Submitted Successfully!
To reward your contribution, here is a gift for you: A free trial for our video production service.
Thank you for your contribution! You can also upload a video entry or images related to this topic.
Version Summary Created by Modification Content Size Created at Operation
1
sandile jali
 -- 2655 2023-12-28 16:24:26 |
2 references update
Fanny Huang
 Meta information modification 2655 2023-12-29 10:07:37 |

Video Upload Options

We provide professional Video Production Services to translate complex research into visually appealing presentations. Would you like to try it?
No, upload directly Yes

Confirm

Are you sure to Delete?
Yes No
Cite
If you have any further questions, please contact Encyclopedia Editorial Office.
Jali, S.; Mohan, T.P.; Mwangi, F.M.; Kanny, K. Nanocomposite Preparation Methods. Encyclopedia. Available online: https://encyclopedia.pub/entry/53233 (accessed on 23 November 2024).
Jali S, Mohan TP, Mwangi FM, Kanny K. Nanocomposite Preparation Methods. Encyclopedia. Available at: https://encyclopedia.pub/entry/53233. Accessed November 23, 2024.
Jali, Sandile, Turup Pandurangan Mohan, Festus Maina Mwangi, Krishnan Kanny. "Nanocomposite Preparation Methods" Encyclopedia, https://encyclopedia.pub/entry/53233 (accessed November 23, 2024).
Jali, S., Mohan, T.P., Mwangi, F.M., & Kanny, K. (2023, December 28). Nanocomposite Preparation Methods. In Encyclopedia. https://encyclopedia.pub/entry/53233
Jali, Sandile, et al. "Nanocomposite Preparation Methods." Encyclopedia. Web. 28 December, 2023.
Nanocomposite Preparation Methods
Edit
This entry is adapted from the peer-reviewed paper 10.3390/polym16010051

Synthetic plastics are commonly used because they exhibit sufficient characteristics for packaging requirements, but their end lives result in environmental pollution, the depletion of landfill space, rising sea pollution, and more. These exist because of their poor biodegradability, limited recyclability, etc. There has been an increasing demand for replacing these polymers with bio-based biodegradable materials for a sustainable environment. Cellulosic nanomaterials have been proposed as a potential substitute in the preparation of packaging films. Cellulose can be extracted from different sources, such as wood, agricultural by-products, annual plants, and marine algae. There are two forms of nanocellulose extracted from plant fibers: cellulose nanofibers (CNFs) and cellulose nanocrystals (CNCs).

cellulose nanocellulose

1. Introduction

In the global economy, synthetic polymer plastic materials are produced and made to meet various human needs. The most common application for synthetic plastics is in packaging. Because oxygen and water vapor must be blocked from food and electronic packaging, synthetic polymers are required. Such barriers are required for some food packaging to preserve freshness, prevent diseases and infections, delay food deterioration, and, ultimately, reduce food waste. Because synthetic polymers are primarily made for performance and durability rather than for recycling and degradability, there are significant amounts of discarded polymers in terrestrial and aquatic environments [1]. The main drawbacks of these polymers are their limited recyclability, poor biodegradability, and dependence on fossil fuels [2]. Using synthetic polymers has resulted in environmental pollution, global warming, and the depletion of petroleum reserves. Processes such as hydrothermal treatment and pyrolysis are used to convert plastic wastes into fuels. However, due to toxic gaseous emissions produced during the high-temperature combustion of plastics, its application is limited. Recently, the biodegradation of synthetic plastics using microbes and enzymes has started, but biological treatments are limited due to the difficulty of colonizing microbes and adhering them to the surfaces of plastics [3]. Temporary recovery has come from mechanical recycling, but the volumes are typically too small [1]. Petroleum-based synthetic polymers have become a significant environmental concern, as their levels continue to rise in seas, causing pollution, and they continue to deplete landfill space [4][5]. The development of new bio-based materials with biodegradability, renewability, biocompatibility, and sustainability has increased in demand in recent years [6][7][8].
Because cellulose-based materials are made of aligned nanocellulose, they exhibit an intriguing structural hierarchy. They are also potential substitutes for petroleum-based polymers due to their availability on the earth, renewability, biodegradability, and biocompatibility. Adaptability, broad modification capabilities, and adaptable morphologies contribute to reducing non-renewable natural resources [9]. Cellulose is a linear homopolysaccharide made up of repeating units of anhydro-d-glucose linked by β(1→4) glycosidic bonds, and it has varying degrees of polymerization (DP).
In nature, the DP of cellulose chains is typically around 10,000. However, in some materials, such as native cellulose cotton, the DP can be higher, up to around 15,000 [10]. Three hydroxyl groups are on the monomer, known as the anhydroglucose unit (AGU). These groups give cellulose the capacity to form powerful hydrogen bonds, as well as its crucial characteristics [11].
Cellulose can be extracted from different sources, such as wood [12], agricultural by-products [13], annual plants [13], and marine algae [14]. There are two forms of nanocellulose extracted from plant fibers: cellulose nanofibers (CNFs) and cellulose nanocrystals (CNCs) [15][16]. Many solvent systems and dissolution methods have been developed for cellulose dissolution, such as N-methylmorpholine-N-oxide (NMMO), LiCl/DMAc, ionic liquids, alkali/urea, NaOH/thiourea aqueous solutions, the TBAF/DMSO system, etc. [17]. However, due to strong hydrogen bond interactions, natural cellulose possesses a high orientation and crystallinity, making it nearly insoluble in ordinary solvents, limiting its applications [18]. Packaging materials made of cellulose have low-water-vapor-barrier properties due to their hydraulic nature, limiting their application in food packaging [19]. Films made of nanocellulose have been reported to lose their oxygen- and water-vapor-barrier properties at high humidity [20][21]. Also, Yu et al. [22] reported that the oxygen permeability of cellulose films increases as the relative humidity increases. Adding fillers, such as montmorillonite, silver nanoparticles, calcium carbonate, and graphene oxide, enhances the water-vapor permeability and mechanical properties of polysaccharide-based matrices [23]. Also, physical and chemical modifications, such as heat treatment, corona modification, plasma treatment, acetylation, periodate oxidation, etc., have been reported to improve properties such as the oxygen and water barrier of the final product [24]. Cellulose and layered silicate clay are among the most abundant polymers and minerals in nature, respectively, both of which show good compatibility with the surface chemistry of polymer composites [25]. Although similar reviews have been presented, the barrier properties of cellulose and nanoclay-based films have not been reviewed for some time despite the abundance of primary research findings. A knowledge gap and a list of unaddressed research questions are presented to aid further work in the field. 

2. Preparation of Nanocellulose

The extraction of nanocellulose consists of three stages: pretreatment, bleaching, and nano-sized cellulose isolation. 

2.1. Pretreatment Methods of Lignocellulosic Biomass

Various pretreatment methods are used to remove lignin and hemicellulose by disrupting the complex structure of lignocellulose bonded by non-covalent forces and the cross-linkages of covalent bonds, as shown in Figure 1. These methods are grouped as biological, physical (also known as mechanical), chemical, and physicochemical [26]. The pretreatment methods are illustrated in Figure 2.
Figure 1. Schematic of pretreatment of lignocellulosic components.
Figure 2. Pretreatment methods for lignocellulosic biomass residues.

2.1.1. Biological Methods

In these pretreatment methods, microorganisms are used to depolymerize the hemicellulose and lignin in lignocellulosic material, such as soft-, brown-, and white-rot fungi [27][28]. Furthermore, bacteria and actinomycetes are also microorganisms that degrade lignin using enzymes such as laccases and peroxidases [29]. Soft and white rots attack lignin and cellulose, while brown rots mainly attack cellulose [30]. This technique has the advantages of consuming low energy, emitting no toxic compounds into the environment, which makes it environmentally friendly, and requiring no chemical recycling [26][28]. The drawbacks of this method are the low hydrolysis rate compared to other technologies [27] and the time consumption [26]. Additionally, improvement in the selectivity for the preferential degradation of lignin by applying non-cellulose or cellulose-deficient white-rot fungi, thereby preserving more cellulose, is still a challenge in fungal pretreatment [29].

2.1.2. Physical Methods

The physical methods comprise mechanical extrusion, milling, ultrasound, pyrolysis, microwaves, and the pulsed electric field. Feedstock materials are heated above 300 °C under shear mixing in mechanical extrusion. This is the most canonical method for the pretreatment of biomass. However, it is a cost-intensive method that is difficult to scale up for industrial purposes because it requires a significant amount of energy [31]. Mechanical grinding, or milling, includes chipping that reduces the biomass size to 10–30 mm, whereas milling and grinding can reduce it up to 0.2–2 mm [32]. Moreover, chipping reduces the mass transfer and heat limitations, while the cellulose crystallinity and particle size are effectively reduced in milling and grinding. Different milling methods are commonly used, like ball mills, shown in Figure 3, centrifugal mills, vibratory mills, extruders, colloid mills, and attrition mills [31]. The particle size of the biomass is decreased with the degree of crystallinity of the cellulose in ball milling. However, energy is consumed, and high power is required for this method [26].
Figure 3. Ball-milling process.
Microwaves are a handy tool for modifying polymer materials by grafting, degrading, and crosslinking them [27]. They are widely used because of their advantages, such as low energy consumption, easy operation, the degradation of the cellulose fraction’s structural organization, and more [28][31]. The drawback of the microwave-heating process is that it is not uniform, meaning that standing waves are formed by the reflection of electromagnetic waves, leading to heat spots on the material [33]. A technique that is relatively new for lignocellulosic biomass pretreatment is sonication. However, it causes small cavitation bubbles, rupturing the hemicellulose and cellulose fractions. In the pulsed electric field, the biomass is subjected to a voltage ranging from 5.0 to 20.0 kV/cm [28][31][34]. However, this technique can be performed in cases that require low energy under ambient conditions [26]. The thermal decomposition of the biomass organic matrix in non-oxidizing atmospheres is known as biomass pyrolysis [35]. The low rate of cellulose decomposition is a disadvantage of this method [36].

2.1.3. Physicochemical Methods

A technique that uses both physical and chemical techniques for breaking the structure of lignocellulosic material is known as steam explosion. In this technique, the material is subjected to a high temperature and pressure for a short duration [37]. However, it has some disadvantages, such as the release of the phenolic compound during the breakdown of lignocellulose. Moreover, during pretreatment, yeast and enzyme inhibitors are generated [38]. Another method similar to steam explosion is the hot-water treatment (also called the hot-compressed-water treatment), which uses pressure up to 5 MPa and a high temperature between 170 and 230 °C instead of steam. This causes hemicellulose to hydrolyze and lignin to be removed, making the cellulose more accessible [31]. However, the extraction of hemicellulose is higher in this technique [38].
Moreover, a lot of energy is required because of the water involved in the downstream processing [31]. Two techniques have been paired by many authors, namely, Ammonia Fiber Explosion and Ammonia Recycle Percolation. In Ammonia Fiber Explosion, the biomass material is subjected to liquid anhydrous ammonia under high pressures and moderate temperatures and is then rapidly depressurized. The disadvantages are the costs associated with recycling and the treatment of the used chemicals [37]. Soaking aqueous ammonia is an ammonia-based pretreatment like Ammonia Fiber Explosion. Ammonia Recycle Percolation is a type of Ammonia Fiber Explosion that treats the biomass with aqueous ammonia in a batch reactor at 30–60 °C, reducing the liquid throughput during the pretreatment process [31].

2.1.4. Chemical Methods

A pretreatment technique used with organic acids (propionic, acetic, and formic acids) and inorganic acids (nitric, phosphoric sulfuric, and hydrochloric acids) is known as acid pretreatment. There are two types of inorganic-acid pretreatment methods, namely, dilute- and concentrated-acid pretreatment [39]. Concentrated acids are not preferred because they are corrosive and must be covered for feasible economic pretreatment [40]. Alkali pretreatment is the most effective method among the chemical pretreatments for breaking the ester bonds between cellulose, lignin, and hemicellulose, and with it, hemicellulose polymer fragmentation is avoided [41]. In alkali pretreatment, alkali compounds are used, such as calcium hydroxide, sodium hydroxide, hydrogen peroxide, potassium hydroxide, ammonium hydroxide, aqueous ammonia, or a combination. However, this pretreatment has drawbacks, such as the incorporation of salts into the biomass or their conversion to irrecoverable salts [40]. Ionic liquids are a new type of cellulose solvent known as green solvents because they do not produce any explosive or toxic gases [39]. In ionic liquids, the hydrogen bonds are broken down during the interaction of the ionic liquid and cellulose-OH, as the breaking of the cellulose molecular chains results in cellulose dissolution [42][43]. However, ionic liquids are still too expensive to be used for biomass pretreatment on a large scale, even though they are an innovative and promising biomass pretreatment technology [38]. Chemicals like acids, salts, oxidizing agents, and alkalis can degrade cellulose, lignin, and hemicelluloses from lignocellulosic waste. An aqueous or organic solvent mixed with inorganic acids (HCl or H2SO4) can also be used to break the internal lignin and hemicellulose bonds. Furthermore, organic acids, such as oxalic acid, salicylic acid, and acetylsalicylic acid, can also be catalysts [44][45][46].

2.2. Bleaching

Bleaching is also known as delignification. It is the process of the further removal of the remaining residual cementing material, mainly lignin, from alkali-treated fibers. Bleaching is a necessary additional step because the remaining content of lignin in cellulose after alkali treatment could hinder the extraction of cellulose nanocrystals and lead to a poor wettability surface between the natural fiber and polymer matrix material [16][47][48]. Bleaching is used to degrade hemicellulose and lignin to release cellulose fibers [49]. In bleaching, the solution’s temperature, concentration, time, and pH are the four primary conditions that influence the chemical reactions. Provided that the other factors are kept constant, a greater extent of cellulose is obtained by increasing the reaction time, whereas speeding up the reaction is achieved by increasing the temperature [26]. Examples of agents that are used in bleaching are sodium hypochlorite, hydrogen peroxide, and sodium chlorite [50]. By using the oxidizing agent sodium hypochlorite (NaOCl), it is possible to make lignin removal more efficient [51]. Due to the alkali-resistant linkage that is formed between lignin and hemicellulose after alkali treatment, some studies have used hydrogen peroxide treatment as a precursor to sodium chlorite treatment, which could suppress the lignin removal. In most cases, hydrogen peroxide can break the linkages and delignify lignocellulosic fibers by acting as an oxidizing agent. The bleaching process must be repeated an increasing number of times or stages until the tissues/fabrics are permanently white. Increased bleaching stages are used to increase the cellulose content while removing hemicellulose and lignin, resulting in purer and more separated cellulose fibers than with the previous process [47]. The two-stage bleaching process is shown in Figure 4 below. It can be observed that the fibers after the second stage of bleaching are whiter than those after the first stage.
Figure 4. Two-stage bleaching process.

2.3. Methods for Cellulose Nanoparticle Isolation

The simple process of nanoparticle extraction is presented in Figure 5. Fibers are extracted from the source, followed by either acid hydrolysis or mechanical disintegration. Acid hydrolysis is used for nanocrystal isolation, and mechanical disintegration is used for nanofibers. CNCs are rod-like, stiff particles consisting of cellulose chain segments that are nearly perfect crystalline structures. Cellulose nanocrystals exhibit unique liquid crystalline properties and high specific strengths, surface areas, and moduli compared to bulk cellulose, which consists of more significant amorphous fractions [52][53]. These nanocrystals are achieved via several techniques, which are employed to transform cellulose into cellulose nanocrystals. These techniques are grouped as physical hydrolysis (also known as mechanical hydrolysis), enzymatic hydrolysis, and acid hydrolysis. Compared with the mechanical method, the chemical method is better because it produces CNCs with improved crystallinity and reduces energy consumption [54]. However, acid hydrolysis is the most widely explored technique [55][56].
Polymers 16 00051 g005
Figure 5. Isolation of cellulose nanoparticles from cellulose source. Reprinted from Ref. [16] (open access).

2.3.1. Physical Methods

The mechanical techniques include microfluidization techniques, high-intensity ultrasonic treatments, and cryocrushing, which split the cellulose fibers along the longitudinal axis and help extract the cellulose microfibrils by producing enough shear force [54]. Mechanical methods have also been extensively researched for producing nanocellulose particles as part of the fabrication using enzymatic treatment, acid hydrolysis, oxidation, or a combination. These methods are commonly used to create cellulose nanofibers, which are nanometers or tens of nanometers in diameter and have lengths up to several microns [57]. Among others, ball milling is the most promising method and is widely used for CNC preparation. It is a cost-effective and environmentally friendly technique that is widely preferred over traditional methods (acid hydrolysis) involving concentrated acid. It requires the proper removal of excess acid via dialysis during centrifugation post-processing and is a time-consuming process [58][59]. Some drawbacks include contamination from the grinding containers and medium, usually metal or ceramic contamination, the formation of irregular shapes, and extended cleaning and milling times [60].

2.3.2. Enzymatic Hydrolysis

In enzymatic hydrolysis, the reaction between cellulases and cellulose is involved in degrading the cellulose into fermentable sugars. There are three main cellulose groups: Endo-Glucanase, which attacks the low-crystallinity areas of cellulose fibers and generates free chain ends; Exo-Glucanase, which produces free chain ends that are cleaved to the sugar chains; and b-Glucosidase, which releases glucose from cellobiose [61]. The enzymatic hydrolysis of cellulose offers the potential for higher selectivity, higher yields, milder operating conditions, and lower energy costs than chemical processes [62].

2.3.3. Acid Hydrolysis

Acid hydrolysis is a technique that is currently widely used for the production of nanocellulose. Several acids are used in acid hydrolysis, such as phosphoric, malic, hydrochloric, and sulfuric acids [16][55]. CNCs have recently been produced using hydrochloric, organic, phosphoric, hydrobromic, liquid, gaseous, organic, and inorganic acids. Acid hydrolysis using sulfuric acid is the oldest process, and it remains the most commonly used method for CNC preparation [53]. In acid hydrolysis, amorphous domains regularly distributed along the microfibrils are usually removed using strong-acid hydrolysis. Strong acids can easily penetrate low-order amorphous regions and hydrolyze them while leaving the crystalline regions unaffected [54]. The reaction ends with the surface hydroxyl group of nanocellulose during sulfuric acid hydrolysis, yielding surface sulfate groups, which leads to a negatively charged layer on the nanocrystals. This improves the phase stability of nanocrystalline particles in aqueous solutions even more [55].

References

  1. Lindström, T.; Österberg, F. Evolution of biobased and nanotechnology packaging—A review. Nord. Pulp Pap. Res. J. 2020, 35, 491–515.
  2. Bardet, R.; Reverdy, C.; Belgacem, N.; Leirset, I.; Syverud, K.; Bardet, M.; Bras, J. Substitution of nanoclay in high gas barrier films of cellulose nanofibrils with cellulose nanocrystals and thermal treatment. Cellulose 2015, 22, 1227–1241.
  3. Abelti, A.L.; Teka, T.A.; Fikreyesus Forsido, S.; Tamiru, M.; Bultosa, G.; Alkhtib, A.; Burton, E. Bio-based smart materials for fish product packaging: A review. Int. J. Food Prop. 2022, 25, 857–871.
  4. Palali, S.N. Cellulose Nanocrystals: Potential Replacement for Food Packaging. Science 2019, 39–73.
  5. Romão, S.; Bettencourt, A.; Ribeiro, I.A. Novel Features of Cellulose-Based Films as Sustainable Alternatives for Food Packaging. Polymers 2022, 14, 4968.
  6. Ohlrogge, J.; Allen, D.; Berguson, B.; DellaPenna, D.; Shachar-Hill, Y.; Stymne, S. Driving on biomass. Science 2009, 324, 1019–1020.
  7. Abdullah, J.A.A.; Jiménez-Rosado, M.; Guerrero, A.; Romero, A. Biopolymer-Based Films Reinforced with Green Synthesized Zinc Oxide Nanoparticles. Polymers 2022, 14, 5202.
  8. Cakmak, H.; Dekker, M. Optimization of Cellulosic Fiber Extraction from Parsley Stalks and Utilization as Filler in Composite Biobased Films. Foods 2022, 11, 3932.
  9. Fang, Z.; Hou, G.; Chen, C.; Hu, L. Nanocellulose-based films and their emerging applications. Curr. Opin. Solid State Mater. Sci. 2019, 23, 100764.
  10. Li, J.; Song, Z.; Li, D.; Shang, S.; Guo, Y. Cotton cellulose nanofiber-reinforced high density polyethylene composites prepared with two different pretreatment methods. Ind. Crops Prod. 2014, 59, 318–328.
  11. Rodríguez-Fabià, S.; Torstensen, J.; Johansson, L.; Syverud, K. Hydrophobization of lignocellulosic materials part III: Modification with polymers. Cellulose 2022, 29, 5943–5977.
  12. Boluk, Y.; Lahiji, R.; Zhao, L.; McDermott, M.T. Suspension viscosities and shape parameter of cellulose nanocrystals (CNC). Colloids Surf. A Physicochem. Eng. Asp. 2011, 377, 297–303.
  13. Siró, I.; Plackett, D. Microfibrillated cellulose and new nanocomposite materials: A review. Cellulose 2010, 17, 459–494.
  14. Hua, K.; Carlsson, D.O.; Ålander, E.; Lindström, T.; Strømme, M.; Mihranyan, A.; Ferraz, N. Translational study between structure and biological response of nanocellulose from wood and green algae. RSC Adv. 2014, 4, 2892–2903.
  15. Jonoobi, M.; Oladi, R.; Davoudpour, Y.; Oksman, K.; Dufresne, A.; Hamzeh, Y.; Davoodi, R. Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: A review. Cellulose 2015, 22, 935–969.
  16. Poulose, A.; Parameswaranpillai, J.; George, J.J.; Gopi, J.A.; Krishnasamy, S.; Dominic, C.D.M.; Hameed, N.; Salim, N.V.; Radoor, S.; Sienkiewicz, N. Nanocellulose: A Fundamental Material for Science and Technology Applications. Molecules 2022, 27, 8032.
  17. Wang, C.; Shi, J.; He, M.; Ding, L.; Li, S.; Wang, Z.; Wei, J. High strength cellulose/ATT composite films with good oxygen barrier property for sustainable packaging applications. Cellulose 2018, 25, 4145–4154.
  18. Ai, B.; Zheng, L.; Li, W.; Zheng, X.; Yang, Y.; Xiao, D.; Shi, J.; Sheng, Z. Biodegradable cellulose film prepared from banana pseudo-stem using an ionic liquid for mango preservation. Front. Plant Sci. 2021, 12, 625878.
  19. Taherimehr, M.; YousefniaPasha, H.; Tabatabaeekoloor, R.; Pesaranhajiabbas, E. Trends and challenges of biopolymer-based nanocomposites in food packaging. Compr. Rev. Food Sci. Food Saf. 2021, 20, 5321–5344.
  20. Nair, S.S.; Zhu, J.; Deng, Y.; Ragauskas, A.J. High performance green barriers based on nanocellulose. Sustain. Chem. Process. 2014, 2, 1–7.
  21. Sethi, J.; Wågberg, L.; Larsson, P.A. Water-resistant hybrid cellulose nanofibril films prepared by charge reversal on gibbsite nanoclays. Carbohydr. Polym. 2022, 295, 119867.
  22. Yu, Z.; Ji, Y.; Bourg, V.; Bilgen, M.; Meredith, J.C. Chitin-and cellulose-based sustainable barrier materials: A review. Emergent Mater. 2020, 3, 919–936.
  23. Abdul Khalil, H.P.S.; Chong, E.W.N.; Owolabi, F.A.T.; Asniza, M.; Tye, Y.Y.; Rizal, S.; Nurul Fazita, M.R.; Mohamad Haafiz, M.K.; Nurmiati, Z.; Paridah, M.T. Enhancement of basic properties of polysaccharide-based composites with organic and inorganic fillers: A review. J. Appl. Polym. Sci. 2019, 136, 47251.
  24. Saedi, S.; Garcia, C.V.; Kim, J.T.; Shin, G.H. Physical and chemical modifications of cellulose fibers for food packaging applications. Cellulose 2021, 28, 8877–8897.
  25. Hussin, F.N.N.M.; Wahab, R.A.; Attan, N. Nanocellulose and nanoclay as reinforcement materials in polymer composites: A review. Malays. J. Fundam. Appl. Sci. 2020, 16, 145–153.
  26. Mdletshe, G.P. Extraction and Characterisation of Cellulose Nanocrystals (CNCs) from Sugarcane Bagasse Using Ionic Liquids. Ph.D. Thesis, Durban University of Technoloy, Durban, South Africa, 2019.
  27. Beig, B.; Riaz, M.; Naqvi, S.R.; Hassan, M.; Zheng, Z.; Karimi, K.; Pugazhendhi, A.; Atabani, A.; Chi, N.T.L. Current challenges and innovative developments in pretreatment of lignocellulosic residues for biofuel production: A review. Fuel 2021, 287, 119670.
  28. Bhutto, A.W.; Qureshi, K.; Harijan, K.; Abro, R.; Abbas, T.; Bazmi, A.A.; Karim, S.; Yu, G. Insight into progress in pre-treatment of lignocellulosic biomass. Energy 2017, 122, 724–745.
  29. Das, N.; Jena, P.K.; Padhi, D.; Kumar Mohanty, M.; Sahoo, G. A comprehensive review of characterization, pretreatment and its applications on different lignocellulosic biomass for bioethanol production. Biomass Convers. Biorefin. 2021, 13, 1503–1527.
  30. Saritha, M.; Arora, A.; Lata. Biological Pretreatment of Lignocellulosic Substrates for Enhanced Delignification and Enzymatic Digestibility. Indian J. Microbiol. 2012, 52, 122–130.
  31. Cheng, J.J.; Timilsina, G.R. Status and barriers of advanced biofuel technologies: A review. Renew. Energy 2011, 36, 3541–3549.
  32. Kumar, A.K.; Sharma, S. Recent updates on different methods of pretreatment of lignocellulosic feedstocks: A review. Bioresour. Bioprocess 2017, 4, 7.
  33. Sun, Y.; Cheng, J. Hydrolysis of lignocellulosic materials for ethanol production: A review. Bioresour. Technol. 2002, 83, 1–11.
  34. Aguilar-Reynosa, A.; Romaní, A.; Rodríguez-Jasso, R.M.; Aguilar, C.N.; Garrote, G.; Ruiz, H.A. Microwave heating processing as alternative of pretreatment in second-generation biorefinery: An overview. Energy Convers. Manag. 2017, 136, 50–65.
  35. Kumar, P.; Barrett, D.M.; Delwiche, M.J.; Stroeve, P. Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Ind. Eng. Chem. Res. 2009, 48, 3713–3729.
  36. Kan, T.; Strezov, V.; Evans, T.J. Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters. Renew. Sustain. Energy Rev. 2016, 57, 1126–1140.
  37. Sarkar, N.; Ghosh, S.K.; Bannerjee, S.; Aikat, K. Bioethanol production from agricultural wastes: An overview. Renew. Energy 2012, 37, 19–27.
  38. Brodeur, G.; Yau, E.; Badal, K.; Collier, J.; Ramachandran, K.B.; Ramakrishnan, S. Chemical and physicochemical pretreatment of lignocellulosic biomass: A review. Enzym. Res 2011, 2011, 787532.
  39. Teixeira, R.S.S.; Silva, A.S.; Moutta, R.O.; Ferreira-Leitão, V.S.; Barros, R.R.O.; Ferrara, M.A.; Bon, E.P.S. Biomass pretreatment: A critical choice for biomass utilization via biotechnological routes. BMC Proc. 2014, 8, O34.
  40. Chen, H.; Liu, J.; Chang, X.; Chen, D.; Xue, Y.; Liu, P.; Lin, H.; Han, S. A review on the pretreatment of lignocellulose for high-value chemicals. Fuel Process. Technol. 2017, 160, 196–206.
  41. Behera, S.; Arora, R.; Nandhagopal, N.; Kumar, S. Importance of chemical pretreatment for bioconversion of lignocellulosic biomass. Renew. Sustain. Energy Rev. 2014, 36, 91–106.
  42. Gáspár, M.; Kálmán, G.; Réczey, K. Corn fiber as a raw material for hemicellulose and ethanol production. Process Biochem. 2007, 42, 1135–1139.
  43. Zhao, Y.; Wang, J.; Liu, X.; Zhang, S. Effects of cationic structure on cellulose dissolution in ionic liquids: A molecular dynamics study. ChemPhysChem 2012, 13, 3126–3133.
  44. Feng, L.; Chen, Z.-L. Research progress on dissolution and functional modification of cellulose in ionic liquids. J. Mol. Liq. 2008, 142, 1–5.
  45. Aita, G.M.; Kim, M. Pretreatment Technologies for the Conversion of Lignocellulosic Materials to Bioethanol. In Sustainability of the Sugar and Sugar−Ethanol Industries; ACS Symposium Series; American Chemical Society: Washington, DC, USA, 2010; pp. 117–145.
  46. Carvalheiro, F.; Duarte, L.C.; Gírio, F.M. Hemicellulose biorefineries: A review on biomass pretreatments. J. Sci. Ind. Res. 2008, 67, 849–864.
  47. Singh, L.K.; Chaudhary, G.; Majumder, C.; Ghosh, S. Utilization of hemicellulosic fraction of lignocellulosic biomaterial for bioethanol production. Adv. Appl. Sci. Res. 2011, 2, 508–521.
  48. Ng, H.-M.; Sin, L.T.; Tee, T.-T.; Bee, S.-T.; Hui, D.; Low, C.-Y.; Rahmat, A.R. Extraction of cellulose nanocrystals from plant sources for application as reinforcing agent in polymers. Compos. Part B Eng. 2015, 75, 176–200.
  49. Hazwan Hussin, M.; Trache, D.; Chuin, C.T.H.; Nurul Fazita, M.; Mohamad Haafiz, M.; Hossain, M. Extraction of cellulose nanofibers and their eco-friendly polymer composites. In Sustainable Polymer Composites and Nanocomposites; Springer: Berlin/Heidelberg, Germany, 2019; pp. 653–691.
  50. Pereira, A.L.S.; Nascimento, D.M.; Cordeiro, E.M.S.; Morais, J.P.S.; Sousa, M.d.S.M.; Rosa, M.d.F. Characterization of Lignocellulosic Materials Extracted from the Banana Pseudostem. 2010. Available online: https://ainfo.cnptia.embrapa.br/digital/bitstream/item/34240/1/AT10096.pdf (accessed on 5 April 2023).
  51. Aridi, A.S.; Chin, N.L.; Ishak, N.A.; Yusof, N.N.M.; Kadota, K.; Manaf, Y.N.; Yusof, Y.A. Effect of Sodium Hypochlorite Concentration during Pre-treatment on Isolation of Nanocrystalline Cellulose from Leucaena leucocephala (Lam.) Mature Pods. BioResources 2021, 16, 3137.
  52. Shin, H.K.; Pyo Jeun, J.; Bin Kim, H.; Hyun Kang, P. Isolation of cellulose fibers from kenaf using electron beam. Radiat. Phys. Chem. 2012, 81, 936–940.
  53. Trache, D.; Tarchoun, A.F.; Derradji, M.; Hamidon, T.S.; Masruchin, N.; Brosse, N.; Hussin, M.H. Nanocellulose: From Fundamentals to Advanced Applications. Front. Chem. 2020, 8, 392.
  54. George, J.; Sabapathi, S.N. Cellulose nanocrystals: Synthesis, functional properties, and applications. Nanotechnol. Sci. Appl. 2015, 8, 45–54.
  55. Marakana, P.G.; Dey, A.; Saini, B. Isolation of nanocellulose from lignocellulosic biomass: Synthesis, characterization, modification, and potential applications. J. Environ. Chem. Eng. 2021, 9, 106606.
  56. Tahir, D.; Karim, M.R.A.; Hu, H.; Naseem, S.; Rehan, M.; Ahmad, M.; Zhang, M. Sources, Chemical Functionalization, and Commercial Applications of Nanocellulose and Nanocellulose-Based Composites: A Review. Polymers 2022, 14, 4468.
  57. Trache, D.; Hussin, M.H.; Haafiz, M.M.; Thakur, V.K. Recent progress in cellulose nanocrystals: Sources and production. Nanoscale 2017, 9, 1763–1786.
  58. Rana, A.K.; Frollini, E.; Thakur, V.K. Cellulose nanocrystals: Pretreatments, preparation strategies, and surface functionalization. Int. J. Biol. Macromol. 2021, 182, 1554–1581.
  59. Piras, C.C.; Fernández-Prieto, S.; De Borggraeve, W.M. Ball milling: A green technology for the preparation and functionalisation of nanocellulose derivatives. Nanoscale Adv. 2019, 1, 937–947.
  60. Ferreira, R.R.; Souza, A.G.; Nunes, L.L.; Shahi, N.; Rangari, V.K.; dos Santos Rosa, D. Use of ball mill to prepare nanocellulose from eucalyptus biomass: Challenges and process optimization by combined method. Mater. Today Commun. 2020, 22, 100755.
  61. Shokrkar, H.; Ebrahimi, S.; Zamani, M. A review of bioreactor technology used for enzymatic hydrolysis of cellulosic materials. Cellulose 2018, 25, 6279–6304.
  62. Yang, B.; Dai, Z.; Ding, S.-Y.; Wyman, C.E. Enzymatic hydrolysis of cellulosic biomass. Biofuels 2014, 2, 421–449.
More
© Text is available under the terms and conditions of the Creative Commons Attribution (CC BY) license; additional terms may apply. By using this site, you agree to the Terms and Conditions and Privacy Policy.
Upload a video for this entry
Information
Subjects: Materials Science, Biomaterials
Contributors MDPI registered users' name will be linked to their SciProfiles pages. To register with us, please refer to https://encyclopedia.pub/register :
Sandile Jali
,
Turup Pandurangan Mohan
,
Festus Maina Mwangi
,
Krishnan Kanny
View Times: 268
Revisions: 2 times (View History)
Update Date: 29 Dec 2023
Table of Contents
    1000/1000
    Hot Most Recent
    ScholarVision Creations
    Feedback