Summary

Physics advocates research on unifying chemical bonds and recognized parallels on a different (and non-reductive) level, as per the concept of the Great Unification of Forces in Nature. From this perspective, a Physicochemical Grand Unification of Forces would be a worthy project for humankind in order to increase our undertanding of existence and to improve our lives. This entry collection aims to present an account of chemical bonds and interactions in nano- to maco-environments.

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Topic Review
Characterization of Ti/SnO2 Interface by X-ray Photoelectron Spectroscopy
The Ti/SnO2 interface has been investigated in situ via the technique of x-ray photoelectron spectroscopy. Thin films (in the range from 0.3 to 1.1 nm) of titanium were deposited on SnO2 substrates via the e-beam technique. The deposition was carried out at two different substrate temperatures, namely room temperature and 200 °C. The photoelectron spectra of tin and titanium in the samples were found to exhibit significant differences upon comparison with the corresponding elemental and the oxide spectra. These changes result from chemical interaction between SnO2 and the titanium overlayer at the interface. The SnO2 was observed to be reduced to elemental tin while the titanium overlayer was observed to become oxidized. Complete reduction of SnO2 to elemental tin did not occur even for the lowest thickness of the titanium overlayer. The interfaces in both the types of the samples were observed to consist of elemental Sn, SnO2, elemental titanium, TiO2, and Ti-suboxide. 
  • 1.3K
  • 26 Jan 2022
Topic Review
Mechanochemistry in Portugal
In Portugal, publications with mechanochemical methods date back to 2009, with the report on mechanochemical strategies for the synthesis of metallopharmaceuticals. Since then, mechanochemical applications have grown in Portugal, spanning several fields, mainly crystal engineering and supramolecular chemistry, catalysis, and organic and inorganic chemistry.
  • 1.4K
  • 24 Jan 2022
Topic Review
Binders Used for the Manufacturing of Composite Materials
Binders, or tackifiers, have become widespread in the production of new composite materials by liquid composite molding (LCM) techniques due to their ability to stabilize preforms during laying-up and impregnation, as well as to improve fracture toughness of the obtained composites, which is very important in aviation, automotive, ship manufacturing, etc. Furthermore, they can be used in modern methods of automatic laying of dry fibers into preforms, which significantly reduces the labor cost of the manufacturing process.
  • 5.0K
  • 19 Jan 2022
Topic Review
Natural Emulsion Stabilizers
Natural emulsion stabilizers are polymers of amino acid, nucleic acid, carbohydrate, etc., which are derived from microorganisms, bacteria, and other organic materials. Plant and animal proteins are basic sources of natural emulsion stabilizers. Pea protein-maltodextrin and lentil protein feature entrapment capacity up to 88%, (1–10% concentrated), zein proteins feature 74–89% entrapment efficiency, soy proteins in various concentrations increase dissolution, retention, and stability to the emulsion and whey proteins, egg proteins, and proteins from all other animals are applicable in membrane formation and encapsulation to stabilize emulsion/nanoemulsion. In pharmaceutical industries, phospholipids, phosphatidyl choline (PC), phosphatidyl ethanol-amine (PE), and phosphatidyl glycerol (PG)-based stabilizers are very effective as emulsion stabilizers. Lecithin (a combination of phospholipids) is used in the cosmetics and food industries. Various factors such as temperature, pH, droplets size, etc. destabilize the emulsion. Therefore, the emulsion stabilizers are used to stabilize, preserve and safely deliver the formulated drugs, also as a preservative in food and stabilizer in cosmetic products. Natural emulsion stabilizers offer great advantages because they are naturally degradable, ecologically effective, non-toxic, easily available in nature, non-carcinogenic, and not harmful to health.
  • 8.5K
  • 19 Jan 2022
Topic Review
The Design of Ni-Based Single Crystal Superalloys
The most important performance characteristics of heat-resistant alloys (HRAs) are creep and fatigue resistance, which are very complex functions of chemical composition and microstructure. The microstructure of metal HRAs, among which the first place is occupied by Ni-based alloys, usually consists of two main phases: a solid solution based on the main element containing alloying elements (matrix), and a strengthening phase, which is usually used as intermetallides, carbides and silicides.
  • 1.8K
  • 17 Jan 2022
Topic Review
Metal (Mo, W, Ti) Carbides for Dry Reforming
Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Transition metal carbides (TMCs) can potentially replace traditional nickel catalysts due to their stability and activity in DR processes. 
  • 1.6K
  • 18 Jan 2022
Topic Review
Chromophoric Dendrimer-Based Materials
Dendrimers (from the Greek dendros → tree; meros → part) are macromolecules with well-defined three-dimensional and tree-like structures. Remarkably, this hyperbranched architecture is one of the most ubiquitous, prolific, and recognizable natural patterns observed in nature. 
  • 1.1K
  • 16 Jan 2022
Topic Review
Developing Edible Starch Film Used for Packaging Seasonings
Edible starch-based film was developed for packaging seasoning applied in instant noodles. The edible film can quickly dissolve into hot water so that the seasoning bag can mix in the soup of instant noodles during preparation.
  • 1.5K
  • 11 Jan 2022
Topic Review
Alginate Application in Drug Delivery
Alginates are generally used in the food, beverage, cosmetic, paper, textile printing, and pharmaceutical industries. They have been utilized as stabilizers, thickeners, emulsifiers, and hydration and gelling agents. The main use of alginate in the biomedical industry is mainly focused on hydrogels used in wound healing, drug delivery, and tissue regeneration. The broad range of applications is due to its biocompatibility, low toxicity and relatively low-cost consumption, and structural similarity to the extracellular matrices of living tissue.
  • 2.1K
  • 22 Dec 2021
Topic Review
CO2 Activation on Catalyst Surfaces
Utilizing CO2 as a sustainable carbon source to form valuable products requires activating it by active sites on catalyst surfaces. These active sites are usually in or below the nanometer scale. Some metals and metal oxides in this scale dimension can catalyze the CO2 transformation reactions. Herein, CO2 activation on metal-based catalyst surfaces and how their structures impact the activation process are highlighted.
  • 4.4K
  • 13 Dec 2021
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