Your browser does not fully support modern features. Please upgrade for a smoother experience.
Submitted Successfully!
Thank you for your contribution! You can also upload a video entry or images related to this topic. For video creation, please contact our Academic Video Service.
Version Summary Created by Modification Content Size Created at Operation
1 Jack Zhong -- 172 2026-10-20 09:06:17 |
2 delete taxonomomy Jack Zhong -9 word(s) 163 2026-10-20 09:08:45 |

Video Upload Options

We provide professional Academic Video Service to translate complex research into visually appealing presentations. Would you like to try it?
No, upload directly Yes
Cite
If you have any further questions, please contact Encyclopedia Editorial Office.
Zhong, J. Porous Organic Polymers. Encyclopedia. Available online: https://encyclopedia.pub/entry/61182 (accessed on 12 November 2026).
Zhong J. Porous Organic Polymers. Encyclopedia. Available at: https://encyclopedia.pub/entry/61182. Accessed November 12, 2026.
Zhong, Jack. "Porous Organic Polymers" Encyclopedia, https://encyclopedia.pub/entry/61182 (accessed November 12, 2026).
Zhong, J. (2026, October 20). Porous Organic Polymers. In Encyclopedia. https://encyclopedia.pub/entry/61182
Zhong, Jack. "Porous Organic Polymers." Encyclopedia. Web. 20 October, 2026.

Porous Organic Polymers

Edit

Porous organic polymers are amorphous networks built entirely from light elements through covalent bonds, and they contain permanent pores as a result of their rigid, contorted architecture. Because no metal is present, the framework is stable in acid and in base, which distinguishes it from a coordination network [1]. The porosity is introduced either by a rigid monomer of intrinsic free volume or by a template that is removed after polymerisation [2]. Hyper-crosslinked polystyrene and polymers of intrinsic microporosity are the two families studied most, and they are prepared by routes that are compatible with large-scale synthesis [3]. Their main roles are gas storage and separation, and the selectivity can be tuned by introducing a polar or a basic group into the pore [4]. The amorphous structure means there is no single pore size, so the adsorption isotherm is broader than that of a crystalline framework, and modelling the transport is correspondingly harder [5].

amorphous network intrinsic microporosity hyper-crosslinked polymer gas storage permanent porosity covalent bond adsorption isotherm
Help expand this entry Share your expertise by adding detailed content and references to improve this entry.
Add content

References

  1. Xu, Y.; Chang, D.; Feng, S.; Zhang, C.; Jiang, J.X. BODIPY-containing porous organic polymers for gas adsorption. New Journal of Chemistry 2016, 40, 9415-9423. [CrossRef]
  2. Kodrin, I.; Biljan, I. Porous Organic Polymers with Azo, Azoxy, and Azodioxy Linkages: Design, Synthesis, and CO2 Adsorption Properties. Polymers 2026, 18, 735. [CrossRef]
  3. Park, J.K. Syntheses of Porous Organic Polymers via Cobalt‐catalyzed Acetylene Trimerization and Their Gas Adsorption Properties. Bulletin of the Korean Chemical Society 2016, 37, 617-618. [CrossRef]
  4. Matias, P.M.C.; Murtinho, D.; Valente, A.J.M. Triazine-Based Porous Organic Polymers: Synthesis and Application in Dye Adsorption and Catalysis. Polymers 2023, 15, 1815. [CrossRef]
  5. Nie, W.; Liu, J.; Bai, X.; Xing, Z.; Gao, Y. Designing Phenyl Porous Organic Polymers with High-Efficiency Tetracycline Adsorption Capacity and Wide pH Adaptability. Polymers 2022, 14, 203. [CrossRef]
More
©Text is available under the terms and conditions of the Creative Commons-Attribution ShareAlike (CC BY-SA) license; additional terms may apply. By using this site, you agree to the Terms and Conditions and Privacy Policy.
Upload a video for this entry
Information
Subjects: Polymer Science
Contributor MDPI registered users' name will be linked to their SciProfiles pages. To register with us, please refer to https://encyclopedia.pub/register : Jack Zhong
View Times: 10
Revisions: 2 times (View History)
Update Date: 20 Oct 2026
Table of Contents
    Notice
    You are not a member of the advisory board for this topic. If you want to update advisory board member profile, please contact office@encyclopedia.pub.
    OK
    Confirm
    Only members of the Encyclopedia advisory board for this topic are allowed to note entries. Would you like to become an advisory board member of the Encyclopedia?
    Yes
    No
    ${ textCharacter }/${ maxCharacter }
    Submit
    Cancel
    There is no comment~
    ${ textCharacter }/${ maxCharacter }
    Submit
    Cancel
    ${ selectedItem.replyTextCharacter }/${ selectedItem.replyMaxCharacter }
    Submit
    Cancel
    Confirm
    Are you sure to Delete?
    Yes No
    Write an Entry
    Feedback