Topic Review
Oscillatory Spinning Drop Interfacial Rheology
The oscillatory spinning drop method has been proven recently to be an accurate technique to measure dilational interfacial rheological properties. It is the only available equipment for measuring dilational moduli in low interfacial tension systems, as is the case in applications dealing with surfactant-oil-water three-phase behavior like enhanced oil recovery, crude oil dehydration, or extreme microemulsion solubilization. Different systems can be studied with this method with the lower density phase as the spinning drop, i.e, oil-in-water, microemulsion-in-water, oil-in-microemulsion, including systems with the presence of complex natural surfactants like asphaltene aggregates or particles. The technique allows studying the characteristics and properties of water/oil interfaces, particularly when the oil contains asphaltenes and when surfactants are present. We have found that using the oscillating spinning drop method to measure interfacial rheology properties can help make precise measurements in a reasonable amount of time. This is of significance when systems with long equilibration times, e.g., asphaltene or high molecular weight surfactant-containing systems are measured, or with systems formulated with a demulsifier which is generally associated with optimum formulation and a low interfacial tension.
  • 1.7K
  • 05 Sep 2021
Topic Review
Mining for Gluon Saturation
Quantum chromodynamics (QCD) is the theory of strong interactions of quarks and gluons collectively called partons, the basic constituents of all nuclear matter. Its non-abelian character manifests in nature in the form of two remarkable properties: color confinement and asymptotic freedom. At high energies, perturbation theory can result in the growth and dominance of very gluon densities at small-x. If left uncontrolled, this growth can result in gluons eternally growing violating a number of mathematical bounds. The resolution to this problem lies by balancing gluon emissions by recombinating gluons at high energies : phenomena of gluon saturation. High energy nuclear and particle physics experiments have spent the past decades quantifying the structure of protons and nuclei in terms of their fundamental constituents confirming predicted extraordinary behavior of matter at extreme density and pressure conditions. In the process they have also measured seemingly unexpected phenomena. We will give a state of the art review of the underlying theoretical and experimental tools and measurements pertinent to gluon saturation physics. We will argue for the need of high energy electron-proton/ion colliders such as the proposed EIC (USA) and LHeC (Europe) to consolidate our knowledge of QCD in the small x kinematic domains. 
  • 732
  • 02 Sep 2021
Topic Review
Physical Aspects of Organogelation
The physics side of organogelation is broached through three main aspects, thermodynamics (formation and melting), structure (morphology and molecular organization), and rheology.  Organogelation is a system constituted of fibril-like entities. Gel formation occurs through first-order transitions, chiefly by homogeneous nucleation. 
  • 766
  • 31 Aug 2021
Topic Review
Laser-Induced Breakdown Spectroscopy
Laser-Induced Breakdown Spectroscopy (LIBS) has been firstly introduced and proposed for analytical applications almost immediately after the invention of the laser in 1960. Since then, it has been proposed and today is widely used as an alternative analytical method for numerous applications. The operating principle of LIBS is quite simple and is based on the interaction of a powerful enough laser beam, focused usually on or in a sample, inducing a dielectric breakdown of the material, thus resulting in plasma formation consisting of excited and non-excited atoms and molecules, fragments of molecular species, electrons and ions, and emitting characteristic radiations, whose spectroscopic analysis can in principle provide the elemental composition fingerprint of the material. The required instrumentation consisting basically of a laser source, and a spectrometer/monochromator equipped with the appropriate light detector (nowadays being almost exclusively some CCD or ICCD type detector) is relatively simple and economically affordable, while significant progresses have been achieved to small size and/or portable equipment, facilitating largely the in situ operation.
  • 1.8K
  • 31 Aug 2021
Topic Review
Effects in Molecular Nanomagnets
Molecular magnets, in principle, have a similar hierarchy. Starting from single-molecule magnets (SMM)and single-chain magnets (SCM), more complex structures are also possible. In general, molecular nanomagnets can be built without the aforementioned magnetic elements; however, highly interesting molecular nanomagnets can be created by adding Mn12, Fe8, Mn4, or other metallic elements.
  • 519
  • 26 Aug 2021
Topic Review
Amperometric Biosensors and Biofuel Cells
Amperometric biosensors and biofuel cells are mostly based on immobilized enzymes or living cells. Among the many oxidoreductases, glucose oxidase (GOx) is used mostly in biosensor design. The same GOx can be well applied for the development of biofuel cells and self-charging capacitors based on the operation of biofuel cells. 
  • 935
  • 24 Aug 2021
Topic Review
Acoustic Properties of Natural-fiber-based Composites
Recent advancement in controlling noise through sound absorption provides an opportunity to investigate various porous materials including fiber-based composites. Natural-fiber-based composites exhibit relatively good sound absorption capability due to their porous structure. Surface modification by alkali treatment can enhance the sound absorption performance. These materials can be used in buildings and interiors for efficient sound insulation. Natural-fiber-based composites have advantages such as high abrasive resistance, low emission of toxic fumes with heat, high specific strength, light weight, low cost, and eco-friendliness. Very rapid growth has been observed in the innovations and use of natural-fiber-based materials and composites for acoustic applications.
  • 3.8K
  • 24 Aug 2021
Topic Review
A discrete quantum momentum operator
We introduce finite-differences derivatives intended to be exact when applied to the real exponential function. We want to recover the known results of continuous calculus with our finite differences derivatives but in a discrete form. The purpose of this work is to have a discrete momentum operator suitable for use as an operator in discrete quantum mechanics theory.
  • 2.0K
  • 24 Aug 2021
Topic Review
3D Live Cell Imaging Challenges
Relevant samples are described and various problems and challenges—including 3D Challenges of 3D imaging by optical sectioning, light scattering and phototoxicity—are addressed. Furthermore, enhanced methods of wide-field or laser scanning microscopy together with some relevant examples and applications are summarized. In the future one may profit from a continuous increase in microscopic resolution, but also from molecular sensing techniques in the nanometer range using e.g., non-radiative energy transfer (FRET).
  • 783
  • 23 Aug 2021
Topic Review
Extinction-Coefficient Modulation of MoO3 Films
This entry focused on the application of the effective medium theory to describe the extinction coefficient (Qext) in molybdenum trioxide (MoO3) doped with different kinds of plasmonic nanoparticles, such as silver (Ag), gold (Au), and copper (Cu). Usually, in studies of these materials, it is normal to analyze the transmission or absorption spectra. However, the effect of this type or size of nanoparticles on the spectra is not as remarkable as the effect that is found by analyzing the Qext of MoO3. It was shown that the β-phase of MoO3 enhanced the intensity response of the Qext when compared to the α-phase of MoO3. With a nanoparticle size of 5 nm, the Ag-doped MoO3 was the configuration that presents the best response in Qext. On the other hand, Cu nanoparticles with a radius of 20 nm embedded in MoO3 was the configuration that presented intensities in Qext similar to the cases of Au and Ag nanoparticles. Therefore, implementing the effective medium theory can serve as a guide for experimental researchers for the application of these materials as an absorbing layer in photovoltaic cells. 
  • 722
  • 20 Aug 2021
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