| Version | Summary | Created by | Modification | Content Size | Created at | Operation |
|---|---|---|---|---|---|---|
| 1 | Jack Zhong | -- | 124 | 2026-11-06 02:31:46 | | | |
| 2 | Jack Zhong | -9 word(s) | 115 | 2026-11-06 03:08:41 | | |
Nitrile rubber is a copolymer of butadiene and acrylonitrile in which the unsaturated diene segments form the elastomeric network and the nitrile groups supply polarity [1]. The acrylonitrile fraction, usually between 18 and 50 percent, sets the balance: higher content raises oil resistance and the glass transition temperature, while lower content preserves flexibility in the cold [1]. Vulcanisation proceeds through the residual double bonds, and the resulting crosslink density fixes compression set and swelling [2]. Hydrogenated grades convert backbone double bonds into methylene sequences, which removes the sites at which oxidation and ozonolysis begin [3]. The nitrile dipole also makes the polymer compatible with polar plasticisers and incompatible with non-polar oils [1].