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1 Jack Zhong -- 237 2026-09-22 05:21:16 |
2 changed reference order Jack Zhong + 9 word(s) 246 2026-09-22 05:46:02 | |
3 format correct Catherine Yang -11 word(s) 235 2026-09-22 07:42:23 |

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Zhong, J. Organic Solar Cell. Encyclopedia. Available online: https://encyclopedia.pub/entry/60212 (accessed on 27 September 2026).
Zhong J. Organic Solar Cell. Encyclopedia. Available at: https://encyclopedia.pub/entry/60212. Accessed September 27, 2026.
Zhong, Jack. "Organic Solar Cell" Encyclopedia, https://encyclopedia.pub/entry/60212 (accessed September 27, 2026).
Zhong, J. (2026, September 22). Organic Solar Cell. In Encyclopedia. https://encyclopedia.pub/entry/60212
Zhong, Jack. "Organic Solar Cell." Encyclopedia. Web. 22 September, 2026.
Organic Solar Cell
Edit

An organic solar cell is a photovoltaic device in which light is absorbed and charge is separated by molecular or polymeric semiconductors rather than by an inorganic crystal. Absorption creates a bound exciton, so a donor-acceptor interface is needed to split it; in the bulk heterojunction the two materials are cast from a common solution and interpenetrate on a scale of 10 to 20 nanometres, which sets how many excitons reach an interface before they decay [1]; in an oligothiophene-fullerene blend it is this interpenetrating structure that carries the photocurrent [2]. The morphology of the blend depends on the solvent, the drying rate and any thermal or solvent annealing, and small changes in domain purity and size can move the power conversion efficiency by several percentage points [1], the domain structure entering the optical and photovoltaic response directly [3]. Early devices used fullerene derivatives as the acceptor, and laboratory cells of that type reached efficiencies approaching 10 percent [2]. Non-fullerene acceptors, whose absorption and energy levels can be tuned independently of the donor, were introduced to raise both the current and the voltage [4]. Certified efficiencies in single junctions now exceed 19 percent where wide-bandgap donors are matched to them to keep the open-circuit voltage high [5]. Stability under illumination and in air, and the difficulty of reproducing the blend morphology outside spin coating, remain the main obstacles [3].

bulk heterojunction non-fullerene acceptor power conversion efficiency exciton morphology bulk heterojunction non-fullerene acceptor power conversion efficiency exciton morphology

References

  1. Giridharagopal, R.; Ginger, D.S. Characterizing Morphology in Bulk Heterojunction Organic Photovoltaic Systems. The Journal of Physical Chemistry Letters 2010, 1, 1160-1169. [CrossRef]
  2. Sakai, J.; Taima, T.; Saito, K. Efficient oligothiophene:fullerene bulk heterojunction organic photovoltaic cells. Organic Electronics 2008, 9, 582-590. [CrossRef]
  3. Asanov, N.; Schopp, N.; Valagiannopoulos, C.; Brus, V. Optical and photovoltaic properties of organic solar cells versus bulk-heterojunction morphology. Physical Review B 2024, 109, 205201. [CrossRef]
  4. Cheng, P.; Zhao, X.; Zhou, W.; Hou, J.; Li, Y.; Zhan, X. Towards high-efficiency non-fullerene organic solar cells: Matching small molecule/polymer donor/acceptor. Organic Electronics 2014, 15, 2270-2276. [CrossRef]
  5. He, K.; Kumar, P.; Yuan, Y.; Li, Y. Wide bandgap polymer donors for high efficiency non-fullerene acceptor based organic solar cells. Materials Advances 2021, 2, 115-145. [CrossRef]
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