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Zhong, J. High Temperature Corrosion. Encyclopedia. Available online: https://encyclopedia.pub/entry/60555 (accessed on 06 October 2026).
Zhong J. High Temperature Corrosion. Encyclopedia. Available at: https://encyclopedia.pub/entry/60555. Accessed October 06, 2026.
Zhong, Jack. "High Temperature Corrosion" Encyclopedia, https://encyclopedia.pub/entry/60555 (accessed October 06, 2026).
Zhong, J. (2026, September 28). High Temperature Corrosion. In Encyclopedia. https://encyclopedia.pub/entry/60555
Zhong, Jack. "High Temperature Corrosion." Encyclopedia. Web. 28 September, 2026.
High Temperature Corrosion
Edit

High temperature corrosion is the degradation of a material by chemical reaction with a hot gas, a molten salt or a deposit, at temperatures where the reaction product is a solid scale rather than an aqueous electrolyte film. In practice the dominant form is oxidation: a growing oxide layer separates the metal from the gas, and the rate is then controlled by the transport of ions or electrons through that layer, which is why the growth usually follows a parabolic law and why the composition and the defect structure of the scale matter more than the composition of the alloy. A protective scale is one that is dense, slow-growing and adherent, and the classical studies of refractory-metal oxidation established how quickly an alloy fails when the oxide is none of these [1]. The same criteria are applied to the compositionally concentrated alloys now being developed, where the oxidation behaviour of a medium-entropy alloy has been measured directly [2]. The results for the high-entropy families have been critically reviewed [3]. Surface treatments that introduce a second element into the surface layer improve the resistance by promoting a more protective scale [4]. Where an oxide is deliberately formed before service, as on zirconium alloy cladding, the initial scale changes the subsequent kinetics [5]. Spallation on thermal cycling, and attack by molten deposits, remain the limiting mechanisms.

oxidation oxide scale parabolic rate law protective scale spallation hot corrosion

References

  1. Sikka, V.; Rosa, C. High temperature oxidation of Nb-10 at. % W alloy. Corrosion Science 1980, 20, 1221-1239. [CrossRef]
  2. Agustianingrum, M.P.; Lee, U.; Park, N. High-temperature oxidation behaviour of CoCrNi medium-entropy alloy. Corrosion Science 2020, 173, 108755. [CrossRef]
  3. Singh, D.; Singh, H.; Kumar, R. High-Temperature Oxidation of CoCrFeMnNi- and AlCoCrFeNi-Based High-Entropy Alloys: A Critical Review on Mechanisms, Kinetics, and Alloy Design Principles. High Temperature Corrosion of Materials 2026, 103, 94. [CrossRef]
  4. Garip, Y. Improving the Oxidation Behavior of CoCrFe2Ni0.5 High Entropy Alloy Through Powder-Pack Boriding. High Temperature Corrosion of Materials 2024, 101, 549-571. [CrossRef]
  5. Lee, C.M.; Sohn, D.S. Enhanced high-temperature oxidation resistance of a zirconium alloy cladding by high-temperature preformed oxide on the cladding. Corrosion Science 2018, 131, 116-125. [CrossRef]
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