| Version | Summary | Created by | Modification | Content Size | Created at | Operation |
|---|---|---|---|---|---|---|
| 1 | Jack Zhong | -- | 120 | 2026-11-05 17:28:05 | | | |
| 2 | Catherine Yang | -9 word(s) | 111 | 2026-11-06 01:28:17 | | | | |
| 3 | Jack Zhong | Meta information modification | 111 | 2026-11-06 03:13:53 | | |
Dialdehyde cellulose is cellulose whose anhydroglucose units carry two aldehyde groups at C2 and C3, produced by oxidative cleavage of the vicinal diols of the glucopyranose ring [1]. Cleavage opens the ring, so the product is a chain of 2,3-dialdehydic residues whose aldehyde content is expressed per anhydroglucose unit [1]. Because the aldehydes hydrate and form hemiacetals with neighbouring hydroxyls, the polymer is partly crosslinked and its crystallinity falls as oxidation proceeds [2]. The dialdehyde groups condense with amines and hydrazides to give imines and hydrazones, and that reactivity separates the material from carboxymethyl or hydroxyethyl cellulose [3]. Over-oxidation shortens the chain and introduces carboxyl groups [3].