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Topic Review
[18F]Difluoromethyl Heteroaryl-Sulfones
The suitability of the 18F radioisotope in positron emission tomography (PET) demanded novel approaches for 18F-fluorination and 18F-fluoroalkylation. The difluoromethyl (CF2H) group has gained increasing attention in medicinal chemistry due to its lipophilic hydrogen-bond donor properties. In non-radioactive chemistry, difluoromethyl heteroaryl-sulfones has been extensively used in difluoromethylation of substrates bearing C=C, C≡C, and C≡N bonds by visible light photoredox catalysis. Herein, we highlight our recent work on the synthesis of [18F]difluoromethyl heteroaryl-sulfones with improved molar activities and their application in photoinduced C-H 18F-difluoromethylation of N-containing heteroarenes via a radical-mediated pathway.
  • 1.3K
  • 25 Aug 2021
Topic Review
{001} Faceted Anatase TiO2-Based Composites
For anatase TiO2, the {001} crystal facets are the most reactive because they exhibit unique surface characteristics such as visible light responsiveness, dissociative adsorption, efficient charge separation capabilities and photocatalytic selectivity. In this review, a concise survey of the literature in the field of {001} dominated anatase TiO2 crystals and their composites is presented. Even though the design and morphologically controlled synthesis of TiO2-001 is considered to be a hot spot in scientific research, it still has some drawbacks like its wide band gap and high recombination rate. These drawbacks can easily be overcome by coupling them with other materials to form TiO2-001-based composites. This review focusses on the synthesis, properties and applications of TiO2-001-based composites. 
  • 880
  • 12 Nov 2021
Topic Review
Leucoagaricus gongylophorus and Leaf-Cutting Ants
Leaf-cutting ants are eusocial insects, as they show a highly developed social structure, manifesting ecological relationships. Their complex structure is characterized by an organized social behavior, the cultivation of a fungus garden and high levels of hygiene, which hinders the management of leaf-cutting ants compared to other insects. Leaf-cutting ants cause damage in agricultural and silviculture areas, mainly in monocultures.
  • 737
  • 21 Apr 2022
Topic Review
1D MOS Nanostructures
1D electrospun MOS are basically nanofibers, nanotubes or nanowires, which are made of one or more semiconductor metal oxides or with other dopant material. Polymer/MOS precursor nanofibers that are formed in the electrospinning process are calcined until the polymer is removed and pristine MOS nanostructure is obtained.
  • 526
  • 10 Dec 2021
Topic Review
1D MPC and Thin-Film Analysis
The development of magnetic photonic crystals (MPC) has been a rapidly evolving research area since the late 1990s. Magneto-optic (MO) materials and the techniques for their characterization have also continually undergone functional and property-related improvements. MPC Optimization is a feature-rich Windows software application designed to enable researchers to analyse the optical and magneto-optical spectral properties of multilayers containing gyrotropic constituents. A set of computational approaches, and a custom software package have been described, designed to enable the design and optimization of 1D magnetic photonic crystals in terms of the achievable combinations of Faraday rotation, transmission, and reflection spectra. 
  • 1.0K
  • 25 Aug 2021
Topic Review
3D Graphene-Based Toxic Gas Sensors
Air pollution is becoming an increasingly important global issue. Toxic gases such as ammonia, nitrogen dioxide, and volatile organic compounds (VOCs) like phenol are very common air pollutants. To date, various sensing methods have been proposed to detect these toxic gases. Researchers are trying their best to build sensors with the lowest detection limit, the highest sensitivity, and the best selectivity. As a 2D material, graphene is very sensitive to many gases and so can be used for gas sensors. Recent studies have shown that graphene with a 3D structure can increase the gas sensitivity of the sensors. The limit of detection (LOD) of the sensors can be upgraded from ppm level to several ppb level.
  • 904
  • 25 Aug 2021
Topic Review
3D Printing to Produce BioComposite
Current environmental concerns have led to a search of more environmentally friendly manufacturing methods, thus, natural fibers have gained attention in the 3D printing industry to be used as biofilters along with thermoplastics. The utilization of natural fibers is very convenient as they are easily available, cost-effective, eco-friendly, and biodegradable. Using natural fibers rather than synthetic fibers in the production of the 3D printing filaments will reduces gas emissions associated with the production of the synthetic fibers that would add to the current pollution problem. As a matter of fact, natural fibers have a reinforcing effect on plastics. This review analyzes how the properties of the different types of polymers vary when natural fibers processed to produce filaments for 3D Printing are added. The results of using natural fibers for 3D Printing are presented in this study and appeared to be satisfactory, while a limited number of studies have reported some issues.
  • 919
  • 12 May 2021
Topic Review
6-formyl-indolo(3,2-b)carbazole
6-formyl-indolo[3,2-b]carbazole (FICZ) (chemical formula C19H12N2O) is a nitrogen heterocycle, having an extremely high affinity (Kd = 7 x 10-11M) for binding to the Aryl hydrocarbon receptor (AhR). It was originally identified as a photooxidized derivative of the amino acid tryptophan and suggested to be the endogenous liagand of the AhR.
  • 442
  • 04 Nov 2022
Topic Review
6061 Aluminium Alloy
6061 (Unified Numbering System (UNS) designation A96061) is a precipitation-hardened aluminium alloy, containing magnesium and silicon as its major alloying elements. Originally called "Alloy 61S", it was developed in 1935. It has good mechanical properties, exhibits good weldability, and is very commonly extruded (second in popularity only to 6063). It is one of the most common alloys of aluminum for general-purpose use. It is commonly available in pre-tempered grades such as 6061-O (annealed), tempered grades such as 6061-T6 (solutionized and artificially aged) and 6061-T651 (solutionized, stress-relieved stretched and artificially aged).
  • 9.1K
  • 22 Nov 2022
Topic Review
Acid Throwing
Acid throwing, also called an acid attack, a vitriol attack or vitriolage, is a form of violent assault defined as the act of throwing acid or a similarly corrosive substance onto the body of another "with the intention to disfigure, maim, torture, or kill". Perpetrators of these attacks throw corrosive liquids at their victims, usually at their faces, burning them, and damaging skin tissue, often exposing and sometimes dissolving the bones. The most common types of acid used in these attacks are sulfuric and nitric acid. Hydrochloric acid is sometimes used, but is much less damaging. Aqueous solutions of strongly alkaline materials, such as caustic soda (sodium hydroxide), are used as well, particularly in areas where strong acids are controlled substances. The long term consequences of these attacks may include blindness, as well as permanent scarring of the face and body, along with far-reaching social, psychological, and economic difficulties. Today, acid attacks are reported in many parts of the world. Since the 1990s, Bangladesh has been reporting the highest number of attacks and highest incidence rates for women, with 3,512 Bangladeshi people acid attacked between 1999 and 2013, and in Pakistan and India acid attacks are at an all-time high and increasing every year. Although acid attacks occur all over the world, this type of violence is most common in South Asia. The UK has one of the highest rates of acid attacks per capita in the world, according to Acid Survivors Trust International (ASTI). In 2016 there were over 601 acid attacks in the UK based on ASTI figures. Over 1,200 cases were recorded over the past 5 years. From 2011 to 2016 there were 1,464 crimes involving acid or corrosive substance in London alone.
  • 5.1K
  • 21 Oct 2022
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