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Stafilov, T.; Šajn, R.; Alijagić, J. Geographic Description of North Macedonia. Encyclopedia. Available online: https://encyclopedia.pub/entry/56512 (accessed on 23 April 2024).
Stafilov T, Šajn R, Alijagić J. Geographic Description of North Macedonia. Encyclopedia. Available at: https://encyclopedia.pub/entry/56512. Accessed April 23, 2024.
Stafilov, Trajče, Robert Šajn, Jasminka Alijagić. "Geographic Description of North Macedonia" Encyclopedia, https://encyclopedia.pub/entry/56512 (accessed April 23, 2024).
Stafilov, T., Šajn, R., & Alijagić, J. (2024, March 28). Geographic Description of North Macedonia. In Encyclopedia. https://encyclopedia.pub/entry/56512
Stafilov, Trajče, et al. "Geographic Description of North Macedonia." Encyclopedia. Web. 28 March, 2024.
Geographic Description of North Macedonia
Edit

North Macedonia is a landlocked country in the central part of the Balkan Peninsula between 40°50′ and 42°20′ north latitude and between 20°28′ and 23°05′ east longitude, with an area of about 25,700 km2.

chemical elements distribution pollution soil North Macedonia

1. Introduction

The impact of humans on the biosphere is extensive and complex and, in most cases, has led to irreversible changes. All human-induced changes disturb the natural balance of ecosystems as they have evolved over a long period. Therefore, in most cases, these changes lead to a degradation of the natural environment for humans. Although the human impact on the biosphere dates back to the Neolithic period, the problems of ecosystem degradation through pollution have intensified in the last few decades of the 20th century. Most of the chemical elements necessary for life on Earth are mainly supplied from the soil above the lithosphere. The content of elements in plants often correlates with their presence in the surrounding soils. Most of the chemical elements that are essential for human life are also essential for plants. However, the concentrations of most elements that can be harmful to humans are not toxic to plants, as they have adapted to such concentrations [1][2]. The consumption of energy and mineral resources leads to the contamination of the biosphere with potentially toxic elements (PTEs). Anthropogenic environmental changes, especially those associated with contamination, lead to environmental degradation. The most potentially hazardous PTEs for the biosphere are As, Cd, Cr, Cu, Hg, Mo, Ni, Pb, Se and Zn. However, elements, such as Ag, Au, Be, Mn, Sb, Sn, Tl, U and V, can be hazardous to the environment if they are released in excessive quantities [3][4][5].
Soil is crucial for the survival of humanity, which is closely linked to its productivity. Soil acts as a filtering, buffering, storage and transformation system and protects against the effects of heavy metal pollution in groundwater. Soil is the most important source of chemical elements for plants, both in the form of micronutrients and pollutants [2]. Due to geological and climatic influences, soils have very different properties. Soils have a unique structural feature that distinguishes them from pure earth materials and serves as the basis for their classification: a vertical sequence of layers formed by the combined action of percolating water and living organisms [1].
The problem of the destruction of ecosystems through pollution became increasingly acute towards the end of the 20th century. The rapid increase in PTE concentrations in the environment is usually accompanied by the development of utilisation technologies. Soils contain chemical elements of different origins: lithogenic elements, which originate directly from the lithosphere; geogenic elements, which are of lithogenic origin but whose concentration and distribution in the soil layers are altered by paedogenetic processes; or anthropogenic elements, which originate from direct or indirect anthropogenic activities. The behaviour of chemical elements in the soil and, thus, their bioavailability differ depending on their origin and soil conditions as well as their chemical and physical properties. Regardless of the chemical form of the anthropogenic elements in the soil, their availability to plants is significantly higher than that of elements of geogenic origin. In several regions of the world, soils are exposed to increasing mineral fertilisation, pesticide use, waste disposal and industrial pollution. All these human activities affect both chemical and physical soil properties and lead to changes in the behaviour of chemical elements in soils [1][6][7][8][9]. The behaviour of elements during weathering and paedogenetic processes, the basic soil-forming processes, is closely related to their geochemical properties. Most elements have a lithophilic character [10][11]. Paedogenetic processes occur simultaneously with weathering processes; usually, these different processes are closely related.
The content of chemical elements in soil materials from natural and contaminated sites shows great variability, both horizontally and vertically. The heterogeneity of soils, especially at the micro level, leads to considerable problems when taking representative soil samples. This affects the reproducibility and comparability of analytical data, which are very important for assessing the background content of chemical elements in soils. Although, today, there is no truly pristine state of PTEs in soils even in remote regions, some values of PTEs in “uncontaminated” soils are used as reference values for the assessment of soil contamination [2].
The terms contamination and soil pollution are used synonymously. Soil contaminated with PTEs is only considered polluted if a threshold concentration is exceeded, and biochemical and biological processes are adversely affected [12]. The main sources of inorganic substances are industrial activities, such as mining and smelting of metal-bearing ores, brick and pipe manufacturing, cement, ceramic and glass production, electricity generation, fossil fuel combustion, nuclear reactors, municipal waste incineration, agricultural practises, such as soil amendment by sewage sludge, manure, mineral fertilisers and pesticides, fumigation, traffic and urban pollution, cosmic particles and long-range transport of pollutants [2][3].
Soil has recently become the subject of numerous studies, some of which deal with large areas. For example, Salminen et al. [13] and De Vos et al. [14] produced the first Geochemical Atlas of Europe as part of the FOREGS (Forum of European Geological Surveys) Geochemical Baseline Programme, which contains data on 63 elements in about 800 topsoil and subsoil samples. In 2014, Chemistry of Europe’s Agricultural soils (in which North Macedonia participated) was published by Reimann and the GEMAS study group (Geochemical Mapping of Agricultural and Grazing Land Soil), which is based on the geochemical analysis of agricultural and grazing soils [15][16]. There are also numerous studies on soil pollution at the national or regional level [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55].
Regional soil contamination occurs mainly in industrial regions and in the centres of large settlements, where factories, traffic and municipal waste are located [1]. Due to the heterogeneity and constant change of urban areas, it is necessary to understand the natural distribution of PTEs and the methods by which they can be distinguished from man-made anomalies in nature. The natural background of the content of PTEs in soil is variable, which means that higher levels of some elements may be normal in one region but abnormal in another. However, in cases where industrial enterprises, particularly mining and smelting operations, are located close to cities, pollution may increase. Recently published works have shown that mining and smelting activities lead to enormous soil pollution [56][57][58][59][60][61][62][63][64][65][66][67][68][69][70][71][72][73][74][75] and that the most serious soil pollution is a consequence of Pb-Zn mining and smelting activities [64][67][76][77][78][79][80][81][82] as well as similar activities for copper, arsenic and antimony [42][51][52][53][54][55][65][70][71][72][73][74][75][79][80][81][82][83][84][85][86][87][88] or coal-fired power plants [89].
North Macedonia first participated in the UNECE ICP Vegetation Programme–Heavy Metals in European Mosses [90][91] in 2002 (survey 2000/2001) and again in 2005, 2010, 2013, 2015 and 2020, in which the atmospheric deposition of trace elements was investigated using samples of terrestrial mosses. The results of these studies in North Macedonia indicate a deterioration in air quality with regards to PTE pollution [92]. The main emission sources are metallurgical activities, power plants and mining. Therefore, additional studies were conducted in the areas with the highest PTE pollution of various environmental media.

2. Geographic Description of North Macedonia

North Macedonia is a landlocked country in the central part of the Balkan Peninsula between 40°50′ and 42°20′ north latitude and between 20°28′ and 23°05′ east longitude (Figure 1), with an area of about 25,700 km2. According to the 2022 census, North Macedonia has a total population of 1,830,000 (2022 census). North Macedonia is divided into eight statistical regions: Skopje, Pelagonia, Polog, Vardar, eastern, southeastern, northeastern and southwestern.
Figure 1. Topographic map of North Macedonia.
North Macedonia is geographically bounded by a central valley formed by the Vardar River and framed by mountain ranges, and the terrain is mostly rugged.
About two-thirds of the country’s territory is mountainous; they belong partly to the old Rodope Group in the eastern part and to the young Dinaric Group in the western part of the country. The eastern mountains are generally lower than 2000 m, while the Dinaric Group over 2500 m high, with Golem Korab, 2764 m, as the highest peak in North Macedonia.
Valleys and plains cut through the mountainous relief structures and cover about a third of the country. The most pronounced valleys are those along the Vardar River, including the Skopje Valley (1840 km2), while the largest plain in North Macedonia is the Pelagonian Plain in the southwest, which covers an area of about 4000 km2 at an average altitude of 600 m. North Macedonia also has scenic mountains, belonging to two different mountain ranges: the Šar Mountains (Dinaric Mountains) and the Osogovo–Belasica mountain chain (Rhodope Mountains) [28].
Due to the characteristic natural and geographical conditions, North Macedonia has two distinct climatic zones: a modified Mediterranean climate and a temperate continental climate. It also features two distinct seasons: cold, wet winters and dry, hot summers, associated with the transitional seasons of spring and autumn [93]. The complex relief structure and differences in altitude significantly alter the Mediterranean influence on the climate. The average annual temperature depends mainly on the altitude of the respective areas; the average annual variation can be up to 20 °C. In the mountain regions, the average annual temperatures are relatively low and range between 4.7 °C (1750 m) and 8.2 °C (1230 m). The highest average annual temperature of 14.5 °C is found in the lower reaches of the Vardar, which is influenced by the Aegean Sea.
The annual rainfall in North Macedonia is very unevenly distributed, with the lowest amounts, often less than 500 mm, falling in the central part of the country. Areas with higher rainfall are Skopje, Kumanovo and the Kočani-Radoviš valleys, with an average rainfall of 500–550 mm. The highest amounts of precipitation were found in the Debar Valley (870 mm) and in the mountainous regions of Bistra and Šar Mountains with over 1000 mm.
North Macedonia is rich in minerals, with deposits of various metals (Cr, Cu, Fe, Pb, Zn, Ni and Mn). Based on these mineral deposits, three mines for lead–zinc ore, one for copper ore and mines for iron, nickel and chrome ore have been opened in the past. In addition, smelters have been built for the extraction of various metals: iron and steel in Skopje, ferronickel in Kavadarci, ferrochromium and ferrosilicon in Jegunovce, and lead and zinc in Veles. The country also has gypsum, limestone, marble, lignite and granite mines.
Based on previous studies, it has been established that North Macedonia has a complex geology, comprising many geological formations of different ages and geological composition, which has led to a great variety of soil types. From a tectonic point of view, North Macedonia comprises six major tectonic units (Figure 2A), including the Vardar Zone (VZ) (Figure 2, IV) in the central region, the Pelagonian Massif (PM) (Figure 2, III), West-Macedonian Zone (WMZ) (Figure 2, II), a small part of the Cukali-Krasta Zone (CKZ) (Figure 2, I) in the west, the Serbo-Macedonian Massif (SMM) (Figure 2, V) and the Kraishtide Zone (KZ) (Figure 2, VI) in the east of the country [28][94][95][96][97].
Figure 2. (A) Simplified geological map of North Macedonia. Tectonic units: I—Cukali-Krasta zone (CKZ), II—West-Macedonian zone (WMZ), III—Pelagonian massif (PM), IV—Vardar zone (VZ), V—Serbo-Macedonian massif (SMM), VI—Kraishtide zone (KZ) [28]; (B) generalized pedological map [28].
The Cukali-Krasta Zone (CKZ) is mainly distributed in Albania, with a small part in North Macedonia. This zone consists of Upper Cretaceous, conglomerates–sandstones, claystones and limestones with olistostromes and rudist limestones. Evaporites and minor Paleogene sediments can be found in this zone. The West-Macedonian Zone (WMZ) has an internal tectonic structure that was mainly formed during the Hercynian and Laramide compressions. The West-Macedonian Zone is lithologically composed of low-grade metamorphic rocks and anchi-metamorphic Paleozoic rocks and magmatites, Triassic and Jurassic sediments and magmatites, and Tertiary sediments. The Vardar Zone separates the Pelagonian Massif and the WMZ in the west from the Serbo-Macedonian massif in the east. It is an old structure that dates back to the Lower Palaeozoic. The Serbo-Macedonian Massif (SMM) is an accretionary wedge on the eastern edge of the Eurasian plate, which lies in the Carpatho-Balkanides and was pulled down over the Vardar Zone. The main mass consists of a complex of the lower or overthrusted Proterozoic and the Upper Riphean-Cambrian. The Kraishtide Zone (KZ) represents the southernmost segment of the Carpatho-Balkanides, which are part of the Serbo-Macedonian Massif. The largest part of the zone is located in Bulgaria and is characterised by a particular type of Alpine development.
The territory of North Macedonia is covered by the following 15 main geological units: Quaternary alluvium, Quaternary deluvium/proluvium, Neogene clastites, Paleogene clastites, Mesozoic clastites, Mesozoic carbonates, Paleozoic carbonates, Proterozoic carbonates, Paleozoic metamorphic rocks, metamorphic rocks from the Pelagonian Massif, metamorphic rocks from the Serbo-Macedonian Massif, Neogene, Paleogene, Mesozoic and Paleozoic magmatic rocks.
North Macedonia has a very heterogeneous land cover, consisting of many soil types and lower taxonomic units. According to the pedological map of the country [98][99], the following soil types are predominant: lithosol, lithosol (limestone/dolomite), regosol, colluvial soil, rendzina, ranker, vertisol, cambisol, cromic cambisol, cambisol (limestone/dolomite), fluvisol, hydromorphic soil and anthrosol (Figure 2B).

References

  1. Kabata-Pendias, A. Trace Elements in Soils and Plants, 4th ed.; CRC Press: Boca Raton, FL, USA, 2010; ISBN 9780429192036.
  2. Kabata-Pendias, A.; Mukherjee, A.B. Trace Elements from Soil to Human; Springer: Berlin/Heidelberg, Germany, 2007; ISBN 978-3-540-32713-4.
  3. Bowen, H.J.M. Environmental Chemistry of the Elements; Academic Press: New York, NY, USA, 1979.
  4. Nieder, R.; Benbi, D.K.; Reichl, F.X. Role of Potentially Toxic Elements in Soils. In Soil Components and Human Health; Springer: Dordrecht, The Netherlands, 2018; pp. 375–450.
  5. Mehmood, S.; Wang, X.; Ahmed, W.; Imtiaz, M.; Ditta, A.; Rizwan, M.; Irshad, S.; Bashir, S.; Saeed, Q.; Mustafa, A.; et al. Removal Mechanisms of Slag against Potentially Toxic Elements in Soil and Plants for Sustainable Agriculture Development: A Critical Review. Sustainability 2021, 13, 5255.
  6. Mirsal, I.A. Soil Pollution: Origin, Monitoring & Remediation, 2nd ed.; Springer: Berlin/Heidelberg, Germany, 2008.
  7. Förstner, U.; Salomons, W.; Mader, P. Heavy Metals—Problems and Solutions; Förstner, U., Salomons, W., Mader, P., Eds.; Springer: Berlin/Heidelberg, Germany, 1995; ISBN 978-3-642-79318-9.
  8. Desaules, A.; Ammann, S.; Schwab, P. Advances in Long-term Soil-pollution Monitoring of Switzerland. J. Plant Nutr. Soil Sci. 2010, 173, 525–535.
  9. Wei, B.; Yang, L. A Review of Heavy Metal Contaminations in Urban Soils, Urban Road Dusts and Agricultural Soils from China. Microchem. J. 2010, 94, 99–107.
  10. Adriano, D.C. Trace Elements in Terrestrial Environments; Springer: New York, NY, USA, 2001; ISBN 978-1-4684-9505-8.
  11. Goldhaber, M.; Banwart, S.A. Soil Formation. In Soil Carbon Science, Manegement and Policy for Multiple Benefits; Banwart, S.A., Noellemeyer, E., Milne, E., Eds.; CAB International: Wallingford, UK, 2014; pp. 82–97.
  12. Knox, A.S.; Erdinger, A.P.; Adriano, D.C.; Kolka, R.K.; Kaplan, D.I. Sources and Practices Contributing to Soil Contamination. In Bioremediation of Contaminated Soils; Adriano, D.C., Bollag, J.M., Frenkerberger, W.T., Sims, R.C., Eds.; American Society of Agronomy: Madison, WI, USA, 1999; pp. 53–87. ISBN 9780891181378.
  13. Salminen, R.; Tarvainen, T.; Demetriades, A.; Duris, M.; Fordyce, F.M.; Gregorauskiene, V.; Kahelin, H.; Kivisilla, J.; Klaver, G.; Klin, H.; et al. Geochemical Atlas of Europe. Background Information, Methodology and Maps; Geological Survey of Finland: Espoo, Finland, 2005.
  14. De Vos, W.; Tarvainen, T.; Salminen, R.; Reeder, S.; De Vivo, B.; Demetriades, A.; Pirc, S.; Batista, M.J.; Marsina, K.; Ottesen, R.T.; et al. Geochemical Atlas of Europe. Part 2, Interpretation of Geochemical Maps, Additional Tables, Figures, Maps, and Related Publications; Geological Survey of Finland: Espoo, Finland, 2006; ISBN 951-690-956-6.
  15. Reimann, C.; Birke, M.; Demetriades, A.; Filzmoser, P.; O’Connor, P. Chemistry of Europe’s Agricultural Soils—Part A: Methodology and Interpretation of the GEMAS Data Set; Geologisches Jahrbuch Reihe B, Band B 103; Schweizerbart Science Publishers: Stuttgart, Germany, 2014; ISBN 978-3-510-96846-6.
  16. Reimann, C.; Birke, M.; Demetriades, A.; Filzmoser, P.; O’Connor, P.; Akinfiev, G.; Albanese, S.; Amashukeli, Y.; Andersson, M.; Arnoldussen, A.; et al. Chemistry of Europe’s Agricultural Soils—Part B: General Background Information and Further Analysis of the GEMAS Data Set; Geologisches Jahrbuch Reihe B, Band B 103; Schweizerbart Science Publishers: Stuttgart, Germany, 2014; ISBN 978-3-510-96847-3.
  17. Barzi, F.; Naidu, R.; McLaughlin, M.J. Contaminants and the Australian Soil Environment. In Contaminants and the Soil Environment in the Australasia-Pacific Region, Proceedings of the First Australasia-Pacific Conference on Contaminants and Soil Environment in the Australasia-Pacific Region, Adelaide, Australia, 18–23 February 1996; Naidu, R., Kookana, R.S., Oliver, D.P., Rogers, S., McLaughlin, M.J., Eds.; Springer: Dordrecht, The Netherlands, 1996; pp. 451–484.
  18. Salminen, R.; Chekushin, V.; Tenhola, M.; Bogatyrev, I.; Glavatskikh, S.P.; Fedotova, E.; Gregorauskienė, V.; Kashulina, G.; Niskavaara, H.; Polischuok, A.; et al. Geochemical Atlas of the Eastern Barents Region; Elsevier: Amsterdam, The Netherlands, 2004; ISBN 0-444-51815-0.
  19. Bretzel, F.; Calderisi, M. Metal Contamination in Urban Soils of Coastal Tuscany (Italy). Environ. Monit. Assess. 2006, 118, 319–335.
  20. Davidson, C.M.; Urquhart, G.J.; Ajmone-Marsan, F.; Biasioli, M.; da Costa Duarte, A.; Díaz-Barrientos, E.; Grčman, H.; Hossack, I.; Hursthouse, A.S.; Madrid, L.; et al. Fractionation of Potentially Toxic Elements in Urban Soils from Five European Cities by Means of a Harmonised Sequential Extraction Procedure. Anal. Chim. Acta 2006, 565, 63–72.
  21. Micó, C.; Recatalá, L.; Peris, M.; Sánchez, J. Assessing Heavy Metal Sources in Agricultural Soils of an European Mediterranean Area by Multivariate Analysis. Chemosphere 2006, 65, 863–872.
  22. Halamić, J.; Miko, S. Geochemical Atlas of the Republic of Croatia; Croatian Geological Survey: Zagreb, Croatia, 2009; ISBN 978-953-6907-18-2.
  23. Reimann, C.; Äyräs, M.; Chekushin, V.A.; Bogatyrev, I.V.; Boyd, R.; de Caritat, P.; Dutter, R.; Finne, T.E.; Halleraker, J.H.; Jæger, Ø.; et al. Environmental Geochemical Atlas of the Central Barents Region; Reimann, C., Äyräs, M., Chekushin, V., Eds.; Schweizerbart Science Publishers: Stuttgart, Germany, 2010; ISBN 9783510652631.
  24. Birch, G.F.; Vanderhayden, M.; Olmos, M. The Nature and Distribution of Metals in Soils of the Sydney Estuary Catchment, Australia. Water Air Soil Pollut. 2011, 216, 581–604.
  25. Braga Bueno Guerra, M.; Schaefer, C.E.G.R.; de Freitas Rosa, P.; Simas, F.N.B.; Pereira, T.T.C.; Rodrigues Pereira-Filho, E. Heavy Metals Contamination in Century-Old Manmade Technosols of Hope Bay, Antarctic Peninsula. Water Air Soil Pollut. 2011, 222, 91–102.
  26. Cicchella, D.; Giaccio, L.; Lima, A.; Albanese, S.; Cosenza, A.; Civitillo, D.; De Vivo, B. Assessment of the Topsoil Heavy Metals Pollution in the Sarno River Basin, South Italy. Environ. Earth Sci. 2014, 71, 5129–5143.
  27. Freije, A.M. Heavy Metal, Trace Element and Petroleum Hydrocarbon Pollution in the Arabian Gulf: Review. J. Assoc. Arab. Univ. Basic Appl. Sci. 2015, 17, 90–100.
  28. Stafilov, T.; Šajn, R. Geochemical Atlas of the Republic of Macedonia; Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University in Skopje: Skopje, North Macedonia, 2016; ISBN 978-608-4762-04-1.
  29. Šajn, R.; Ristović, I.; Čeplak, B. Mining and Metallurgical Waste as Potential Secondary Sources of Metals—A Case Study for the West Balkan Region. Minerals 2022, 12, 547.
  30. Chen, T.-B.; Zheng, Y.-M.; Lei, M.; Huang, Z.-C.; Wu, H.-T.; Chen, H.; Fan, K.-K.; Yu, K.; Wu, X.; Tian, Q.-Z. Assessment of Heavy Metal Pollution in Surface Soils of Urban Parks in Beijing, China. Chemosphere 2005, 60, 542–551.
  31. Wang, X.S.; Qin, Y.; Sang, S.X. Accumulation and Sources of Heavy Metals in Urban Topsoils: A Case Study from the City of Xuzhou, China. Environ. Geol. 2005, 48, 101–107.
  32. Diawara, M.M.; Litt, J.S.; Unis, D.; Alfonso, N.; Martinez, L.; Crock, J.G.; Smith, D.B.; Carsella, J. Arsenic, Cadmium, Lead, and Mercury in Surface Soils, Pueblo, Colorado: Implications for Population Health Risk. Environ. Geochem. Health 2006, 28, 297–315.
  33. de Moura, M.C.S.; Lopes, A.N.C.; Moita, G.C.; Moita Neto, J.M. Estudo Multivariado de Solos Urbanos Da Cidade de Teresina. Quím. Nova 2006, 29, 429–435.
  34. Crnković, D.; Ristić, M.; Antonović, D. Distribution of Heavy Metals and Arsenic in Soils of Belgrade (Serbia and Montenegro). Soil Sediment Contam. Int. J. 2006, 15, 581–589.
  35. Kaur, R.; Rani, R. Spatial Characterization and Prioritization of Heavy Metal Contaminated Soil-Water Resources in Peri-Urban Areas of National Capital Territory (NCT), Delhi. Environ. Monit. Assess. 2006, 123, 233–247.
  36. Figueiredo, A.M.G.; Nogueira, C.A.; Saiki, M.; Milian, F.M.; Domingos, M. Assessment of Atmospheric Metallic Pollution in the Metropolitan Region of São Paulo, Brazil, Employing Tillandsia usneoides L. as Biomonitor. Environ. Pollut. 2007, 145, 279–292.
  37. Bakirdere, S.; Yaman, M. Determination of Lead, Cadmium and Copper in Roadside Soil and Plants in Elazig, Turkey. Environ. Monit. Assess. 2007, 136, 401–410.
  38. Faiz, Y.; Tufail, M.; Javed, M.T.; Chaudhry, M.M. Naila-Siddique Road Dust Pollution of Cd, Cu, Ni, Pb and Zn along Islamabad Expressway, Pakistan. Microchem. J. 2009, 92, 186–192.
  39. Kadi, M.W. “Soil Pollution Hazardous to Environment”: A Case Study on the Chemical Composition and Correlation to Automobile Traffic of the Roadside Soil of Jeddah City, Saudi Arabia. J. Hazard. Mater. 2009, 168, 1280–1283.
  40. Morton-Bermea, O.; Hernández-Álvarez, E.; González-Hernández, G.; Romero, F.; Lozano, R.; Beramendi-Orosco, L.E. Assessment of Heavy Metal Pollution in Urban Topsoils from the Metropolitan Area of Mexico City. J. Geochem. Explor. 2009, 101, 218–224.
  41. Plyaskina, O.V.; Ladonin, D.V. Heavy Metal Pollution of Urban Soils. Eurasian Soil Sci. 2009, 42, 816–823.
  42. Ajmone-Marsan, F.; Biasioli, M. Trace Elements in Soils of Urban Areas. Water Air Soil Pollut. 2010, 213, 121–143.
  43. Galindo, N.; Varea, M.; Gil-Moltó, J.; Yubero, E.; Nicolás, J. The Influence of Meteorology on Particulate Matter Concentrations at an Urban Mediterranean Location. Water Air Soil Pollut. 2011, 215, 365–372.
  44. Meena, N.K.; Maiti, S.; Shrivastava, A. Discrimination between Anthropogenic (Pollution) and Lithogenic Magnetic Fraction in Urban Soils (Delhi, India) Using Environmental Magnetism. J. Appl. Geophy. 2011, 73, 121–129.
  45. Davis, B.S.; Birch, G.F. Spatial Distribution of Bulk Atmospheric Deposition of Heavy Metals in Metropolitan Sydney, Australia. Water Air Soil Pollut. 2011, 214, 147–162.
  46. Papastergios, G.; Filippidis, A.; Fernandez-Turiel, J.-L.; Gimeno, D.; Sikalidis, C. Surface Soil Geochemistry for Environmental Assessment in Kavala Area, Northern Greece. Water Air Soil Pollut. 2011, 216, 141–152.
  47. Olawoyin, R.; Oyewole, S.A.; Grayson, R.L. Potential Risk Effect from Elevated Levels of Soil Heavy Metals on Human Health in the Niger Delta. Ecotoxicol. Environ. Saf. 2012, 85, 120–130.
  48. Massas, I.; Kalivas, D.; Ehaliotis, C.; Gasparatos, D. Total and Available Heavy Metal Concentrations in Soils of the Thriassio Plain (Greece) and Assessment of Soil Pollution Indexes. Environ. Monit. Assess. 2013, 185, 6751–6766.
  49. Taghipour, H.; Mosaferi, M.; Armanfar, F.; Gaemmagami, S.J. Heavy Metals Pollution in the Soils of Suburban Areas in Big Cities: A Case Study. Int. J. Environ. Sci. Technol. 2013, 10, 243–250.
  50. Chabukdhara, M.; Nema, A.K. Heavy Metals Assessment in Urban Soil around Industrial Clusters in Ghaziabad, India: Probabilistic Health Risk Approach. Ecotoxicol. Environ. Saf. 2013, 87, 57–64.
  51. Hu, Y.; Liu, X.; Bai, J.; Shih, K.; Zeng, E.Y.; Cheng, H. Assessing Heavy Metal Pollution in the Surface Soils of a Region That Had Undergone Three Decades of Intense Industrialization and Urbanization. Environ. Sci. Pollut. Res. 2013, 20, 6150–6159.
  52. Šorša, A.; Halamić, J. Geochemical Atlas of Sisak; Croatian Geological Survey: Zagreb, Croatia, 2014.
  53. Argyraki, A.; Kelepertzis, E. Urban Soil Geochemistry in Athens, Greece: The Importance of Local Geology in Controlling the Distribution of Potentially Harmful Trace Elements. Sci. Total Environ. 2014, 482–483, 366–377.
  54. Czarnecki, S.; Düring, R.-A. Influence of Long-Term Mineral Fertilization on Metal Contents and Properties of Soil Samples Taken from Different Locations in Hesse, Germany. SOIL 2015, 1, 23–33.
  55. Karim, Z.; Qureshi, B.A.; Mumtaz, M. Geochemical Baseline Determination and Pollution Assessment of Heavy Metals in Urban Soils of Karachi, Pakistan. Ecol. Indic. 2015, 48, 358–364.
  56. Lourenço, R.W.; Landim, P.M.B.; Rosa, A.H.; Roveda, J.A.F.; Martins, A.C.G.; Fraceto, L.F. Mapping Soil Pollution by Spatial Analysis and Fuzzy Classification. Environ. Earth Sci. 2010, 60, 495–504.
  57. Stafilov, T.; Šajn, R.; Pančevski, Z.; Boev, B.; Frontasyeva, M.V.; Strelkova, L.P. Heavy Metal Contamination of Topsoils around a Lead and Zinc Smelter in the Republic of Macedonia. J. Hazard. Mater. 2010, 175, 896–914.
  58. Escarré, J.; Lefèbvre, C.; Raboyeau, S.; Dossantos, A.; Gruber, W.; Cleyet Marel, J.C.; Frérot, H.; Noret, N.; Mahieu, S.; Collin, C.; et al. Heavy Metal Concentration Survey in Soils and Plants of the Les Malines Mining District (Southern France): Implications for Soil Restoration. Water Air Soil Pollut. 2011, 216, 485–504.
  59. Lavazzo, P.; Ducci, D.; Adamo, P.; Trifuoggi, M.; Migliozzi, A.; Boni, M. Impact of Past Mining Activity on the Quality of Water and Soil in the High Moulouya Valley (Morocco). Water Air Soil Pollut. 2012, 223, 573–589.
  60. D’Emilio, M.; Caggiano, R.; Macchiato, M.; Ragosta, M.; Sabia, S. Soil Heavy Metal Contamination in an Industrial Area: Analysis of the Data Collected during a Decade. Environ. Monit. Assess. 2013, 185, 5951–5964.
  61. Li, Z.; Ma, Z.; van der Kuijp, T.J.; Yuan, Z.; Huang, L. A Review of Soil Heavy Metal Pollution from Mines in China: Pollution and Health Risk Assessment. Sci. Total Environ. 2014, 468–469, 843–853.
  62. Modis, K.; Vatalis, K.I. Assessing the Risk of Soil Pollution around an Industrialized Mining Region Using a Geostatistical Approach. Soil Sediment Contam. Int. J. 2014, 23, 63–75.
  63. Popov, S.I.; Stafilov, T.; Šajn, R.; Tănăselia, C. Distribution of Trace Elements in Sediment and Soil from River Vardar Basin, Macedonia/Greece. J. Environ. Sci. Health Part A 2016, 51, 1–14.
  64. Balabanova, B.; Stafilov, T.; Šajn, R. Enchasing Anthropogenic Element Trackers for Evidence of Long-Term Atmospheric Depositions in Mine Environs. J. Environ. Sci. Health Part A Toxic/Hazard. Subst. Environ. Eng. 2019, 54, 988–998.
  65. Tomovski, D.; Bačeva Andonovska, K.; Šajn, R.; Karadjov, M.; Stafilov, T. Distribution of Chemical Elements in Sediments and Alluvial Soil from the Crna Reka River Basin. Geol. Maced. 2019, 33, 125–145.
  66. Vasilevska, S.; Stafilov, T.; Šajn, R. Distribution of Trace Elements in Sediments and Soil from Crn Drim River Basin, Republic of Macedonia. SN Appl. Sci. 2019, 1, 555.
  67. Šajn, R.; Stafilov, T.; Balabanova, B.; Alijagić, J. Multi-Scale Application of Advanced ANN-MLP Model for Increasing the Large-Scale Improvement of Digital Data Visualisation Due to Anomalous Lithogenic and Anthropogenic Elements Distribution. Minerals 2022, 12, 174.
  68. Stafilov, T.; Šajn, R.; Blaževska, R.; Tănăselia, C. Assessment of Natural and Anthropogenic Factors on the Distribution of Chemical Elements in Soil from the Skopje Region, North Macedonia. J. Environ. Sci. Health Part A 2022, 57, 357–375.
  69. Steiner, T.M.C.; Bertrandsson Erlandsson, V.; Šajn, R.; Melcher, F. Preliminary Chemical and Mineralogical Characterization of Tailings from Base Metal Sulfide Deposits in Serbia and North Macedonia. Geol. Croat. 2022, 75, 291–302.
  70. Douay, F.; Pruvot, C.; Roussel, H.; Ciesielski, H.; Fourrier, H.; Proix, N.; Waterlot, C. Contamination of Urban Soils in an Area of Northern France Polluted by Dust Emissions of Two Smelters. Water Air Soil Pollut. 2008, 188, 247–260.
  71. Dragović, S.; Mihailović, N.; Gajić, B. Heavy Metals in Soils: Distribution, Relationship with Soil Characteristics and Radionuclides and Multivariate Assessment of Contamination Sources. Chemosphere 2008, 72, 491–495.
  72. Liao, G.; Liao, D.; Li, Q. Heavy Metals Contamination Characteristics in Soil of Different Mining Activity Zones. Trans. Nonferrous Met. Soc. China 2008, 18, 207–211.
  73. Jiménez-Cárceles, F.J.; Álvarez-Rogel, J.; Conesa Alcaraz, H.M. Trace Element Concentrations in Saltmarsh Soils Strongly Affected by Wastes from Metal Sulphide Mining Areas. Water Air Soil Pollut. 2008, 188, 283–295.
  74. Kasassi, A.; Rakimbei, P.; Karagiannidis, A.; Zabaniotou, A.; Tsiouvaras, K.; Nastis, A.; Tzafeiropoulou, K. Soil Contamination by Heavy Metals: Measurements from a Closed Unlined Landfill. Bioresour. Technol. 2008, 99, 8578–8584.
  75. Fernández-Caliani, J.C.; Barba-Brioso, C.; González, I.; Galán, E. Heavy Metal Pollution in Soils Around the Abandoned Mine Sites of the Iberian Pyrite Belt (Southwest Spain). Water Air Soil Pollut. 2009, 200, 211–226.
  76. Chrastný, V.; Vaněk, A.; Teper, L.; Cabala, J.; Procházka, J.; Pechar, L.; Drahota, P.; Penížek, V.; Komárek, M.; Novák, M. Geochemical Position of Pb, Zn and Cd in Soils near the Olkusz Mine/Smelter, South Poland: Effects of Land Use, Type of Contamination and Distance from Pollution Source. Environ. Monit. Assess. 2012, 184, 2517–2536.
  77. Zawadzki, J.; Fabijańczyk, P. Geostatistical Evaluation of Lead and Zinc Concentration in Soils of an Old Mining Area with Complex Land Management. Int. J. Environ. Sci. Technol. 2013, 10, 729–742.
  78. Jeftimova, M.; Stafilov, T.; Šajn, R.; Bačeva Andonovska, K.; Karadjova, I. Spatial Distribution of Chemical Elements in Soil Samples in the Veles Region, Republic of Macedonia. Geol. Maced. 2016, 30, 103–114.
  79. Kalavrouziotis, I.K.; Koukoulakis, P.H. Soil Pollution under the Effect of Treated Municipal Wastewater. Environ. Monit. Assess. 2012, 184, 6297–6305.
  80. Khalil, A.; Hanich, L.; Bannari, A.; Zouhri, L.; Pourret, O.; Hakkou, R. Assessment of Soil Contamination around an Abandoned Mine in a Semi-Arid Environment Using Geochemistry and Geostatistics: Pre-Work of Geochemical Process Modeling with Numerical Models. J. Geochem. Explor. 2013, 125, 117–129.
  81. Cabala, J.; Zogala, B.; Dubiel, R. Geochemical and Geophysical Study of Historical Zn-Pb Ore Processing Waste Dump Areas (Southern Poland). Pol. J. Environ. Study 2008, 17, 693–700.
  82. Rodríguez, L.; Ruiz, E.; Alonso-Azcárate, J.; Rincón, J. Heavy Metal Distribution and Chemical Speciation in Tailings and Soils around a Pb–Zn Mine in Spain. J. Environ. Manag. 2009, 90, 1106–1116.
  83. Nikolic, D.; Milosevic, N.; Zivkovic, Z.; Mihajlovic, I.; Kovacevic, R.; Petrovic, N. Multi-Criteria Analysis of Soil Pollution by Heavy Metals in the Vicinity of the Copper Smelting Plant in Bor (Serbia). J. Serbian Chem. Soc. 2011, 76, 625–641.
  84. Everhart, J.L.; McNear, D.; Peltier, E.; van der Lelie, D.; Chaney, R.L.; Sparks, D.L. Assessing Nickel Bioavailability in Smelter-Contaminated Soils. Sci. Total Environ. 2006, 367, 732–744.
  85. Stafilov, T.; Šajn, R.; Boev, B.; Cvetković, J.; Mukaetov, D.; Andreevski, M.; Lepitkova, S. Distribution of Some Elements in Surface Soil over the Kavadarci Region, Republic of Macedonia. Environ. Earth Sci. 2010, 61, 1515–1530.
  86. Wilson, S.C.; Lockwood, P.V.; Ashley, P.M.; Tighe, M. The Chemistry and Behaviour of Antimony in the Soil Environment with Comparisons to Arsenic: A Critical Review. Environ. Pollut. 2010, 158, 1169–1181.
  87. Bačeva, K.; Stafilov, T.; Šajn, R.; Tănăselia, C.; Makreski, P. Distribution of Chemical Elements in Soils and Stream Sediments in the Area of Abandoned Sb–As–Tl Allchar Mine, Republic of Macedonia. Environ. Res. 2014, 133, 77–89.
  88. Bačvarovski, D.; Šajn, R.; Stafilov, T. Distribution of Chemical Elements in Sediments and Alluvium Soils from the Pčinja River Basin, North Macedonia. Geol. Maced. 2021, 35, 95–113.
  89. Okedeyi, O.O.; Dube, S.; Awofolu, O.R.; Nindi, M.M. Assessing the Enrichment of Heavy Metals in Surface Soil and Plant (Digitaria Eriantha) around Coal-Fired Power Plants in South Africa. Environ. Sci. Pollut. Res. 2014, 21, 4686–4696.
  90. Harmens, H.; Ilyin, I.; Mills, G.; Aboal, J.R.; Alber, R.; Blum, O.; Coşkun, M.; De Temmerman, L.; Fernández, J.Á.; Figueira, R.; et al. Country-Specific Correlations across Europe between Modelled Atmospheric Cadmium and Lead Deposition and Concentrations in Mosses. Environ. Pollut. 2012, 166, 1–9.
  91. Harmens, H.; Norris, D.A.; Sharps, K.; Mills, G.; Alber, R.; Aleksiayenak, Y.; Blum, O.; Cucu-Man, S.-M.; Dam, M.; De Temmerman, L.; et al. Heavy Metal and Nitrogen Concentrations in Mosses Are Declining across Europe Whilst Some “Hotspots” Remain in 2010. Environ. Pollut. 2015, 200, 93–104.
  92. Stafilov, T.; Šajn, R.; Barandovski, L.; Andonovska, K.B.; Malinovska, S. Moss Biomonitoring of Atmospheric Deposition Study of Minor and Trace Elements in Macedonia. Air Qual. Atmos. Health 2018, 11, 137–152.
  93. Lazarevski, A. Climate in Macedonia; Kultura: Skopje, North Macedonia, 1993.
  94. Pendžerkovski, J.; Hadži-Mitrova, S. Geological Map of SR Macedonia 1:200,000 (Map and Interpreter); Professional Fund of the Geological Survey of Macedonia: Skopje, North Macedonia, 1977.
  95. Dumurdzanov, N.; Serafimovski, T.; Burchfield, B.C. Evolution of the Neogene-Pleistocene Basins of Macedonia; Geological Society of America Digital map and Chart Series 1; Geological Society of America: Boulder, CO, USA, 2004; Volume 1, pp. 1–20.
  96. Dumurdzanov, N.; Serafimovski, T.; Burchfiel, B.C. Cenozoic Tectonics of Macedonia and Its Relation to the South Balkan Extensional Regime. Geosphere 2005, 1, 1–20.
  97. Arsovski, M. Tectonics of Macedonia; Faculty of Mining and Geology: Štip, North Macedonia, 1997.
  98. Filipovski, G. Soil Maps of the Republic of Macedonia. Contrib. Sect. Nat. Math. Biotech. Sci. 2017, 37, 55–68.
  99. Aksoy, E.; Arsov, S.; Mincev, I.; Fang, C. Agro-Ecological Atlas of the Republic of North Macedonia; FAO: Rome, Italy, 2020; ISBN 978-92-5-132122-5.
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