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Zhong, J. Polyvinyl Pyrrolidone. Encyclopedia. Available online: https://encyclopedia.pub/entry/62010 (accessed on 12 November 2026).
Zhong J. Polyvinyl Pyrrolidone. Encyclopedia. Available at: https://encyclopedia.pub/entry/62010. Accessed November 12, 2026.
Zhong, Jack. "Polyvinyl Pyrrolidone" Encyclopedia, https://encyclopedia.pub/entry/62010 (accessed November 12, 2026).
Zhong, J. (2026, November 06). Polyvinyl Pyrrolidone. In Encyclopedia. https://encyclopedia.pub/entry/62010
Zhong, Jack. "Polyvinyl Pyrrolidone." Encyclopedia. Web. 06 November, 2026.

Polyvinyl Pyrrolidone

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Polyvinyl pyrrolidone is a vinyl polymer built from N-vinylpyrrolidone units, in which a lactam ring hangs from each backbone carbon [1]. The amide carbonyl and the ring nitrogen make the polymer a strong hydrogen-bond acceptor and strongly hygroscopic, and the same polarity makes it soluble in water and in alcohols while insoluble in hydrocarbons [2]. Because the lactam is non-ionic, the polymer carries no charge at any pH and its solutions stay stable across the pH range [1]. The ring also complexes iodine and phenolic compounds, and the chain adsorbs onto polar surfaces through the carbonyl oxygen [3]. Molar mass spans several orders of magnitude, and the chain-length grade rather than the chemistry sets the viscosity of a solution [2].

pvp lactam ring hygroscopic polymer hydrogen-bond acceptor iodine complex
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References

  1. Sapir, L.; Stanley, C.B.; Harries, D. Properties of Polyvinylpyrrolidone in a Deep Eutectic Solvent. The Journal of Physical Chemistry A 2016, 120, 3253-3259. [CrossRef]
  2. Lubasova, D.; Niu, H.; Zhao, X.; Lin, T. Hydrogel properties of electrospun polyvinylpyrrolidone and polyvinylpyrrolidone/poly(acrylic acid) blend nanofibers. RSC Advances 2015, 5, 54481-54487. [CrossRef]
  3. Pourmadadi, M.; Shamsabadipour, A.; Aslani, A.; Eshaghi, M.M.; Rahdar, A.; Pandey, S. Development of Polyvinylpyrrolidone-Based nanomaterials for biosensors applications: A Review. Inorganic Chemistry Communications 2023, 152, 110714. [CrossRef]
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Subjects: Polymer Science
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Update Date: 06 Nov 2026
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