electric fields, which restricts the industrialization of high voltage direct current (HVDC) gas-insulated transmission lines (GILs). In this paper, the state of art in gas/solid interface charging physics and models, covering areas of charge measurement techniques, charge transport mechanisms, charge related DC surface flashover models, and charge control methods, is reviewed and discussed. Key issues that should be considered in future studies are summarized and proposed. The purpose of this work is to provide a brief update on the most important and latest progress in this research area, and to educate readers as to the current state of the gas-solid interface charging phenomenon, which has seen great progress in the past few years.
  • 557
  • 10 Dec 2020
Topic Review
Vanadium and Melanoma
Melanoma is the most aggressive type of skin cancer, the incidence of which has been increasing annually worldwide.
  • 557
  • 08 Jun 2021
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