Cadmium sulfide is a II-VI compound semiconductor with a direct band gap in the visible, examined mostly as a photocatalyst and as a quantum dot. Immobilising the sulfide on a polymer support was an early route to photocatalytic hydrogen sulfide splitting [1]. Embedding gold quantum dots in hollow sulfide spheres raises the hydrogen evolution rate by shortening the path to the surface [2]. Interfacial charge transfer from a sulfide quantum dot into a monolayer dichalcogenide can be followed directly [3]. Pairing a zinc-cadmium sulfide with graphitic carbon nitride gives a type-II heterojunction [4]. Sequential proton-coupled electron transfer at a sulfide surface converts nitrobenzene to aniline [5].
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Li, M.; Fron, E.; Cotlet, M. Interfacial Charge Transfer in Lead Sulfide/Cadmium Sulfide Quantum Dot–Monolayer Molybdenum Disulfide Heterostructures. ACS Omega2026, 11, 30617-30623. [CrossRef]
Yousaf, A.B.; Imran, M.; Farooq, M.; Kausar, S.; Yasmeen, S.; Kasak, P. Graphitic Carbon Nitride Nanosheets Decorated with Zinc-Cadmium Sulfide for Type-II Heterojunctions for Photocatalytic Hydrogen Production. Nanomaterials2023, 13, 2609. [CrossRef]
Jensen, S.C.; Bettis Homan, S.; Weiss, E.A. Photocatalytic Conversion of Nitrobenzene to Aniline through Sequential Proton-Coupled One-Electron Transfers from a Cadmium Sulfide Quantum Dot. Journal of the American Chemical Society2016, 138, 1591-1600. [CrossRef]
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