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Zhong, J. Fire Retardant. Encyclopedia. Available online: https://encyclopedia.pub/entry/61976 (accessed on 12 November 2026).
Zhong J. Fire Retardant. Encyclopedia. Available at: https://encyclopedia.pub/entry/61976. Accessed November 12, 2026.
Zhong, Jack. "Fire Retardant" Encyclopedia, https://encyclopedia.pub/entry/61976 (accessed November 12, 2026).
Zhong, J. (2026, November 05). Fire Retardant. In Encyclopedia. https://encyclopedia.pub/entry/61976
Zhong, Jack. "Fire Retardant." Encyclopedia. Web. 05 November, 2026.

Fire Retardant

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A fire retardant is a substance that slows ignition or reduces the rate at which a polymer burns, without necessarily preventing combustion [1]. The action follows four chemical routes: a halogen or phosphorus species interrupts the radical chain of the gas-phase flame, a filler releases water or an inert gas on heating, a char-forming agent promotes a carbonaceous layer at the surface, and a diluent lowers the fuel fraction reaching the flame [1]. The char layer separates the condensed phase from the heat flux and from oxygen, so its continuity governs the residual performance [2]. Additives are described by the loading needed to reach a limiting oxygen index and a vertical burn rating, and by whether they are reactive or merely blended into the host polymer [3]. Bio-based additives act through intumescence or through phosphorus released on decomposition [3].

flame retardancy char formation limiting oxygen index intumescence vertical burn rating
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References

  1. Villamil Watson, D.A.; Schiraldi, D.A. Biomolecules as Flame Retardant Additives for Polymers: A Review. Polymers 2020, 12, 849. [CrossRef]
  2. Kianfar, M.; Ipakchi, H.; Mohajer, S.; Rasoulifard, M.H.; Seyed Dorraji, M.S.; Louaguef, D.B.; Azat, S.; Saeb, M.R.; Vahabi, H. Flame‐Retardant Self‐Healing Polymers: A Review. Journal of Polymer Science 2025, 63, 5291-5327. [CrossRef]
  3. Camino, G.; Costa, L.; Luda di Cortemiglia, M. Overview of fire retardant mechanisms. Polymer Degradation and Stability 1991, 33, 131-154. [CrossRef]
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Update Date: 06 Nov 2026
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