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1 Helena Kang -- 170 2026-09-23 08:28:31

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Kang, H. Platinum Group Metal Catalysis. Encyclopedia. Available online: https://encyclopedia.pub/entry/60386 (accessed on 03 October 2026).
Kang H. Platinum Group Metal Catalysis. Encyclopedia. Available at: https://encyclopedia.pub/entry/60386. Accessed October 03, 2026.
Kang, Helena. "Platinum Group Metal Catalysis" Encyclopedia, https://encyclopedia.pub/entry/60386 (accessed October 03, 2026).
Kang, H. (2026, September 23). Platinum Group Metal Catalysis. In Encyclopedia. https://encyclopedia.pub/entry/60386
Kang, Helena. "Platinum Group Metal Catalysis." Encyclopedia. Web. 23 September, 2026.
Platinum Group Metal Catalysis
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Platinum group metal catalysis uses ruthenium, rhodium, palladium, osmium, iridium, or platinum as the regenerated catalytic center in a homogeneous or heterogeneous reaction. Molecular PGM catalysts operate through ligand-controlled organometallic steps such as oxidative addition, migratory insertion, β-hydride elimination, and reductive elimination. Heterogeneous PGM catalysts instead present metallic, oxidic, nanoparticle, single-atom, or supported sites at which reactants adsorb and undergo bond activation [1][2]. Accessible oxidation states, strong yet tunable substrate binding, and the ability to activate H–H, C–H, C–X, C=C, O–O, and related bonds are characteristic features of this catalyst family. The class is defined by the identity and turnover of the metal, not by a single reaction mechanism. It excludes stoichiometric use of PGM compounds and processes in which a PGM is only a support or spectator. PGM catalysis is narrower than noble-metal catalysis, which can also include gold and silver, and distinct from base-metal catalysis.

platinum group metal palladium catalysis oxidative addition C–H functionalization

References

  1. Anthony E. Hughes; Nawshad Haque; Stephen A. Northey; Sarbjit Giddey; Platinum Group Metals: A Review of Resources, Production and Usage with a Focus on Catalysts. Resources 2021, 10, 93. [CrossRef]
  2. Jan Krajczewski; Robert Ambroziak; Andrzej Kudelski; Formation and selected catalytic properties of ruthenium, rhodium, osmium and iridium nanoparticles. RSC Adv. 2022, 12, 2123-2144. [CrossRef]
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Subjects: Chemistry, Organic
Contributor MDPI registered users' name will be linked to their SciProfiles pages. To register with us, please refer to https://encyclopedia.pub/register : Helena Kang
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Update Date: 23 Sep 2026
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