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Zhong, J. Nitrile Rubber. Encyclopedia. Available online: https://encyclopedia.pub/entry/62020 (accessed on 12 November 2026).
Zhong J. Nitrile Rubber. Encyclopedia. Available at: https://encyclopedia.pub/entry/62020. Accessed November 12, 2026.
Zhong, Jack. "Nitrile Rubber" Encyclopedia, https://encyclopedia.pub/entry/62020 (accessed November 12, 2026).
Zhong, J. (2026, November 06). Nitrile Rubber. In Encyclopedia. https://encyclopedia.pub/entry/62020
Zhong, Jack. "Nitrile Rubber." Encyclopedia. Web. 06 November, 2026.

Nitrile Rubber

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Nitrile rubber is a copolymer of butadiene and acrylonitrile in which the unsaturated diene segments form the elastomeric network and the nitrile groups supply polarity [1]. The acrylonitrile fraction, usually between 18 and 50 percent, sets the balance: higher content raises oil resistance and the glass transition temperature, while lower content preserves flexibility in the cold [1]. Vulcanisation proceeds through the residual double bonds, and the resulting crosslink density fixes compression set and swelling [2]. Hydrogenated grades convert backbone double bonds into methylene sequences, which removes the sites at which oxidation and ozonolysis begin [3]. The nitrile dipole also makes the polymer compatible with polar plasticisers and incompatible with non-polar oils [1].

nbr elastomer acrylonitrile content hydrogenated nitrile rubber oil resistance vulcanisation
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References

  1. Verdier, N.; Lepage, D.; Prébé, A.; Aymé‐Perrot, D.; Dollé, M.; Rochefort, D. Crosslinker free thermally induced crosslinking of hydrogenated nitrile butadiene rubber. Journal of Polymer Science Part A: Polymer Chemistry 2018, 56, 1825-1833. [CrossRef]
  2. Alcock, B.; Olafsen, K.; Huse, J.; Grytten, F. The low temperature crystallization of hydrogenated nitrile butadiene rubber (HNBR). Polymer Testing 2018, 66, 228-234. [CrossRef]
  3. Wang, H.; Yang, L.; Rempel, G.L. Homogeneous Hydrogenation Art of Nitrile Butadiene Rubber: A Review. Polymer Reviews 2013, 53, 192-239. [CrossRef]
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Subjects: Polymer Science
Contributor MDPI registered users' name will be linked to their SciProfiles pages. To register with us, please refer to https://encyclopedia.pub/register : Jack Zhong
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Update Date: 06 Nov 2026
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