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Fire Retardant: History
Please note this is an old version of this entry, which may differ significantly from the current revision.
Contributor: Jack Zhong

A fire retardant is a substance that slows ignition or reduces the rate at which a polymer burns, without necessarily preventing combustion [1]. The action follows four chemical routes: a halogen or phosphorus species interrupts the radical chain of the gas-phase flame, a filler releases water or an inert gas on heating, a char-forming agent promotes a carbonaceous layer at the surface, and a diluent lowers the fuel fraction reaching the flame [1]. The char layer separates the condensed phase from the heat flux and from oxygen, so its continuity governs the residual performance [2]. Additives are described by the loading needed to reach a limiting oxygen index and a vertical burn rating, and by whether they are reactive or merely blended into the host polymer [3]. Bio-based additives act through intumescence or through phosphorus released on decomposition [3].

  • flame retardancy
  • char formation
  • limiting oxygen index
  • intumescence
  • vertical burn rating

References

  1. Villamil Watson, D.A.; Schiraldi, D.A.; Biomolecules as Flame Retardant Additives for Polymers: A Review. Polymers 2020, 12, 849, 10.3390/polym12040849.
  2. Kianfar, M.; Ipakchi, H.; Mohajer, S.; Rasoulifard, M.H.; Seyed Dorraji, M.S.; Louaguef, D.B.; Azat, S.; Saeb, M.R.; Vahabi, H.; Flame‐Retardant Self‐Healing Polymers: A Review. Journal of Polymer Science 2025, 63, 5291-5327, 10.1002/pol.20240489.
  3. Camino, G.; Costa, L.; Luda di Cortemiglia, M.; Overview of fire retardant mechanisms. Polymer Degradation and Stability 1991, 33, 131-154, 10.1016/0141-3910(91)90014-i.
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