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Kang, H. Catalytic Oxidation. Encyclopedia. Available online: https://encyclopedia.pub/entry/60423 (accessed on 03 October 2026).
Kang H. Catalytic Oxidation. Encyclopedia. Available at: https://encyclopedia.pub/entry/60423. Accessed October 03, 2026.
Kang, Helena. "Catalytic Oxidation" Encyclopedia, https://encyclopedia.pub/entry/60423 (accessed October 03, 2026).
Kang, H. (2026, September 24). Catalytic Oxidation. In Encyclopedia. https://encyclopedia.pub/entry/60423
Kang, Helena. "Catalytic Oxidation." Encyclopedia. Web. 24 September, 2026.
Catalytic Oxidation
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Catalytic oxidation is an oxidation in which a catalyst mediates electron and/or oxygen-atom transfer from an oxidant to a substrate and is regenerated in the catalytic cycle [1][2]. In catalysis and oxidation reactions the concept is bounded by a net increase in the oxidation state of the substrate and by turnover of the catalytic species, whether a metal surface, a molecular metal complex, or a mediator. Essential features are an oxidant (O2, H2O2, or an anodic equivalent), a catalyst that activates that oxidant or the substrate, and a sequence of electron-transfer steps that returns the catalyst to its resting state [2][3]. Heterogeneous variants include plasmon-enhanced oxidation at silver nanostructures and interface-confined ferrous centers that activate oxygen at a metal–oxide boundary [1][4]. Homogeneous biomimetic systems couple a metal catalyst to a coupled electron-transfer chain so that molecular oxygen or hydrogen peroxide can be used without stoichiometric metal consumption [3]. The concept is distinguished from stoichiometric oxidation by regeneration of the oxidant-activating species, and from catalytic reduction by the direction of electron flow. Conceptual limits exclude combustions in which the catalyst only ignites an uncontrolled radical chain and exclude oxygen-atom transfers that do not change the substrate’s formal oxidation state.

catalytic oxidation electron transfer oxygen activation heterogeneous catalyst

References

  1. Phillip Christopher; Hongliang Xin; Suljo Linic; Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures. Nat. Chem. 2011, 3, 467-472. [CrossRef]
  2. Chi He; Jie Cheng; Xin Zhang; Mark Douthwaite; Samuel Pattisson; Zhengping Hao; Recent Advances in the Catalytic Oxidation of Volatile Organic Compounds: A Review Based on Pollutant Sorts and Sources. Chem. Rev. 2019, 119, 4471-4568. [CrossRef]
  3. Julio Piera; Jan‐E. Bäckvall; Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach. Angew. Chem. Int. Ed. 2008, 47, 3506-3523. [CrossRef]
  4. Qiang Fu; Wei-Xue Li; Yunxi Yao; Hongyang Liu; Hai-Yan Su; Ding Ma; Xiang-Kui Gu; Limin Chen; Zhen Wang; Hui Zhang; Bing Wang; Xinhe Bao; Interface-Confined Ferrous Centers for Catalytic Oxidation. Science 2010, 328, 1141-1144. [CrossRef]
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Subjects: Chemistry, Organic
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Update Date: 24 Sep 2026
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