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Topic Review Peer Reviewed
Opportunities for Catalytic Reactions and Materials in Buildings
Residential and commercial buildings are responsible for over 30% of global final energy consumption and accounts for ~40% of annual direct and indirect greenhouse gas emissions. Energy efficient and sustainable technologies are necessary to not only lower the energy footprint but also lower the environmental burden. Many proven and emerging technologies are being pursued to meet the ever-increasing energy demand. Catalytic science has a significant new role to play in helping address sustainable energy challenges, particularly in buildings, compared to transportation and industrial sectors. Thermally driven heat pumps, dehumidification, cogeneration, thermal energy storage, carbon capture and utilization, emissions suppression, waste-to-energy conversion, and corrosion prevention technologies can tap into the advantages of catalytic science in realizing the full potential of such approaches, quickly, efficiently, and reliably. Catalysts can help increase energy conversion efficiency in building related technologies but must utilize low cost, easily available and easy-to-manufacture materials for large scale deployment. This entry presents a comprehensive overview of the impact of each building technology area on energy demand and environmental burden, state-of-the-art of catalytic solutions, research, and development opportunities for catalysis in building technologies, while identifying requirements, opportunities, and challenges.
  • 3.8K
  • 18 Apr 2022
Topic Review
Energetic Valorisation of Olive Biomass
The generation, composition, properties and potential energetic applications of the main three biomass obtained from the olive oil industry are illustrated.
  • 3.8K
  • 27 Oct 2020
Topic Review
Containment Building
A containment building, in its most common usage, is a reinforced steel, concrete or lead structure enclosing a nuclear reactor. It is designed, in any emergency, to contain the escape of radioactive steam or gas to a maximum pressure in the range of 275 to 550 kPa (40 to 80 psi) . The containment is the fourth and final barrier to radioactive release (part of a nuclear reactor's defence in depth strategy), the first being the fuel ceramic itself, the second being the metal fuel cladding tubes, the third being the reactor vessel and coolant system. Each nuclear plant in the US is designed to withstand certain conditions which are spelled out as "Design Basis Accidents" in the Final Safety Analysis Report (FSAR). The FSAR is available for public viewing, usually at a public library near the nuclear plant. The containment building itself is typically an airtight steel structure enclosing the reactor normally sealed off from the outside atmosphere. The steel is either free-standing or attached to the concrete missile shield. In the United States , the design and thickness of the containment and the missile shield are governed by federal regulations (10 CFR 50.55a), and must be strong enough to withstand the impact of a fully loaded passenger airliner without rupture. While the containment plays a critical role in the most severe nuclear reactor accidents, it is only designed to contain or condense steam in the short term (for large break accidents) and long term heat removal still must be provided by other systems. In the Three Mile Island accident the containment pressure boundary was maintained, but due to insufficient cooling, some time after the accident, radioactive gas was intentionally let from containment by operators to prevent over pressurization. This, combined with further failures, caused the release of up to 13 million curies of radioactive gas to atmosphere during the accident. While the Fukushima Daiichi plant had operated safely since 1971, an earthquake and tsunami well beyond the design basis resulted in failure of AC power, backup generators and batteries which defeated all safety systems. These systems were necessary to keep the fuel cool after the reactor had been shut down. This resulted in partial or complete meltdown of fuel rods, damage to fuel storage pools and buildings, release of radioactive debris to surrounding area, air and sea, and resorting to the expedient use of fire engines and concrete pumps to deliver cooling water to spent fuel pools and containment. During the incident, pressure within the containments of reactors 1-3 rose to exceed design limits, which despite attempts to reduce pressure by venting radioactive gases, resulted in breach of containment. Hydrogen leaking from the containment mixed with air into an explosive mixture which resulted in explosions in Unit 1, 3 and 4, complicating attempts to stabilize the reactors.
  • 3.7K
  • 08 Nov 2022
Topic Review
Enzymatic Transesterification in Biodiesel Production
       Biodiesel constitutes an attractive source of energy because it is renewable,  biodegradable, and non-polluting. Up to 20% biodiesel can be blended with fossil diesel and is being produced and used in many countries. Biodiesel is produced through the transesterification reaction of fat waste with a short-chain alcohol, usually methanol, in the presence of a catalyst. Animal fats, usually found as waste from slaughterhouses, meat processing industry, and cooking facilities, constitute an important waste with costly treatment that can be reduced if used as feedstock for biodiesel production. Animal fat waste represents near 6% of total feedstock used to produce biodiesel through alkaline catalysis transesterification after its pretreatment. Lipase transesterification has some advantages such as the requirement of mild conditions, absence of pretreatment, no soap formation, simple downstream purification process and generation of high quality biodiesel. However, it has some disadvantages like the cost of the enzyme, its poor stability, and the enzyme deactivation by alcohol, that can be partly overcome through enzyme immobilization. A few companies are using liquid lipase formulations and, in some cases, immobilized lipases for industrial biodiesel production.        Biodiesel constitutes an attractive source of energy because it is renewable,  biodegradable, and non-polluting. Up to 20% biodiesel can be blended with fossil diesel and is being produced and used in many countries. Biodiesel is produced through the transesterification reaction of fat waste with a short-chain alcohol, usually methanol, in the presence of a catalyst. Animal fats, usually found as waste from slaughterhouses, meat processing industry, and cooking facilities, constitute an important waste with costly treatment that can be reduced if used as feedstock for biodiesel production. Animal fat waste represents near 6% of total feedstock used to produce biodiesel through alkaline catalysis transesterification after its pretreatment. Lipase transesterification has some advantages such as the requirement of mild conditions, absence of pretreatment, no soap formation, simple downstream purification process and generation of high quality biodiesel. However, it has some disadvantages like the cost of the enzyme, its poor stability, and the enzyme deactivation by alcohol, that can be partly overcome through enzyme immobilization. A few companies are using liquid lipase formulations and, in some cases, immobilized lipases for industrial biodiesel production.
  • 3.7K
  • 30 Oct 2020
Topic Review Video
Classification of Energy Storage Technologies
The intensive exploitation and usage of fossil fuels has led to serious environmental consequences, including soil, water, and air pollution and climate changes, and it has compromised the natural resources available for future generations. In this context, identifying new energy storage technologies can be considered a sustainable solution to these problems, with potential long-term effects.
  • 3.7K
  • 19 Jan 2024
Topic Review
Hydrogen Storage Technologies for Railway Engineering
According to the specific requirements of railway engineering, a techno-economic comparison for onboard hydrogen storage technologies is conducted to discuss their feasibility and potentials for hydrogen-powered hybrid trains. Physical storage methods, including compressed hydrogen (CH2), liquid hydrogen (LH2), and cryo-compressed hydrogen (CcH2), and material-based (chemical) storage methods, such as ammonia, liquid organic hydrogen carriages (LOHCs), and metal hydrides, are carefully discussed in terms of their operational conditions, energy capacity, and economic costs.
  • 3.7K
  • 23 Sep 2022
Topic Review
Critical Heat Flux Amelioration
Critical heat flux (CHF) is the thermal limit of a phase change phenomenon where boiling occurs during heating, which suddenly decreases the efficiency of heat transfer. Ameliorating CHF by altering the boiling surface characteristics can lead to more efficiency, safety, and reliability of the system.
  • 3.7K
  • 11 Aug 2020
Topic Review
Identification of Optimal Binders for Torrefied Biomass Pellets
The pretreatment of biomass through torrefaction is an effective means of improving the fuel quality of woody biomass and its suitability for use in existing facilities burning thermal coal. Densification of torrefied biomass produces a fuel of similar energy density, moisture content, and fixed carbon content to low-grade coals. Additionally, if the torrefaction conditions are optimized, the produced torrefied pellet will be resistant to weathering and biological degradation, allowing for outdoor storage and transport in a manner similar to coal. In untreated biomass, lignin is the primary binding agent for biomass pellets and is activated by the heat and pressures of the pellet extrusion process. The thermal degradation of lignin during torrefaction reduces its binding ability, resulting in pellets of low durability not suitable for transportation. The use of a binding agent can increase the durability of torrefied pellets/briquettes through a number of different binding mechanisms depending on the binder used.
  • 3.7K
  • 19 Apr 2023
Topic Review
Energy Piles
Energy piles are a relatively new technology that have dual function as heat transferring and load bearing. Due to the influence of temperature cycles, additional thermal stress and relative displacement of the pile will be generated; this is different from the load transferring mechanism of the conventional pile. In order to study the thermodynamic characteristics of the energy pipe pile under dual working conditions and temperature cycles, field tests were carried out on the PHC (prestressed high-strength concrete) energy pipe pile without constraining on the top of the piles. Displacement gauges were arranged on the top of the pile, and concrete strain gauges (temperature, strain) were embedded in the pile.
  • 3.6K
  • 31 Jul 2021
Topic Review
Mechanical Durability of PEM Fuel Cells
The mechanical durability of PEM fuel cells is a significant barrier to commercializing these systems for stationary and transportation power applications. The performance of a PEM fuel cell or stack is affected pointedly by the degradation of its components materials. Performance degradation is unavoidable, but the degradation rate can be minimized by comprehensively understanding degradation and failure mechanisms. Furthermore, the degradation processes of the different components are often interconnected in fuel cells. Therefore, the degradation phenomena of each fuel cell component must be separated, analyzed, and systematically understood to develop novel component materials and build novel cells/stacks that mitigate insufficient fuel cell mechanical durability.
  • 3.5K
  • 01 Aug 2022
Topic Review
Biofuel production from different sources
Due to the depletion of fossil fuels, biofuel production from renewable sources has gainedinterest. Malaysia, as a tropical country with huge resources, has a high potential to produce differenttypes of biofuels from renewable sources. In Malaysia, biofuels can be produced from various sources,such as lignocellulosic biomass, palm oil residues, and municipal wastes. Besides, biofuels are dividedinto two main categories, called liquid (bioethanol and biodiesel) and gaseous (biohydrogen andbiogas). Malaysia agreed to reduce its greenhouse gas (GHG) emissions by 45% by 2030 as theysigned the Paris agreement in 2016. Therefore, we reviewed the status and potential of Malaysia asone of the main biofuel producers in the world in recent years. The role of government and existingpolicies have been discussed to analyze the outlook of the biofuel industries in Malaysia.
  • 3.5K
  • 27 Oct 2020
Topic Review
Hydrogen Storage in Activated Carbons
With the rising demand for H2 in the past decades and its favorable characteristics as an energy carrier, the escalating USA consumption of pure H2 can be projected to reach 63 million tons by 2050. Despite the tremendous potential of H2 generation and its widespread application, transportation and storage of H2 have remained the major challenges of a sustainable H2 economy. Recently, the literature has been stressing the need to develop biomass-based activated carbons as an effective H2 storage material, as these are inexpensive adsorbents with tunable chemical, mechanical, and morphological properties.  This article reviews the current research trends and perspectives on the role of various properties of biomass-based activated carbons on its H2 uptake capacity. The critical aspects of the governing factors of H2 storage, namely, the surface morphology (specific surface area, pore volume, and pore size distribution), surface functionality (heteroatom and functional groups), physical condition of H2 storage (temperature and pressure), and thermodynamic properties (heat of adsorption and desorption), are discussed. A comprehensive survey of the literature showed that an “ideal” biomass-based activated carbon sorbent with a micropore size typically below 10 Å, micropore volume greater than 1.5 cm3/g, and high surface area of 4000 m2/g or more may help in substantial gravimetric H2 uptake of >10 wt% at cryogenic conditions (−196 °C), as smaller pores benefit by stronger physisorption due to the high heat of adsorption.
  • 3.3K
  • 01 Apr 2021
Topic Review
Compressed Hydrogen Tank Applications across Transportation
The transportation sector faces a new paradigm to address the threat of climate change and environmental pollution. The application of hydrogen fuel cells in transportation offers a great possibility to decarbonize an activity sector, which alone is responsible for the largest share of greenhouse gas emissions. This is particularly attractive to sectors with limited low-carbon fuel options, such as aviation and maritime sectors.
  • 3.2K
  • 27 Jul 2022
Topic Review
Electric Vehicles for Vehicle-to-Grid Services
With every passing second, we witness the effect of the global environmental impact of fossil fuels and carbon emissions, to which nations across the globe respond by coming up with ambitious goals to become carbon-free and energy-efficient. At the same time, electric vehicles (EVs) are developed as a possible solution to reach this ambitious goal of making a cleaner environment and facilitating smarter transportation modes. This excellent idea of shifting towards an entirely EV-based mobility industry and economy results in a range of issues that need to be addressed. The issues range from ramping up the electricity generation for the projected increase in consumption to developing an infrastructure that is large enough to support the higher demand for electricity that arises due to the market penetration of EVs. Vehicle to grid (V2G) is a concept that is largely in a testing phase in the current scenario. However, it appears to offer a solution to the issues created by a mobility sector that the constantly growing EV fleet will dominate. Furthermore, the integration of EVs with the grid seems to offer various cost-wise and environment-wise benefits while assisting the grid by tapping into the idle energy of parked EVs during peak hours
  • 3.2K
  • 17 Apr 2024
Topic Review
Functional Polymer Materials for Energy Applications
This entry provides insight into the recent energy applications of polymers.
  • 3.2K
  • 15 Dec 2021
Topic Review
Opportunities and Challenges in Developing Ocean Energy Sources
The optimal utilization of renewable energies is a crucial factor toward the realization of sustainability and zero carbon in a future energy system. Tidal currents, waves, and thermal and salinity gradients in the ocean are excellent renewable energy sources. Ocean tidal, osmotic, wave, and thermal energy sources have yearly potentials that exceed the global power demand of 22,848 TWh/y. It is expected that a better insight into ocean energy and a deep understanding of various potential devices can lead to a broader adoption of ocean energy. It is also clear that further research into control strategies is needed. Policy makers should provide financial support for technologies in the demonstration stage and employ road mapping to accelerate the cost and risk reductions to overcome economic hurdles. 
  • 3.2K
  • 23 May 2022
Topic Review
Electricity Tariffs and Solutions for Optimal Energy Management
Today, electricity tariffs play an essential role in the electricity retail market as they are the key factor for the decision-making of end-users. Additionally, tariffs are necessary for increasing competition in the electricity market. They have a great impact on load energy management. Moreover, tariffs are not taken as a fixed approach to expense calculations only but are influenced by many other factors, such as electricity generation, transmission, distribution costs, and governmental taxation. Thus, electricity pricing differs significantly between countries or between regions within a country. Improper tariff calculation methodologies in some areas have led to high-power losses, unnecessary investments, increased operational expenses, and environmental pollution due to the non-use of available sustainable energy resources.
  • 3.2K
  • 25 Nov 2022
Topic Review
Hydrogen Storage Techniques for On-Board Applications
Hydrogen as an energy carrier could help decarbonize industrial, building, and transportation sectors, and be used in fuel cells to generate electricity, power, or heat. One of the numerous ways to solve the climate crisis is to make the vehicles on our roads as clean as possible. Fuel cell electric vehicles (FCEVs) have demonstrated a high potential in storing and converting chemical energy into electricity with zero carbon dioxide emissions. This text presents the most favorable hydrogen storage approaches for FCEV on-board applications. To achieve long-range autonomy (over 500 km), FCEVs must be capable of storing 5-10 kg of hydrogen in compressed vessels at 700 bar, with Type IV vessels being the primary option. Although physical and chemical storage technologies are expected to be valuable to the hydrogen economy, compressed hydrogen storage remains the most advanced technology for on-board applications.
  • 3.2K
  • 09 Aug 2023
Topic Review
Brackish Water Reverse Osmosis Desalination
Brackish water desalination, using the reverse osmosis (BWRO) process, has become common in global regions, where vast reserves of brackish groundwater are found (e.g., the United States, North Africa).
  • 3.1K
  • 25 Aug 2021
Topic Review
Biomass Pyrolysis
Pyrolysis process has been considered to be an efficient approach for valorization of lignocellulosic biomass into bio-oil and value-added chemicals. Bio-oil refers to biomass pyrolysis liquid, which contains alkanes, aromatic compounds, phenol derivatives, and small amounts of ketone, ester, ether, amine, and alcohol. Lignocellulosic biomass is a renewable and sustainable energy resource for carbon that is readily available in the environment. This review article provides an outline of the pyrolysis process including pretreatment of biomass, pyrolysis mechanism, and process products upgrading. The pretreatment processes for biomass are reviewed including physical and chemical processes. In addition, the gaps in research and recommendations for improving the pretreatment processes are highlighted. Furthermore, the effect of feedstock characterization, operating parameters, and types of biomass on the performance of the pyrolysis process are explained. Recent progress in the identification of the mechanism of the pyrolysis process is addressed with some recommendations for future work. In addition, the article critically provides insight into process upgrading via several approaches specifically using catalytic upgrading. In spite of the current catalytic achievements of catalytic pyrolysis for providing high-quality bio-oil, the production yield has simultaneously dropped. This article explains the current drawbacks of catalytic approaches while suggesting alternative methodologies that could possibly improve the deoxygenation of bio-oil while maintaining high production yield.
  • 3.1K
  • 21 Jul 2020
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