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Topic Review
Benzimidazole
Benzimidazole is an important heterocyclic fragment, present in many biologically active compounds with a great variety of therapeutic purposes. Most of the benzimidazole activities are explained through the existence of 1,3-tautomeric equilibrium. As the binding affinity of each tautomer to a protein target depends on an established bioactive conformation, the effect of tautomers on the ligand protein binding mechanism is determinant.
  • 1.1K
  • 27 Oct 2022
Topic Review
Gemcitabine Peptide-Based Conjugates
Gemcitabine is an anticancer drug used to treat a wide range of solid tumors and is a first-line treatment for pancreatic cancer. The effect of gemcitabine is significantly weakened by its rapid plasma degradation. In addition, the systemic toxicity and drug resistance significantly reduce its chemotherapeutic efficacy. Up to now, many approaches have been made to improve the therapeutic index of gemcitabine. One of the recently developed approaches to improve conventional chemotherapy is based on the direct targeting of chemotherapeutics to cancer cells using the peptide-drug conjugates (PDCs).
  • 1.1K
  • 24 Feb 2021
Topic Review
Photocatalysis for Water Splitting Capabilities
Water could be used as the main source of hydrogen production. By definition, the dissociation of the water molecules into their constituents (hydrogen and oxygen) is known as water splitting. Rapid population growth and ever-increasing energy consumption have resulted in increased environmental pollution and energy demands. Accordingly, studies and research on innovative and efficient ways of wastewater clean-up and exploiting eco-friendly and renewable energy sources such as sunlight have become a necessity. 
  • 1.1K
  • 07 Nov 2022
Topic Review
Bioplastics in the Circular Economy
The European Union is working towards the 2050 net-zero emissions goal and tackling the ever-growing environmental and sustainability crisis by implementing the European Green Deal. The shift towards a more sustainable society is intertwined with the production, use, and disposal of plastic in the European economy. Emissions generated by plastic production, plastic waste, littering and leakage in nature, insufficient recycling, are some of the issues addressed by the European Commission. Adoption of bioplastics–plastics that are biodegradable, bio-based, or both–is under assessment as one way to decouple society from the use of fossil resources, and to mitigate specific environmental risks related to plastic waste. 
  • 1.1K
  • 22 Jun 2021
Topic Review
Polyurethane
Polyurethane is widely considered as the biggest polymer product which is categorized under plastics. PUs belong to a group of elastomers that are linked to a urethane material with a distinctive feature of being hard and soft parts in the macromolecule. Plastic and modular construction industries produce big quantities of PU wastes in the fabrication process during either processing or utilization of materials.
  • 1.1K
  • 06 Aug 2021
Topic Review
HiPIMS coatings for self-cleaning application: cyclic Reactive Green 12 degradation
We propose a new photocatalytic interface prepared by High-Power Impulse Magnetron Sputtering (HiPIMS) and investigated for the degradation of Reactive Green 12 (RG12) as target contaminant under visible light LEDs illumination. The CuxO/TiO2 nanoparticulate photocatalyst was sequentially sputtered on polyester (PES). The photocatalyst formulation was optimized by investigating the effect of different parameters such as: the sputtering time of CuxO, the applied current and the deposition mode (Direct Current Magnetron Sputtering, DCMS or HiPIMS). The results show that the fastest RG12 degradation was obtained on CuxO/TiO2 sample prepared at 40 A in HIPIMS mode under low intensity LEDs irradiation. The better self-cleaning efficiency of 53.4% within 360 min was found with 4 mg/L of RG12 initial concentration and 0.05 % Cuwt/PESwt as determined by X-ray Fluorescence. All the prepared samples contain a TiO2 under layer with 0.02% Tiwt/PESwt. By transmission electron microscopy (TEM), both layers were seen uniformly distributed on the PES fibers. The effect of the surface-area to volume (dye volume) ratio (SA/V) on the photocatalytic self-cleaning efficiency was also investigated for the discoloration of 4 mg/L RG12. The CuxO/TiO2 photocatalyst was found to have a good reusability and stability up to 21 cycles. Ions release were quantified by mean of inductively coupled plasma mass spectrometry (ICP-MS) showing low Cu-ions release.
  • 1.1K
  • 30 Oct 2020
Topic Review
Reduction of Graphene Oxide
Graphene is a single layer of carbon atoms lined up in a hexagonal lattice, and graphite is composed of these multiple layers.
  • 1.1K
  • 27 Apr 2021
Topic Review
Crossover Effect in Cement-Based Materials
Cement-based materials (CBMs) such as pastes, mortars and concretes are the most frequently used building materials in the present construction industry. Cement hydration, along with the resulting compressive strength in these materials, is dependent on curing temperature, methods and duration. A concrete subjected to an initial higher curing temperature undergoes accelerated hydration by resulting in non-uniform scattering of the hydration products and consequently creating a great porosity at later ages. This phenomenon is called crossover effect (COE). The COE may occur even at early ages between seven to 10 days for Portland cements with various mineral compositions. Compressive strength and other mechanical properties are important for the long life of concrete structures, so any reduction in these properties is of great concern to engineers.  COE phenomenon was reported in the literature. However, based on the data reported in some papers, COE could be observed while the authors did not highlight and discuss this phenomenon in the publications.  This study is a broad literature review on this phenomenon based on the existing published papers and try to identify this phenomenon in the other published papers those could not discover and discuss about it in the study. In addition, this paper tries to further explain about COE, reason and mechanisms and methods to overcome this drawback in concrete/mortar.    
  • 1.1K
  • 25 Oct 2020
Topic Review
Fused 1,5-naphthyridines
Heterocyclic nitrogen compounds, including fused 1,5-naphthyridines, have versatile applications in synthetic organic chemistry and play an important role in the field of medicinal chemistry, as many of them have a wide range of biological activities. In this review, a wide range of synthetic protocols for the construction of this scaffold are presented. For example, Friedländer, Skraup, Semmlere-Wolff, and hetero-Diels-Alder, among others, are well known classical synthetic protocols used for the construction of the main 1,5-naphthyridine scaffold. These syntheses are classified according to the nature of the cycle fused to the 1,5-naphthyridine ring: carbocycles, nitrogen heterocycles, oxygen heterocycles, and sulphur heterocycles. In addition, taking into account the aforementioned versatility of these heterocycles, their reactivity is presented as well as their use as a ligand for metal complexes formation. Finally, those fused 1,5-naphthyridines that present biological activity and optical applications, among others, are indicated.
  • 1.1K
  • 31 Aug 2020
Topic Review
Photocatalysis for Air Purification
Photocatalysis since a long time has been recognized  as a eco-technology to fight air pollution. It is focused  on the generation of reactive oxygen species (ROSs) under light on the surface of a photocatalytic material. It could be applied in different manners such as for the purification of industrial polluted air, photoconversion of toxic gas into valuable products, self-cleaning systems, photocatalytic filters, etc. However, it faces some technological issues limiting its wide application in real-world.  
  • 1.1K
  • 17 May 2021
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