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Zhong, J. Oligomers. Encyclopedia. Available online: https://encyclopedia.pub/entry/62095 (accessed on 12 November 2026).
Zhong J. Oligomers. Encyclopedia. Available at: https://encyclopedia.pub/entry/62095. Accessed November 12, 2026.
Zhong, Jack. "Oligomers" Encyclopedia, https://encyclopedia.pub/entry/62095 (accessed November 12, 2026).
Zhong, J. (2026, November 09). Oligomers. In Encyclopedia. https://encyclopedia.pub/entry/62095
Zhong, Jack. "Oligomers." Encyclopedia. Web. 09 November, 2026.

Oligomers

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Oligomers are molecules composed of a small number of repeat units, conventionally fewer than about ten, joined by the same bonds that form a polymer, so they occupy the range between monomers and macromolecules [1]. Because the chain is short, properties that depend on entanglement or on long-range cooperative motion are absent, and the melting or softening behaviour is dominated by end groups and by the specific sequence of units [2]. Individual oligomers are discrete compounds with a defined molar mass, whereas a polymer is a distribution of chain lengths, and this distinction separates the two classes [3]. Oligomers retain the reactivity of their functional end groups, which allows them to be extended into higher polymers by further coupling [1].

repeat unit degree of polymerization low molar mass end group step-growth
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References

  1. Ly, H.V.; Parvez, M.; Roesler, R. An Unusual Ligand in Copper Chemistry: Coordination Oligomers and Polymers Containing the [{CpMo(CO)2}2(μ,η2-Sb2)] Cluster. Inorganic Chemistry 2006, 45, 345-351. [CrossRef]
  2. Yamaguchi, S.; Tamao, K. Cross-coupling reactions in the chemistry of silole-containing π-conjugated oligomers and polymers. Journal of Organometallic Chemistry 2002, 653, 223-228. [CrossRef]
  3. Puddephatt, R.J. Macrocycles, catenanes, oligomers and polymers in gold chemistry. Chemical Society Reviews 2008, 37, 2012. [CrossRef]
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Subjects: Polymer Science
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Update Date: 09 Nov 2026
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