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Platinum Group Metal Catalysis: History
Please note this is an old version of this entry, which may differ significantly from the current revision.
Subjects: Chemistry, Organic
Contributor: Helena Kang

Platinum group metal catalysis uses ruthenium, rhodium, palladium, osmium, iridium, or platinum as the regenerated catalytic center in a homogeneous or heterogeneous reaction. Molecular PGM catalysts operate through ligand-controlled organometallic steps such as oxidative addition, migratory insertion, β-hydride elimination, and reductive elimination. Heterogeneous PGM catalysts instead present metallic, oxidic, nanoparticle, single-atom, or supported sites at which reactants adsorb and undergo bond activation [1][2]. Accessible oxidation states, strong yet tunable substrate binding, and the ability to activate H–H, C–H, C–X, C=C, O–O, and related bonds are characteristic features of this catalyst family. The class is defined by the identity and turnover of the metal, not by a single reaction mechanism. It excludes stoichiometric use of PGM compounds and processes in which a PGM is only a support or spectator. PGM catalysis is narrower than noble-metal catalysis, which can also include gold and silver, and distinct from base-metal catalysis.

  • platinum group metal
  • palladium catalysis
  • oxidative addition
  • C–H functionalization

Synthesis and Catalytic Reactions • Organic Chemistry • Chemistry • Physical Sciences

References

  1. Anthony E. Hughes; Nawshad Haque; Stephen A. Northey; Sarbjit Giddey; Platinum Group Metals: A Review of Resources, Production and Usage with a Focus on Catalysts. Resources 2021, 10, 93, 10.3390/resources10090093.
  2. Jan Krajczewski; Robert Ambroziak; Andrzej Kudelski; Formation and selected catalytic properties of ruthenium, rhodium, osmium and iridium nanoparticles. RSC Adv. 2022, 12, 2123-2144, 10.1039/d1ra07470a.
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