Insights into Si-Si and Si-H Bond
  • View Times: 117
  • |
  • Release Date: 2023-04-03
  • hydrosilane
  • disilane
  • oxidative addition
  • silicon
  • catalysis
  • ligand design
Video Introduction

The research on silicon chemistry have increased over the years due to the great importance of silyl compounds and their applications in industry, in academy and materials science fields. The silicon-silicon and the silicon-hydrogen bonds can be activated by transition and other p-block metals, being the most important pathways for obtaining molecular entities that contain, witihin their structures, silane motifs. Although the chemistry of Si-H bond activation is under continue development, Si-Si bonds are poorly characterized and less used and thus, disilanes represent good starting precursors because of their stability towards ambient conditions. 

The present video briefly describes the physicochemical properties of Si-H and Si-Si bonds, some trends and finally highlighting their impact on the synthesis of metal complexes. [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20]

References
  1. Chem. Commun. (London) 1966, 19, 700-701, 10.1039/C19660000700.
  2. J. Am. Chem. Soc. 1975, 97, 931-932, 10.1021/ja00837a061
  3. J. Organomet. Chem. 1993, 445, 19-28, 10.1016/0022-328X(93)80181-A
  4. J. Am. Chem. Soc. 1958, 80, 608-611, 10.1021/ja01536a025
  5. J. Am. Chem. Soc. 1959, 81, 5320-5322, 10.1021/ja01529a019
  6. J. Organomet. Chem. 1994, 473, 29-34, 10.1016/0022-328X(94)80102-9
  7. Dalton Trans. 2010, 39, 2062-2069, 10.1039/B920846A
  8. Chem. Rev. 2011, 111, 863-1071, 10.1021/cr900359c
  9. Inorg. Chem. 2009, 48, 1588–1598, 10.1021/ic8019777
  10. J. Am. Chem. Soc. 1987, 109, 5267–5268, 10.1021/ja00251a035
  11. J. Molec. Struct. 1973, 18, 463-469, 10.1016/0022-2860(73)85097-5
  12. J. Organomet. Chem. 1968, 11, 423-427, 10.1016/0022-328X(68)80066-X
  13. Russ. Chem. Bull. 1981, 30, 1552–1554, 10.1007/BF00952214
  14. J. Am. Chem. Soc. 1992, 114, 5754–5758, 10.1021/ja00040a041
  15. J. Organomet. Chem. 1998, 551, 81-92, 10.1016/S0022-328X(97)00433-6
  16.   J. Am. Chem. Soc. 2000, 122, 11511–11512, 10.1021/ja993279w
  17. J. Am. Chem. Soc. 2001, 123, 10526–10534, 10.1021/ja011472w
  18. J. Am. Chem. Soc. 1972, 94, 9263–9264, 10.1021/ja00781a066
  19. J. Organomet. Chem. 1983, 259, 337-343, 0.1016/0022-328X(83)87184-8
  20. Organometallics 1994, 13, 3237–3243, 10.1021/om00020a042
Full Transcript
1000/1000
Hot Most Recent
©Text is available under the terms and conditions of the Creative Commons-Attribution ShareAlike (CC BY-SA) license; additional terms may apply. By using this site, you agree to the Terms and Conditions and Privacy Policy.

Confirm

Are you sure to Delete?
Yes No
Cite
If you have any further questions, please contact Encyclopedia Editorial Office.
Palacios-Can, F.J. Insights into Si-Si and Si-H Bond. Encyclopedia. Available online: https://encyclopedia.pub/video/video_detail/679 (accessed on 15 November 2024).
Palacios-Can FJ. Insights into Si-Si and Si-H Bond. Encyclopedia. Available at: https://encyclopedia.pub/video/video_detail/679. Accessed November 15, 2024.
Palacios-Can, Francisco José. "Insights into Si-Si and Si-H Bond" Encyclopedia, https://encyclopedia.pub/video/video_detail/679 (accessed November 15, 2024).
Palacios-Can, F.J. (2023, April 03). Insights into Si-Si and Si-H Bond. In Encyclopedia. https://encyclopedia.pub/video/video_detail/679
Palacios-Can, Francisco José. "Insights into Si-Si and Si-H Bond." Encyclopedia. Web. 03 April, 2023.
ScholarVision Creations
Feedback