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Topic Review
AB5 Derivatives of Cyclotriphosphazene
AB5 compounds issued from the reactivity of hexachlorocyclotriphosphazene are relatively easy to obtain using two ways: either first the reaction of one chloride with one reagent, followed by the reaction of the five remaining Cl with another reagent, or first the reaction of five chlorides with one reagent, followed by the reaction of the single remaining Cl with another reagent. This particular property led to the use of such compounds as core for the synthesis of dendrons (dendritic wedges), using the five functions for growing the dendritic branches. The single function can be used for the synthesis of diverse types of dendrimers (onion peel, dumbbell-shape, Janus), for covalent or non-covalent grafting to solid surfaces, providing nanomaterials, for grafting a fluorophore, especially for studying biological mechanisms, or for self-associations to get micelles.
  • 1.1K
  • 04 Aug 2021
Topic Review
Natural Deep Eutectic Solvents for Sustainable Extraction Techniques
The analysis of foods is a comprehensive process of extraction, identification, and quantification of several classes of compounds from natural matrices. The detection and quantification of primary metabolites (sugars, amino acids, vitamins, and lipids), contaminants (toxins, heavy metals, and allergens), and secondary metabolites (polyphenolics, flavonoids, terpenes, and alkaloids) is a crucial practice for ensuring the safety and quality of foods and related functional products. Due to the variable structure of food analytes, a gap in a universal method suitable for the extraction and analysis of all compounds is lacking. Moreover, conventional extractants are usually made of organic solvents and common extraction techniques usually require a long extraction time to exhaust the matrix. The actual discussions about climatic changes provide a growing awareness of the scientific and industrial community to reduce the environmental impact by using sustainable processes. In general, the main principles of “green chemistry” are based on the design of processes aimed to reduce energy consumption and the use of eco-friendly solvents with less toxicity to the environment and human health.
  • 1.1K
  • 09 Jan 2023
Topic Review
Catalytic Cathodes for Na-CO2 Batteries
Na-CO2 batteries with high energy density are drawing tremendous attention because of their advantages of combining cost-effective energy conversion and storage with CO2 clean recycle and utilization. Nevertheless, their commercial applications are impeded by unsatisfactory electrochemical performance including large overpotentials, poor rate capability, fast capacity deterioration, and inferior durability, which mainly results from the inefficient electrocatalysts of cathode materials. 
  • 1.1K
  • 23 Jun 2021
Topic Review
Toughening Approaches of Recycled Polystyrene
Several environmental and techno-economic assessments highlighted the advantage of placing polystyrene-based materials in a circular loop, from production to waste generation to product refabrication, either following the mechanical or thermochemical routes.
  • 1.1K
  • 22 Nov 2022
Topic Review
Application of Cyclodextrins in the Textile Area
Cyclodextrins (CDs) are biocompatible and accepted in biological applications; therefore, there is a growing interest in them both scientifically and industrially. CDs are obtained through the enzymatic degradation of potatoes, corn and rice starch, which gives a mixture of linear, branched, or cyclic dextrins. CDs have a very important role in textile processing and innovation; their use provides immediate opportunities for the development of environmentally friendly products and eco-textiles, in addition to having great potential in various applications. Cyclodextrins can be applied in the areas of spinning, pretreatment, dyeing, finishing, and dye removal, with dyeing, finishing, and water treatment being the most applicable in the textile area registered so far.
  • 1.1K
  • 14 Sep 2022
Topic Review
Applications of Hydrogels for Wound Healing
Hydrogels represent a class of materials that are widely used in soft tissue engineering of skin, blood vessel, muscle, and fat. Hydrogels are three-dimensional (3D) networks consisting of physically or chemically crosslinked bonds of hydrophilic polymers. The insoluble hydrophilic structures demonstrate a remarkable potential to absorb wound exudates and allows oxygen diffusion to accelerate healing.
  • 1.1K
  • 05 Sep 2022
Topic Review
SPE influence on GTEs coatings
Solid particles erosion (SPE) has and is still one of the main challenges that faces the gas turbine engines (GTE) industry, especially when such systems are utilized in harsh environments. This is because the impingement mechanism of the particles on the blades surface causes them to structurally deform, and hence the system performance gets degraded continuously with the operational lifetime. In order to reduce the impact caused by SPE on gas turbines, it is crucial to know before hands the surrounding environment in which the system will be operating, clearly understand how SPE mechanism behaves with different surface materials, select the appropriate blade material that can balance between the performance of the GTE and SPE resistance, and more advance cases use surface coatings.
  • 1.1K
  • 27 Oct 2020
Topic Review
Shape Memory Materials of Rubbers
Smart materials are much discussed in the current research scenario. The shape memory effect is one of the most fascinating occurrences in smart materials, both in terms of the phenomenon and its applications. Many metal alloys and polymers exhibit the shape memory effect (SME).
  • 1.1K
  • 06 Dec 2021
Topic Review
Near- and Mird-Infrared Spectroscopy
Given the exquisite capability of direct, non-destructive label-free sensing of molecular transitions, IR spectroscopy has become a ubiquitous and versatile analytical tool. IR application scenarios range from industrial manufacturing processes, surveillance tasks and environmental monitoring to elaborate evaluation of (bio)medical samples. Given recent developments in associated fields, IR spectroscopic devices increasingly evolve into reliable and robust tools for quality control purposes, for rapid analysis within at-line, in-line or on-line processes, and even for bed-side monitoring of patient health indicators. 
  • 1.1K
  • 03 Aug 2022
Topic Review
Nanostructured Materials for Uranium Removal
Groundwater is commonly used as a drinking water resource all over the world. Therefore, groundwater contamination by toxic metals is an important issue of utmost concern for public health, and several technologies are applied for their effective removal, such as coagulation, ion exchange, adsorption, and membrane applications like reverse osmosis. Adsorption is acknowledged as a simple, effective and economic technology, which has received increased interest recently, despite certain limitations regarding operational applications. The respective scientific efforts have been specifically focused on the development and implementation of novel nano-structured adsorbent materials, which may offer extensive specific surface areas, much higher than the conventional adsorbents, and hence, are expected to present higher removal efficiencies of pollutants. In this paper, the recent developments of nanomaterial applications for uranium removal from groundwaters are critically reviewed. Particularly, the use of novel composite materials, based mainly on hybrid metallic oxide nanoparticles and on composites based on graphene oxide (GO) (i.e., graphene-based hybrids), showed promising evidences to achieve efficient removal of toxic metals from water sources, even in full scale applications.
  • 1.1K
  • 12 May 2020
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