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Topic Review
Pi Interaction
In chemistry, π-effects or π-interactions are a type of non-covalent interaction that involves π systems. Just like in an electrostatic interaction where a region of negative charge interacts with a positive charge, the electron-rich π system can interact with a metal (cationic or neutral), an anion, another molecule and even another π system. Non-covalent interactions involving π systems are pivotal to biological events such as protein-ligand recognition.
  • 1.4K
  • 07 Dec 2022
Topic Review
Ionic and Excited Species
Experimental and theoretical studies of either characterization and reactivity of ionic and excited species with atoms, molecules, and radicals of interest in the chemistry of plasmas and energy production. Single and ionized species with single or multiple charge (H+, He+, H3+, HCO+, H3O+, He22+, CO22+, etc.), excited atoms and molecules (e.g. O(1D), N(2D), H*(2s2S1/2), He*(21,3S0,1), N2*(A3Σu+), etc.) play a crucial role in various important chemical systems such as flames (i.e. chemi-ionizations), natural plasmas (i.e. planetary ionospheres, comet tails and interstellar clouds), and biological environments (e.g. damaged biological tissues via the interaction between ionizing radiation and living cells). Such processes are very interesting from a fundamental point of view in Physical Chemistry and attracted the attention of a wide scientific community, since many applications to important fields: radiation chemistry, plasma physics and chemistry, combustion processes, development of laser sources. In particular, the conversion of waste carbon dioxide via assisted plasma technology gained recently increasing interest due to the possibility of obtaining value-added products, like gaseous or liquid fuels. Such characteristics make this an encouraging strategy for the storage of electrical energy from renewable sources into chemical energy in a circular economy scheme.
  • 1.3K
  • 01 Nov 2020
Topic Review
Natural Convection
Convection is single or multiphase fluid flow that occurs spontaneously due to the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the convection is unspecified, convection due to the effects of thermal expansion and buoyancy can be assumed. Convection may also take place in soft solids or mixtures where particles can flow. Convective flow may be transient (such as when a multiphase mixture of oil and water separates) or steady state (see Convection cell). The convection may be due to gravitational, electromagnetic or fictitious body forces. Heat transfer by natural convection plays a role in the structure of Earth's atmosphere, its oceans, and its mantle. Discrete convective cells in the atmosphere can be identified by clouds, with stronger convection resulting in thunderstorms. Natural convection also plays a role in stellar physics. Convection is often categorised or described by the main effect causing the convective flow, e.g. Thermal convection. Convection cannot take place in most solids because neither bulk current flows nor significant diffusion of matter can take place.
  • 1.3K
  • 10 Oct 2022
Topic Review
Thermodynamic Potential
A thermodynamic potential (or more accurately, a thermodynamic potential energy) is a scalar quantity used to represent the thermodynamic state of a system. The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886. Josiah Willard Gibbs in his papers used the term fundamental functions. One main thermodynamic potential that has a physical interpretation is the internal energy U. It is the energy of configuration of a given system of conservative forces (that is why it is called potential) and only has meaning with respect to a defined set of references (or data). Expressions for all other thermodynamic energy potentials are derivable via Legendre transforms from an expression for U. In thermodynamics, external forces, such as gravity, are typically disregarded when formulating expressions for potentials. For example, while all the working fluid in a steam engine may have higher energy due to gravity while sitting on top of Mount Everest than it would at the bottom of the Mariana Trench, the gravitational potential energy term in the formula for the internal energy would usually be ignored because changes in gravitational potential within the engine during operation would be negligible. In a large system under even homogeneous external force, like the earth atmosphere under gravity, the intensive parameters ([math]\displaystyle{ p, T, \rho }[/math]) should be studied locally having even in equilibrium different values in different places far from each other (see thermodynamic models of troposphere].
  • 1.2K
  • 04 Nov 2022
Topic Review
Grain Boundary Sliding
Grain Boundary Sliding (GBS) is a material deformation mechanism where grains slide against each other. This occurs in polycrystalline material under external stress at high homologous temperature (above ~0.4) and low strain rate and is intertwined with creep. Homologous temperature describes the operating temperature relative to the melting temperature of the material. There are mainly two types of grain boundary sliding: Rachinger sliding, and Lifshitz sliding. Grain boundary sliding usually occurs as a combination of both types of sliding. Boundary shape often determines the rate and extent of grain boundary sliding. Many people have developed estimations for the contribution of grain boundary sliding to the total strain experienced by various groups of materials, such as metals, ceramics, and geological materials. Grain boundary sliding contributes a significant amount of strain, especially for fine grain materials and high temperatures. It has been shown that Lifshitz grain boundary sliding contributes about 50-60% of strain in Nabarro-Herring diffusion creep. This mechanism is the primary cause of ceramic failure at high temperatures due to the formation of glassy phases at their grain boundaries. 
  • 1.2K
  • 30 Nov 2022
Topic Review
Azulene Moiety as Electron Reservoir
The nonalternant aromatic azulene, an isomer of alternant naphthalene, differs from the latter in peculiar properties. The large polarization of the π-electron system over the seven and five rings gives to azulene electrophile property a pronounced tendency to donate electrons to an acceptor, substituted at azulene 1 position. This paper presents cases in which azulene transfers electrons to a suitable acceptor as methylium ions, positive charged heteroaromatics and examples of neutral molecules that can accept electrons. 
  • 1.1K
  • 18 May 2021
Topic Review
Electromagnetically Excited Acoustic Noise and Vibration
Electromagnetically excited acoustic noise is audible sound directly produced by materials vibrating under the excitation of electromagnetic forces. Some examples of electromagnetically excited acoustic noise include the hum of transformers, the whine of some rotating electric machines, or the buzz of fluorescent lamps. The hissing of high voltage transmission lines is due to corona discharge, not magnetism. The phenomenon is also called audible magnetic noise, electromagnetic acoustic noise, or electromagnetically-induced acoustic noise, or more rarely, electrical noise, "coil noise", or "coil whine", depending on the application. The term electromagnetic noise is generally avoided as the term is used in the field of electromagnetic compatibility, dealing with radio frequencies. The term electrical noise describes electrical perturbations occurring in electronic circuits, not sound. For the latter use, the terms electromagnetic vibrations or magnetic vibrations, focusing on the structural phenomenon are less ambiguous. Acoustic noise and vibrations due to electromagnetic forces can be seen as the reciprocal of microphonics, which describes how a mechanical vibration or acoustic noise can induce an undesired electrical perturbation.
  • 1.1K
  • 28 Oct 2022
Topic Review
AFM-IR
AFM-IR (atomic force microscope infrared-spectroscopy) is one of a family of techniques that are derived from a combination of two parent instrumental techniques; infrared spectroscopy and scanning probe microscopy (SPM). The term was first used to denote a method that combined a tuneable free electron laser with an atomic force microscope (a type of SPM) equipped with a sharp probe that measured the local absorption of infrared light by a sample; it required that the sample be coupled to an infrared-transparent prism and be less than 1μm thick. It improved the spatial resolution of photothermal AFM-based techniques from microns to circa 100 nm. Recording the amount of infrared absorption as a function of wavelength or wavenumber creates an infrared absorption spectra that can be used to chemically characterize and even identify unknown materials. Recording the infrared absorption as a function of position can be used to create chemical composition maps that show the spatial distribution of different chemical components. Novel extensions of the original AFM-IR technique and earlier techniques have enabled the development of bench-top devices capable of nanometer spatial resolution, that do not require a prism and can work with thicker samples, and thereby greatly improving ease of use and expanding the range of samples that can be analysed. One of these techniques has achieved spatial resolutions down to around 20 nm, with a sensitivity down to the scale of molecular monolayer AFM-IR is related to techniques such as tip-enhanced Raman spectroscopy (TERS), scanning near-field optical microscopy (SNOM), nano-FTIR and other methods of vibrational analysis with scanning probe microscopy.
  • 1.0K
  • 11 Nov 2022
Biography
Friedrich Hund
Friedrich Hermann Hund (4 February 1896 – 31 March 1997) was a Germany physicist from Karlsruhe known for his work on atoms and molecules.[1] Hund worked at the Universities of Rostock, Leipzig, Jena, Frankfurt am Main, and Göttingen. Hund worked with such prestigious physicists as Schrödinger, Dirac, Heisenberg, Max Born, and Walter Bothe. At that time, he was Born's assistant, working
  • 942
  • 18 Nov 2022
Topic Review
Valence-shell Electron-pair Repulsion Model
There are the following main assumptions of the Valence-shell Electron-pair Repulsion (VSEPR) model. - The arrangement of covalent bonds of the atom centre analyzed depends on the number of electron pairs in its valence shell: bonds and nonbonding pairs as lone electron pairs. - The arrangement of valence electron pairs around the centre considered is to maximize their distances apart. - The non-valence electrons - inner electrons with nucleus (i.e. the core) possess the spherical symmetry (or at least it is in force for the main groups elements). It is worth to note that the intra- and intermolecular interactions influence on electronic and molecular structures in accordance with this VSEPR model.
  • 865
  • 06 Sep 2021
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