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Topic Review
Metal Bis(trimethylsilyl)amides
Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides. Due to the bulky hydrocarbon backbone metal bis(trimethylsilyl)amide complexes have low lattice energies and are lipophilic . For this reason, they are soluble in a range of nonpolar organic solvents, in contrast to simple metal halides, which only dissolve in reactive solvents. These steric bulky complexes are molecular, consisting of mono-, di-, and tetramers. Having a built-in base, these compounds conveniently react with even weakly protic reagents. The class of ligands and pioneering studies on their coordination compounds were described by Bürger and Wannagat. The ligands are often denoted hmds (e.g. M(N(SiMe3)2)3 = M(hmds)3) in reference to the hexamethyldisilazane from which they are prepared.
  • 2.9K
  • 02 Dec 2022
Topic Review
Handfasting
Handfasting is a traditional practice that, depending on the term's usage, may correspond to an unofficiated wedding (in which a couple marries without an officiant, usually with the intent of later undergoing a second wedding with an officiant), a betrothal (an engagement in which a couple has formally promised to wed, and which can be broken only through divorce), or a temporary wedding (in which a couple makes an intentionally temporary marriage commitment). The phrase refers to the making fast of a pledge by the shaking or joining of hands. The terminology and practice is especially associated with Germanic peoples, including the English and Norse, as well as the Gaelic Scots. As a form of betrothal or unofficiated wedding, it was common up through Tudor England; as a form of temporary marriage, it was practiced in 17th-century Scotland and has been revived in Neopaganism. Sometimes the term is also used synonymously with "wedding" or "marriage" among Neopagans to avoid perceived non-Pagan religious connotations associated with those terms. It is also used, apparently ahistorically, to refer to an alleged pre-Christian practice of symbolically fastening or wrapping the hands of a couple together during the wedding ceremony.
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  • 17 Oct 2022
Topic Review
Rheology of Gels and Yielding Liquids
Gels are understood as soft viscoelastic multicomponent solids that are in the incomplete phase separation state, which, under the action of external mechanical forces, do not transit into a fluid state but rupture like any solid material. Gels can “melt” (again, like any solids) due to a change in temperature or variation in the environment. In contrast to this type of rheology, yielding liquids (sometimes not rigorously referred to as “gels”, especially in relation to colloids) can exist in a solid-like (gel-like) state and become fluid above some defined stress and time conditions (yield stress). At low stresses, their behavior is quite similar to that of permanent solid gels, including the frequency-independent storage modulus. The gel-to-sol transition considered in colloid chemistry is treated as a case of yielding. However, in many cases, the yield stress cannot be assumed to be a physical parameter since the solid-to-liquid transition happens in time and is associated with thixotropic effects. 
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  • 28 Sep 2023
Topic Review Peer Reviewed
Social Aspects of Smart Urban Mobility
There is a growing interest in sustainable urban transport solutions in cities around the world. These changes, known as “smart urban mobility”, aim to reduce the negative effects of transport on the natural environment and enhance the standard of living for urban dwellers. It should be noted that in addition to this transformation’s technological aspects, modifying the city’s structure and architecture also has a social dimension. The transformation of urban mobility has a significant impact on social relations. Introducing new modes of transport, such as city bikes and electric scooters, creates new ways of moving around the city and can impact social interactions. This can increase social integration and a community’s sense of belonging. At the same time, it is necessary to consider the differences between social groups to ensure equal access to the benefits of these changes in addition to deeper social elements, such as changing the habits and expectations of residents and adapting solutions to the specific needs of each city. This paper aims to look at the social aspects of smart urban mobility, including the impact of these changes on the lives and relationships of city residents.
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  • 22 May 2024
Topic Review
Nanobodies
Nanobodies are highly water-soluble and stable, have high specificity, and can bind their targets with very high affinity, often in the low nanomolar range. 
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  • 10 May 2021
Topic Review
Phytoestrogen
Phytoestrogens are compounds derived from plants that have a similar structure to human sex hormones. 
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  • 26 Jan 2021
Topic Review
Actor
An actor or actress is a person who portrays a character in a performance. The actor performs "in the flesh" in the traditional medium of the theatre or in modern media such as film, radio, and television. The analogous Greek term is ὑποκριτής (Script error: No such module "Ancient Greek".), literally "one who answers". The actor's interpretation of a role—the art of acting—pertains to the role played, whether based on a real person or fictional character. This can also be considered an "actor's role," which was called this due to scrolls being used in the theaters. Interpretation occurs even when the actor is "playing themselves", as in some forms of experimental performance art. Formerly, in Ancient Greece and the medieval world, and in England at the time of William Shakespeare, only men could become actors, and women's roles were generally played by men or boys. While Ancient Rome did allow female stage performers, only a small minority of them were given speaking parts. The commedia dell’arte of Italy, however, allowed professional women to perform early on; Lucrezia Di Siena, whose name is on a contract of actors from 10 October 1564, has been referred to as the first Italian actress known by name, with Vincenza Armani and Barbara Flaminia as the first primadonnas and the first well-documented actresses in Italy (and in Europe). After the English Restoration of 1660, women began to appear onstage in England. In modern times, particularly in pantomime and some operas, women occasionally play the roles of boys or young men.
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  • 02 Oct 2022
Topic Review
Clathrate Gun Hypothesis
The clathrate gun hypothesis refers to a proposed explanation for the periods of rapid warming during the Quaternary. The idea is that changes in fluxes in upper intermediate waters in the ocean caused temperature fluctuations that alternately accumulated and occasionally released methane clathrate on upper continental slopes, these events would have caused the Bond Cycles and individual interstadial events, such as the Dansgaard–Oeschger interstadials. The hypothesis was supported for the Bølling-Allerød and Preboreal period, but not for Dansgaard–Oeschger interstadials, although there are still debates on the topic.
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  • 18 Oct 2022
Topic Review
Rainfall Threshold
Sediment-related disaster is one of the most significant natural disasters, from the perspective of magnitude, damage and loss to human life and infrastructure, and disruption to socio-economic activities. The rainfall threshold is the condition or amount of rainfall that is likely to initiate sediment-related disasters, it is agreed that the rainfall threshold is the most significant tool to predict impending occurrences.
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  • 26 Oct 2022
Topic Review
Parliamentary Train
A Parliamentary train is a passenger service operated in the United Kingdom to comply with the Railway Regulation Act 1844 that required train companies to provide inexpensive and basic rail transport for less affluent passengers. The act required that at least one such service per day be run on every railway route in the UK. Now no longer a legal requirement (although most franchise agreements require such trains), the term describes train services that continue to be run to avoid the cost of formal closure of a route or station but with reduced services often to just one train per week and without specially low prices. Such services are often called "ghost trains".
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  • 10 Nov 2022
Topic Review
Non-Cannabinoid Compounds
Cannabinoid and non-cannabinoid phytochemicals possess bioactive and protective properties that are beneficial to human health. In addition to cannabinoids, the cannabis plant also produces hundreds of non-cannabinoid secondary metabolites including approximately 120 terpenoids (61 monoterpenes, 52 sesquiterpenoids, and 5 triterpenoids, essential oils, over 26 flavonoids lignans, stilbenoid derivatives, alkaloids, amino acids, spiroindans, polyphenols, 20 steroids ), dihydrophenanthrenes, glycoproteins (such as galactose, glucose, mannose and xylose), and dibenzyls. This list also includes a-cannabispiranol, chrysoeriol, 6-prenylapigenin, cannflavin A and b-acetyl cannabispiranol.
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  • 01 Apr 2021
Topic Review
LPCS for Metal-Ceramic/Ceramic Coatings
Based on the recent analysis of various databases, cold spray (CS), the newest method among thermal spraying technologies, has received the unabated attention of hundreds of researchers continuously since its invention in the 1980s. The significance of CS lies in the low process temperature, which usually ensures compressive residual stresses and allows for the formation of coatings on a thermally sensitive substrate. 
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  • 13 Sep 2021
Topic Review
A2 Milk
Although milk consumption is increasing worldwide, in some geographical regions, its consumption has persistently declined. This fact, together with the increase in milk production prices, has caused both milk producers and the dairy industry to be immersed in a major crisis. Some possible solutions to this problem are to get people who do not currently consume milk to start drinking it again, or to market milk and dairy products with a higher added value. In this context, a type of milk called A2 has recently received attention from the industry. This type of milk, characterized by a difference in an amino acid at position 67 of the β-casein polypeptide chain, releases much smaller amounts of bioactive opioid peptide β-casomorphin 7 upon digestion, which has been linked to harmful effects on human health. Additionally, A2 milk has been attributed worse technological properties in the production of some dairy products. Thus, doubts exist about the convenience for the dairy industry to bet on this product. 
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  • 30 Aug 2022
Topic Review
Burmese Amber
Burmese amber, also known as Burmite or Kachin amber, is amber from the Hukawng Valley in northern Myanmar. The amber is dated to around 99 million years old, during the earliest part of the Cenomanian age of the Late Cretaceous. The amber is of significant palaeontological interest due to the diversity of flora and fauna contained as inclusions, particularly arthropods including insects and arachnids but also birds, lizards, snakes, frogs and fragmentary dinosaur remains. The amber has been known and commercially exploited since the first century AD, and has been known to science since the mid-nineteenth century. Research on the deposit has attracted controversy due to its role in funding internal conflict in Myanmar and hazardous working conditions in the mines where it is collected.
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  • 24 Nov 2022
Topic Review
Stingless Bee-Collected Pollen
Stingless Bee-collected pollen is a mixture of bee pollen, bee salivary enzymes, and regurgitated honey, fermented by indigenous microbes during storage in the cerumen pot. This review provides knowledge on stingless bee collected pollen, its nutrient and microbes for application in the food and pharmaceutical industries 
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  • 12 Apr 2021
Topic Review
Metal Additive Manufacturing
Additive Manufacturing (AM), also called 3D printing, has been expanding into several industrial sectors due to the technology providing opportunities in terms of improved functionality, productivity, and competitiveness.
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  • 10 Mar 2021
Topic Review
Brake-by-Wire System
With the rapid development of electric vehicles (EVs) in the direction of advanced driving assistance systems and autonomous vehicles, the demands for X-by-wire systems are huge. For example, the brake-by-wire (BBW) system must have a fast enough step response, the adjustable ability of higher accuracy and fault tolerance to ensure the safety of vehicles. The BBW system of “safety, comfort, and low carbon” has become a troublesome issue in the development of the industry. In EVs, the moving parts that can achieve automatic control are more than 200. As an important assurance system for the safe driving of vehicles, the BBW system has the advantages of accurately and independently controlling the pressure of each wheel cylinder and a fast response. 
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  • 26 Apr 2022
Topic Review
Industrial Crystallization of Citrate
The citrate industry has a wide range of applications in food, pharmaceutical, and other fields. As a common class of food additives and functional supplements with tremendous development potential and strong core competitiveness, particles with good powder characteristics and functionalization are becoming one of the primary directions in the evolution of citrate into the high-end market.
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  • 11 Aug 2023
Topic Review
Job Satisfaction and Service Quality in Hotel Industry
The quality of service is one of the key assumptions of a sustainable and profitable business in the hotel industry. On the other hand, employees as direct providers of hotel services have a direct impact on the perceived quality of service. Establishing a relationship between job satisfaction and perceived intangible service quality is of great importance for customer relationship management and sustainable competitive advantage.
  • 2.9K
  • 08 Oct 2023
Topic Review
Contaminants in Tattoo Inks
Tattooing has been an enduring form of body art since ancient times, but it carries inherent health risks, primarily due to the complex composition of tattoo inks. These inks consist of complex mixtures of various ingredients, including pigments, solvents, impurities and contaminants. 
  • 2.9K
  • 19 Oct 2023
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