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Kraka, E.; , . Role of Uranium in the Nuclear Fuel Cycle. Encyclopedia. Available online: https://encyclopedia.pub/entry/23155 (accessed on 24 April 2024).
Kraka E,  . Role of Uranium in the Nuclear Fuel Cycle. Encyclopedia. Available at: https://encyclopedia.pub/entry/23155. Accessed April 24, 2024.
Kraka, Elfi, . "Role of Uranium in the Nuclear Fuel Cycle" Encyclopedia, https://encyclopedia.pub/entry/23155 (accessed April 24, 2024).
Kraka, E., & , . (2022, May 20). Role of Uranium in the Nuclear Fuel Cycle. In Encyclopedia. https://encyclopedia.pub/entry/23155
Kraka, Elfi and . "Role of Uranium in the Nuclear Fuel Cycle." Encyclopedia. Web. 20 May, 2022.
Role of Uranium in the Nuclear Fuel Cycle
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This entry is adapted from the peer-reviewed paper 10.3390/ijms23094655

Uranium was discovered in 1789 by the German chemist Martin Heinrich Klaproth. It is the most known and used actinide element mainly because of its usage in nuclear fuel processing; however, the application potential of uranium compounds is much broader, stretching, e.g., into the field of organometallic synthesis, catalysis and beyond. Moreover, uranium is one of the few naturally occurring actinides, whereas the other members, with the exception of thorium, are considered to be human-made, despite their natural occurrence in traces as a result of uranium and thorium spontaneous fissions. In nature, uranium occurs as three main isotopes, where the non-fissile 238U is the most abundant, encompassing over 99% of the available uranium resources.

uranium nuclear energy Nuclear fuel cycle

1. Introduction

Uranium was discovered in 1789 by the German chemist Martin Heinrich Klaproth [1]. It is the most known and used actinide element mainly because of its usage in nuclear fuel processing; however, the application potential of uranium compounds is much broader, stretching, e.g., into the field of organometallic synthesis, catalysis and beyond, as sketched in Figure 1 [2][3][4][5][6][7][8][9][10][11][12][13]. Moreover, uranium is one of the few naturally occurring actinides [1], whereas the other members, with the exception of thorium, are considered to be human-made, despite their natural occurrence in traces as a result of uranium and thorium spontaneous fissions. In nature, uranium occurs as three main isotopes, where the non-fissile 238U is the most abundant, encompassing over 99% of the available uranium resources.
Ijms 23 04655 g001 550
Figure 1. Examples of the broad range of uranium use.
In the Earth’s crust, there are different types of uranium ores, such as uraninite or pitchblende (xUO2⋅yUO3, with y/x < 2), carnotite (K2O·2UO3⋅V2O5⋅xH2O) and autunite (CaO·2UO3⋅P2O5⋅xH2O) [14][15]. In order to extract uranium from its ore, chemical processes utilizing acids and oxidizing agents are employed. Often, specific isotopic separation processes have to be applied in order to acquire the desired concentration of a given uranium isotope for energy generation purposes [1]. The most used isotopic separation process involves uranium conversion into the gaseous UF6 followed by isotope separation due to mass differences [16].
A number of reviews have been previously published covering the industrial use of uranium, i.e., in energy supply and related fields [15][17][18][19][20][21]. Organouranium compounds, i.e., the uranium equivalent of organometallic complexes, have attracted considerable attention, including reviews on (η8-C8H8)2U and actinides cyclobutadienyl complexes, respectively [22][23].
Uranium coordination chemistry, in general, has been being widely investigated [9][24][25][26], especially with regard to possible applications in nuclear waste treatment [27], where the efficient extraction of uranium from the waste generated during the nuclear fuel cycle (so-called spent nuclear fuel), and its recycling into the nuclear fuel process is an important step to reduce long-term radioactive waste [28][29][30][31][32]. Uranium oxides have been used for a long time as nuclear fuel [33][34]. However, their handling in the spent nuclear fuel regeneration process is difficult [35].

2. Role of Uranium in the Nuclear Fuel Cycle

Uranium is mainly used in the nuclear fuel cycle sketched in Figure 2, an industrial process involving various activities to produce electricity from uranium in nuclear power reactors, i.e., the progression of nuclear fuel from creation to disposal. Typically, uranium is employed in the form of UO2. During uranium decay, fissile plutonium is produced. As spent fuel can be reprocessed and recycled, this explains the presence of a plutonium admixture with uranium in the subsequent fuel cycle [14][36].
Figure 2. Nuclear fuel cycle. Source: Pennsylvania State University Radiation Science and Engineering Center (public domain).
Uranium is a relatively common element that is found throughout the world and mined in a number of countries. After mining, uranium ore is crushed in a mill and grounded to a fine slurry, which is leached in sulfuric acid (or sometimes a strong alkaline solution) to allow the separation of uranium from the waste rock. It is then recovered from solution and precipitated as uranium oxide concentrate, mostly U3O8, which is sometimes referred to as yellowcake uranium (caused by its khaki color). U3O8 concentrate typically contains more than 80% uranium. The original ore, by comparison, may contain as little as 0.1% uranium [14][36].
Often, the yellowcake needs to be highly purified, due to impurities originated from the ore that remain, a process that is highly specific and depends on the ore quality [37]. Alternate processes have been proposed, such as supercritical carbon dioxide extraction, in particular for phosphate ores [38][39]. Purified U3O8 is the product that is sold. About 200 tonnes are required to keep a large (1000 MWe) nuclear power reactor generating electricity for a year.
The uranium oxide obtained after uranium milling is not directly usable as fuel for a nuclear reactor—additional processing is required. Only 0.7% of natural uranium is fissile—capable of undergoing fission, the process by which energy is produced in a nuclear reactor. The form (or isotope) of uranium that is fissile is 235U, whereas the remainder is 238U. About 3.5–5% of the fissile isotope 235U is required to maintain the chain reaction. Therefore, a physical process commonly called uranium enrichment has to be invoked to increase (or ‘enrich’) the 235U concentration, which requires uranium to be in a gaseous form [1]. U3O8 is first refined to uranium dioxide UO2, which can be directly used as fuel for those types of reactors that do not require enriched uranium. For reactors requiring enriched uranium, UO2 is converted into uranium hexafluoride, which is a gas at relatively low temperatures. In order to produce UF6, UO2 is first converted into the solid UF4, followed by oxidation with F2, yielding UF6(g).
This route is often preferable instead of the direct conversion of the oxide into the fluoride, due to the lower fluorine demand. Solid state reactions often lead to byproducts, which also have to be taken into account [37][40][41][42]. A gas-phase mechanism for such reactions was previously studied theoretically [43]. Currently, centrifuges are used for U-enrichment processes. Nonetheless, there are alternative techniques, such as gaseous diffusion, which was widely used in the past, and laser-based processes, which are still in development [44].
Subsequently, uranium has to be re-converted to its oxide form. There are several processes available, including wet conversions employing aqueous ammonia, for example, which hydrolyses UF6, followed by calcination. An alternative process is dry conversion, which is known to be less injurious for the environment. Independent of the method used, it is important that the final product—the actual reactor fuel—has the correct oxygen to uranium ratio [36]. In order to increase the stability and strength, nuclear fuel can be alloyed with zirconium [14][36][45], which has also drawn attention due to its potential use in spent fuel reprocessing [46][47].
The fission process transforms U (and Pu) into lighter elements, denoted as fissile products, which are often also radioactive. Thus, there are safety concerns regarding nuclear waste. Spent fuel still contains large amounts of uranium, known as depleted uranium and, therefore, can be recycled and reused from nuclear waste [14]; however, the often highly radioactive fissile products have to be safely stored [14][48].
As alternative to uranium oxides, uranium nitrides are discussed as novel nuclear fuel as they display higher values for thermal conductivity and melting point [49]. The species N≡U≡N was first obtained in an argon matrix through a molecular nitrogen reaction with atomic uranium. Clearly, uranium has the potential to break the triple bond in N2 [50]. A recent investigation of N≡U≡N in both neutral and negatively charged states has led to new insights into the properties of this molecule in both the ground and excited states [51].
Other uranium nitrides followed, such as the related NUO, that was first observed in solid argon as a product of the reaction between U and NO, and density functional theory calculations predicted a duplet spin state [52]. NUO was also synthesized in solid neon by Zhou and Andrews [53]. A related species, NUNH, was observed as a product of the N≡U≡N reaction with hydrogen atoms, suggesting that NUNH features both double and triple uranium-nitrogen bonds [54].

References

  1. Cotton, S. Introduction to the Actinides. In Lanthanide and Actinide Chemistry; John Wiley & Sons, Ltd.: West Sussex, UK, 2006; Chapter 9; pp. 145–153.
  2. Xin, X.; Douair, I.; Zhao, Y.; Wang, S.; Maron, L.; Zhu, C. Dinitrogen Cleavage by a Heterometallic Cluster Featuring Multiple Uranium-Rhodium Bonds. J. Am. Chem. Soc. 2020, 142, 15004–15011.
  3. Tsoureas, N.; Mansikkamäki, A.; Layfield, R.A. Uranium(IV) cyclobutadienyl sandwich compounds: Synthesis, structure and chemical bonding. Chem. Commun. 2020, 56, 944–947.
  4. Guo, F.S.; Tsoureas, N.; Huang, G.Z.; Tong, M.L.; Mansikkamäki, A.; Layfield, R.A. Isolation of a Perfectly Linear Uranium(II) Metallocene. Angew. Chem. Int. Ed. 2020, 59, 2299–2303.
  5. Boreen, M.A.; McCabe, K.N.; Lohrey, T.D.; Watt, F.A.; Maron, L.; Hohloch, S.; Arnold, J. Uranium Metallocene Azides, Isocyanates, and Their Borane-Capped Lewis Adducts. Inorg. Chem. 2020, 591, 8580–8588.
  6. Boreen, M.A.; Lohrey, T.D.; Rao, G.; Britt, R.D.; Maron, L.; Arnold, J. A Uranium Tri-Rhenium Triple Inverse Sandwich Compound. J. Am. Chem. Soc. 2019, 141, 5144–5148.
  7. Boronski, J.T.; Doyle, L.R.; Seed, J.A.; Wooles, A.J.; Liddle, S.T. f-Element Half-Sandwich Complexes: A Tetrasilylcyclobutadienyl-Uranium(IV)-Tris(tetrahydroborate) Anion Pianostool Complex. Angew. Chem. Int. Ed. 2019, 59, 295–299.
  8. Terrani, K.A.; Jolly, B.C.; Harp, J.M. Uranium nitride tristructural-isotropic fuel particle. J. Nucl. Mater. 2020, 531, 152034.
  9. Hartline, D.R.; Meyer, K. From chemical curiosities and trophy molecules to uranium-based catalysis: Developments for uranium catalysis as a new facet in molecular uranium chemistry. JACS Au 2021, 1, 698–709.
  10. Feng, G.; Zhang, M.; Shao, D.; Wang, X.; Wang, S.; Maron, L.; Zhu, C. Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds. Nat. Chem. 2019, 11, 248–253.
  11. Das, D.; Joshi, M.; Kannan, S.; Kumar, M.; Ghanty, T.K.; Vincent, T.; Manohar, S.; Kaushik, C. A Combined Experimental and Quantum Chemical Studies on the Structure and Binding Preferences of Picolinamide Based Ligands with Uranyl Nitrate. Polyhedron 2019, 171, 486–492.
  12. Lu, G.; Haes, A.J.; Forbes, T.Z. Detection and Identification of Solids, Surfaces, and Solutions of Uranium Using Vibrational Spectroscopy. Coord. Chem. Rev. 2018, 374, 314–344.
  13. Palumbo, C.T.; Scopelliti, R.; Zivkovic, I.; Mazzanti, M. C-H Bond Activation by an Isolated Dinuclear U(III)/U(IV) Nitride. J. Am. Chem. Soc. 2020, 142, 3149–3157.
  14. Loveland, W.D.; Morrissey, D.J.; Seaborg, G.T. Modern Nuclear Chemistry; John Wiley & Sons: New York, NY, USA, 2017.
  15. Navrotsky, A.; Shvareva, T.; Guo, X.; Burns, P. Thermodynamics of uranium minerals and related materials. In Uranium: Cradle to Grave; Burns, P.C., Sigmin, G.E., Eds.; Mineralogical Association of Canada: Winnipeg, MB, Canada, 2013; pp. 147–164.
  16. Olander, D.R. The theory of uranium enrichment by the gas centrifuge. Prog. Nucl. Energy 1981, 8, 1–33.
  17. Mazher, A.K. A review of uranium economics. Int. J. Nucl. Gov. Econ. Ecol. 2009, 2, 337–361.
  18. Edwards, C.; Oliver, A. Uranium processing: A review of current methods and technology. JOM 2000, 52, 12–20.
  19. Ho, M.; Obbard, E.; Burr, P.A.; Yeoh, G. A review on the development of nuclear power reactors. Energy Procedia 2019, 160, 459–466.
  20. Gorman-Lewis, D.; Burns, P.C.; Fein, J.B. Review of uranyl mineral solubility measurements. J. Chem. Thermodyn. 2008, 40, 335–352.
  21. Krivovichev, S.V.; Plášil, J. Mineralogy and crystallography of uranium. In Uranium: From Cradle to Grave; Burns, P.C., Sigmon, G.E., Eds.; Mineralogical Association of Canada Short Courses: Quebec, QC, Canada, 2013; Volume 43, pp. 15–119.
  22. Seyferth, D. Uranocene: The first member of a new class of organometallic derivatives of the f elements. Organometallics 2004, 23, 3562–3583.
  23. Boronski, J.T.; Liddle, S.T. The Emergence of Actinide Cyclobutadienyl Chemistry. Eur. J. Inorg. Chem. 2020, 2020, 2851–2861.
  24. Sessler, J.L.; Melfi, P.J.; Pantos, G.D. Uranium complexes of multidentate N-donor ligands. Coord. Chem. Rev. 2006, 250, 816–843.
  25. Van Horn, J.D.; Huang, H. Uranium (VI) bio-coordination chemistry from biochemical, solution and protein structural data. Coord. Chem. Rev. 2006, 250, 765–775.
  26. Yang, W.; Parker, T.G.; Sun, Z.M. Structural chemistry of uranium phosphonates. Coord. Chem. Rev. 2015, 303, 86–109.
  27. Dam, H.H.; Reinhoudt, D.N.; Verboom, W. Multicoordinate ligands for actinide/lanthanide separations. Chem. Soc. Rev. 2007, 36, 367–377.
  28. Nash, K.L.; Nilsson, M. Introduction to the reprocessing and recycling of spent nuclear fuels. In Reprocessing and Recycling of Spent Nuclear Fuel; Taylor, R., Ed.; Woodhead Publishing Series in Energy; Woodhead Publishing: Oxford, UK, 2015; pp. 3–25.
  29. Geist, A.; Adnet, J.M.; Bourg, S.; Ekberg, C.; Galan, H.; Guilbaud, P.; Miguirditchian, M.; Modolo, G.; Rhodes, C.; Taylor, R. An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, part 1—Heterogeneous recycling. Sep. Sci. Technol. 2021, 56, 1866–1881.
  30. Taylor, R.; Bodel, W.; Stamford, L.; Butler, G. A Review of Environmental and Economic Implications of Closing the Nuclear Fuel Cycle—Part One: Wastes and Environmental Impacts. Energies 2022, 15, 1433.
  31. Ewing, R.C.; Weber, W.J.; Clinard, F.W., Jr. Radiation effects in nuclear waste forms for high-level radioactive waste. Prog. Nucl. Energy 1995, 29, 63–127.
  32. Ewing, R.C.; Weber, W.J.; Lian, J. Nuclear waste disposal—Pyrochlore (A2B2O7): Nuclear waste form for the immobilization of plutonium and “minor” actinides. J. Appl. Phys. 2004, 95, 5949–5971.
  33. McEachern, R.J.; Taylor, P. A review of the oxidation of uranium dioxide at temperatures below 400 °C. J. Nucl. Mater. 1998, 254, 87–121.
  34. Belle, J. Oxygen and uranium diffusion in uranium dioxide (a review). J. Nucl. Mater. 1969, 30, 3–15.
  35. Yoo, T.S.; Herrmann, S.D.; Yoon, S.J.; Marsden, K.C. Analysis and Modeling of Oxide Reduction Processes for Uranium Oxides. J. Nucl. Mater. 2021, 545, 152625.
  36. Crossland, I. Nuclear Fuel Cycle Science and Engineering; Elsevier: Amsterdam, The Netherlands, 2012.
  37. Wilson, P.D. The Nuclear Fuel Cycle from Ore to Wastes; Oxford Science Publications: Oxford, UK, 1996.
  38. Leybros, A.; Hung, L.; Hertz, A.; Hartmann, D.; Grandjean, A.; Boutin, O. Supercritical CO2 extraction of uranium from natural ore using organophosphorus extractants. Chem. Eng. J. 2017, 316, 196–203.
  39. Prabhat, P.; Rao, A.; Mishra, V.G.; Shah, D.J.; Kumar, P.; Tomar, B.S. Direct extraction of uranium from yellow cake and ore matrices using supercritical carbon dioxide. Radiochim. Acta 2020, 108, 769–777.
  40. Zachariasen, W. The Crystal Structure of U2F9. J. Chem. Phys. 1948, 16, 425.
  41. Zachariasen, W. Crystal Chemical Studies of the 5f-Series of Elements. XI. The Crystal Structure of α-UF5 and of β-UF5. Acta Crystallogr. 1949, 2, 296–298.
  42. Cotton, S. Binary Compounds of the Actinides. In Lanthanide and Actinide Chemistry; John Wiley & Sons, Ltd.: West Sussex, UK, 2006; Chapter 10; pp. 155–172.
  43. Peluzo, B.M.; Galvão, B.R. Theoretical study on the structure and reactions of uranium fluorides. J. Mol. Model. 2018, 24, 197.
  44. Krass, A.S. Uranium Enrichment and Nuclear Weapon Proliferation; Oxford University Press: Oxford, UK, 1983.
  45. Katoh, Y.; Vasudevamurthy, G.; Nozawa, T.; Snead, L.L. Properties of zirconium carbide for nuclear fuel applications. J. Nucl. Mater. 2013, 441, 718–742.
  46. McDeavitt, S.; Abraham, D.; Park, J. Evaluation of stainless steel–zirconium alloys as high-level nuclear waste forms. J. Nucl. Mater. 1998, 257, 21–34.
  47. Ali, K.; Ghosh, P.; Arya, A. A DFT study of structural, elastic and lattice dynamical properties of Fe2Zr and FeZr2 intermetallics. J. Alloys Compd. 2017, 723, 611–619.
  48. Basdevant, J.L.; Rich, J. Fundamentals in Nuclear Physics: From Nuclear Structure to Cosmology; Springer Science & Business Media: New York, NY, USA, 2005.
  49. Streit, M.; Ingold, F. Nitrides as a nuclear fuel option. J. Eur. Ceram. Soc. 2005, 25, 2687–2692.
  50. Hunt, R.D.; Yustein, J.T.; Andrews, L. Matrix infrared spectra of NUN formed by the insertion of uranium atoms into molecular nitrogen. J. Chem. Phys. 1993, 98, 6070–6074.
  51. Liu, G.; Zhang, C.; Ciborowski, S.M.; Asthana, A.; Cheng, L.; Bowen, K.H. Mapping the electronic structure of the uranium (VI) dinitride molecule, UN2. J. Phys. Chem. A 2020, 124, 6486–6492.
  52. Kushto, G.P.; Souter, P.F.; Andrews, L.; Neurock, M. A matrix isolation FT–IR and quasirelativistic density functional theory investigation of the reaction products of laser-ablated uranium atoms with NO, NO2 and N2O. J. Chem. Phys. 1998, 106, 5894–5903.
  53. Zhou, M.; Andrews, L. Infrared spectra and pseudopotential calculations for NUO+, NUO, and NThO in solid neon. J. Chem. Phys. 1999, 111, 11044–11049.
  54. Wang, X.; Andrews, L.; Vlaisavljevich, B.; Gagliardi, L. Combined Triple and Double Bonds to Uranium: The N≡U=N-H Uranimine Nitride Molecule Prepared in Solid Argon. Inorg. Chem. 2011, 50, 3826–3831.
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